Guo Feng , Tiantian Liu , Feng Jiang , Zhiqi Guo , Liangliang Xiao , Qian Wu , Xiaojun Zhang , Qing Hu , Jianmin Liu , Jian Liang
{"title":"基于（镍、锰）共掺杂 (CuFe)Fe4O8 的新型无钴、无铬高温黑色陶瓷颜料","authors":"Guo Feng , Tiantian Liu , Feng Jiang , Zhiqi Guo , Liangliang Xiao , Qian Wu , Xiaojun Zhang , Qing Hu , Jianmin Liu , Jian Liang","doi":"10.1016/j.jeurceramsoc.2024.116987","DOIUrl":null,"url":null,"abstract":"<div><div>Novel Co and Cr free, high-temperature (Ni, Mn) co-doping (CuFe)Fe<sub>4</sub>O<sub>8</sub> black ceramic pigment was synthesized. The results indicate that the brightness (L*) values of the synthesized pigments decrease first, then reach an optimal value, and then increase with the doping amounts increasing of both Ni<sub>2</sub>O<sub>3</sub> and MnO<sub>2</sub>. The optimized Ni<sub>2</sub>O<sub>3</sub> and MnO<sub>2</sub> doping amounts are 0.20 (molar ratio to (CuFe)Fe<sub>4</sub>O<sub>8</sub>) and 0.75 (molar ratio to (CuFe)Fe<sub>4</sub>O<sub>8</sub>), respectively. L*, a* and b* values of the optimized pigment (0.20Ni, 0.75Mn) co-doping (CuFe)Fe<sub>4</sub>O<sub>8</sub> are 21.36, 1.10 and −0.24, respectively. The crystal phase of the optimized pigment is (CuFe)Fe<sub>4</sub>O<sub>8</sub> (JCPDS73–2314). The crystal size of the pigment is 0.8–1.5<em>μ</em>m with excellent dispersivity. The glazing temperatures have little effect on the coloration of the pigment when used at 1000℃, 1150℃ and 1300℃. The results show that the pigments have excellent high-temperature resistance and are expected to be widely used in high-temperature glazing coloration.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"45 3","pages":"Article 116987"},"PeriodicalIF":5.8000,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Novel Co and Cr free, high-temperature black ceramic pigment based on (Ni, Mn) co-doping (CuFe)Fe4O8\",\"authors\":\"Guo Feng , Tiantian Liu , Feng Jiang , Zhiqi Guo , Liangliang Xiao , Qian Wu , Xiaojun Zhang , Qing Hu , Jianmin Liu , Jian Liang\",\"doi\":\"10.1016/j.jeurceramsoc.2024.116987\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Novel Co and Cr free, high-temperature (Ni, Mn) co-doping (CuFe)Fe<sub>4</sub>O<sub>8</sub> black ceramic pigment was synthesized. The results indicate that the brightness (L*) values of the synthesized pigments decrease first, then reach an optimal value, and then increase with the doping amounts increasing of both Ni<sub>2</sub>O<sub>3</sub> and MnO<sub>2</sub>. The optimized Ni<sub>2</sub>O<sub>3</sub> and MnO<sub>2</sub> doping amounts are 0.20 (molar ratio to (CuFe)Fe<sub>4</sub>O<sub>8</sub>) and 0.75 (molar ratio to (CuFe)Fe<sub>4</sub>O<sub>8</sub>), respectively. L*, a* and b* values of the optimized pigment (0.20Ni, 0.75Mn) co-doping (CuFe)Fe<sub>4</sub>O<sub>8</sub> are 21.36, 1.10 and −0.24, respectively. The crystal phase of the optimized pigment is (CuFe)Fe<sub>4</sub>O<sub>8</sub> (JCPDS73–2314). The crystal size of the pigment is 0.8–1.5<em>μ</em>m with excellent dispersivity. The glazing temperatures have little effect on the coloration of the pigment when used at 1000℃, 1150℃ and 1300℃. The results show that the pigments have excellent high-temperature resistance and are expected to be widely used in high-temperature glazing coloration.</div></div>\",\"PeriodicalId\":17408,\"journal\":{\"name\":\"Journal of The European Ceramic Society\",\"volume\":\"45 3\",\"pages\":\"Article 116987\"},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2024-10-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The European Ceramic Society\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0955221924008604\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The European Ceramic Society","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0955221924008604","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Novel Co and Cr free, high-temperature black ceramic pigment based on (Ni, Mn) co-doping (CuFe)Fe4O8
Novel Co and Cr free, high-temperature (Ni, Mn) co-doping (CuFe)Fe4O8 black ceramic pigment was synthesized. The results indicate that the brightness (L*) values of the synthesized pigments decrease first, then reach an optimal value, and then increase with the doping amounts increasing of both Ni2O3 and MnO2. The optimized Ni2O3 and MnO2 doping amounts are 0.20 (molar ratio to (CuFe)Fe4O8) and 0.75 (molar ratio to (CuFe)Fe4O8), respectively. L*, a* and b* values of the optimized pigment (0.20Ni, 0.75Mn) co-doping (CuFe)Fe4O8 are 21.36, 1.10 and −0.24, respectively. The crystal phase of the optimized pigment is (CuFe)Fe4O8 (JCPDS73–2314). The crystal size of the pigment is 0.8–1.5μm with excellent dispersivity. The glazing temperatures have little effect on the coloration of the pigment when used at 1000℃, 1150℃ and 1300℃. The results show that the pigments have excellent high-temperature resistance and are expected to be widely used in high-temperature glazing coloration.
期刊介绍：
The Journal of the European Ceramic Society publishes the results of original research and reviews relating to ceramic materials. Papers of either an experimental or theoretical character will be welcomed on a fully international basis. The emphasis is on novel generic science concerning the relationships between processing, microstructure and properties of polycrystalline ceramics consolidated at high temperature. Papers may relate to any of the conventional categories of ceramic: structural, functional, traditional or composite. The central objective is to sustain a high standard of research quality by means of appropriate reviewing procedures.
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