{"title":"作为氯富勒烯的次要 C84 异构体 C84(11)Cl22、C84(14)Cl22、C84(16)Cl22 和 C84(16)Cl24 的结构研究","authors":"Nadezhda B. Tamm, Sergey I. Troyanov","doi":"10.1016/j.mencom.2024.09.035","DOIUrl":null,"url":null,"abstract":"<div><div>Chlorofullerenes C<sub>84</sub>Cl<sub>22,24</sub> were obtained by chlorination of minor C<sub>84</sub> isomers mixture with VCl<sub>4</sub> at 330 °C. An X-ray crystallographic study with the use of synchrotron radiation revealed the presence of C<sub>84</sub>(11)Cl<sub>22</sub>, C<sub>84</sub>(14)Cl<sub>22</sub>, C<sub>84</sub>(16)Cl<sub>22</sub>, and C<sub>84</sub>(16)Cl<sub>24</sub> in the same crystal.</div></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":"34 5","pages":"Pages 734-736"},"PeriodicalIF":1.8000,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Structural study of minor C84 isomers as chlorofullerenes, C84(11)Cl22, C84(14)Cl22, C84(16)Cl22, and C84(16)Cl24\",\"authors\":\"Nadezhda B. Tamm, Sergey I. Troyanov\",\"doi\":\"10.1016/j.mencom.2024.09.035\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Chlorofullerenes C<sub>84</sub>Cl<sub>22,24</sub> were obtained by chlorination of minor C<sub>84</sub> isomers mixture with VCl<sub>4</sub> at 330 °C. An X-ray crystallographic study with the use of synchrotron radiation revealed the presence of C<sub>84</sub>(11)Cl<sub>22</sub>, C<sub>84</sub>(14)Cl<sub>22</sub>, C<sub>84</sub>(16)Cl<sub>22</sub>, and C<sub>84</sub>(16)Cl<sub>24</sub> in the same crystal.</div></div>\",\"PeriodicalId\":18542,\"journal\":{\"name\":\"Mendeleev Communications\",\"volume\":\"34 5\",\"pages\":\"Pages 734-736\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Mendeleev Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0959943624002748\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Mendeleev Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0959943624002748","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
氯富勒烯 C84Cl22,24 是在 330 °C 下用 VCl4 对次要的 C84 异构体混合物进行氯化而得到的。利用同步辐射进行的 X 射线晶体学研究显示，在同一晶体中存在 C84(11)Cl22、C84(14)Cl22、C84(16)Cl22 和 C84(16)Cl24 四种异构体。
Structural study of minor C84 isomers as chlorofullerenes, C84(11)Cl22, C84(14)Cl22, C84(16)Cl22, and C84(16)Cl24
Chlorofullerenes C84Cl22,24 were obtained by chlorination of minor C84 isomers mixture with VCl4 at 330 °C. An X-ray crystallographic study with the use of synchrotron radiation revealed the presence of C84(11)Cl22, C84(14)Cl22, C84(16)Cl22, and C84(16)Cl24 in the same crystal.
期刊介绍：
Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications.
Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
