{"title":"探索质量分散型 rGO 对磷酸三镍金属有机框架的原位影响,以实现更高能量密度的混合超级电容器","authors":"","doi":"10.1016/j.est.2024.114140","DOIUrl":null,"url":null,"abstract":"<div><div>The present study investigates effect of reduced graphene oxide (rGO) mass dispersoid @ 25, 50, 75, and 100 mg through in-situ process into Metal Organic Framework based Nickel Phosphate (MOFNP) synthesized by facile microwave technique. The XRD study confirms monoclinic crystalline geometry and 50 mg rGO dispersed MOFNP (MOFNPG2) composite has shown increase in crystallinity. SEM shows rectangular morphology for MOFNPG2 and Raman studies show I<sub>D</sub>/I<sub>G</sub> ratio of 1.01 for this composite revealing rGO coordination with MOFNP. BET studies reveal higher specific surface area (59.75 m<sup>2</sup> g<sup>−1</sup>) for MOFNPG2 and exhibits mesoporosity (3.14 nm) with type-IV Langmuir isotherm. The deconvoluted XPS spectra confirms oxidation states and chemical compositions of MOFNPG2. The CV profile identifies maximum oxidation for MOFNPG2, revealing EDLC / pseudocapacitance contribution and exhibiting higher specific capacitance of 854 F g<sup>−1</sup> @ 1 A g<sup>−1</sup>. The Full-Cell Device (FCD) MOFNPG2//rGO registers 175 F g<sup>−1</sup> @ 1 A g<sup>−1</sup> and energy density 79 Wh kg<sup>−1</sup>. The R<sub>esr</sub> is lower (0.19 Ω cm<sup>−2</sup>) for FCD which improvises electrode-electrolyte kinetics and results in enhanced conductivity for high energy density supercapacitor applications.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":null,"pages":null},"PeriodicalIF":8.9000,"publicationDate":"2024-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Exploratory mass dispersoid rGO in-situ influence on nickel phosphate-trimesic acid metal-organic framework for higher energy density hybrid supercapacitors\",\"authors\":\"\",\"doi\":\"10.1016/j.est.2024.114140\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The present study investigates effect of reduced graphene oxide (rGO) mass dispersoid @ 25, 50, 75, and 100 mg through in-situ process into Metal Organic Framework based Nickel Phosphate (MOFNP) synthesized by facile microwave technique. The XRD study confirms monoclinic crystalline geometry and 50 mg rGO dispersed MOFNP (MOFNPG2) composite has shown increase in crystallinity. SEM shows rectangular morphology for MOFNPG2 and Raman studies show I<sub>D</sub>/I<sub>G</sub> ratio of 1.01 for this composite revealing rGO coordination with MOFNP. BET studies reveal higher specific surface area (59.75 m<sup>2</sup> g<sup>−1</sup>) for MOFNPG2 and exhibits mesoporosity (3.14 nm) with type-IV Langmuir isotherm. The deconvoluted XPS spectra confirms oxidation states and chemical compositions of MOFNPG2. The CV profile identifies maximum oxidation for MOFNPG2, revealing EDLC / pseudocapacitance contribution and exhibiting higher specific capacitance of 854 F g<sup>−1</sup> @ 1 A g<sup>−1</sup>. The Full-Cell Device (FCD) MOFNPG2//rGO registers 175 F g<sup>−1</sup> @ 1 A g<sup>−1</sup> and energy density 79 Wh kg<sup>−1</sup>. The R<sub>esr</sub> is lower (0.19 Ω cm<sup>−2</sup>) for FCD which improvises electrode-electrolyte kinetics and results in enhanced conductivity for high energy density supercapacitor applications.</div></div>\",\"PeriodicalId\":15942,\"journal\":{\"name\":\"Journal of energy storage\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":8.9000,\"publicationDate\":\"2024-10-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of energy storage\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2352152X24037265\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of energy storage","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2352152X24037265","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Exploratory mass dispersoid rGO in-situ influence on nickel phosphate-trimesic acid metal-organic framework for higher energy density hybrid supercapacitors
The present study investigates effect of reduced graphene oxide (rGO) mass dispersoid @ 25, 50, 75, and 100 mg through in-situ process into Metal Organic Framework based Nickel Phosphate (MOFNP) synthesized by facile microwave technique. The XRD study confirms monoclinic crystalline geometry and 50 mg rGO dispersed MOFNP (MOFNPG2) composite has shown increase in crystallinity. SEM shows rectangular morphology for MOFNPG2 and Raman studies show ID/IG ratio of 1.01 for this composite revealing rGO coordination with MOFNP. BET studies reveal higher specific surface area (59.75 m2 g−1) for MOFNPG2 and exhibits mesoporosity (3.14 nm) with type-IV Langmuir isotherm. The deconvoluted XPS spectra confirms oxidation states and chemical compositions of MOFNPG2. The CV profile identifies maximum oxidation for MOFNPG2, revealing EDLC / pseudocapacitance contribution and exhibiting higher specific capacitance of 854 F g−1 @ 1 A g−1. The Full-Cell Device (FCD) MOFNPG2//rGO registers 175 F g−1 @ 1 A g−1 and energy density 79 Wh kg−1. The Resr is lower (0.19 Ω cm−2) for FCD which improvises electrode-electrolyte kinetics and results in enhanced conductivity for high energy density supercapacitor applications.
期刊介绍:
Journal of energy storage focusses on all aspects of energy storage, in particular systems integration, electric grid integration, modelling and analysis, novel energy storage technologies, sizing and management strategies, business models for operation of storage systems and energy storage developments worldwide.