Yonglei Xing, Huijuan Liu, Yu Ha, Xiaoyong Jin, Beibei Kou, Rui Yang, Gang Ni
{"title":"MnO2/CoMoO4/NF 活化过氧单硫酸盐降解左氧氟沙星","authors":"Yonglei Xing, Huijuan Liu, Yu Ha, Xiaoyong Jin, Beibei Kou, Rui Yang, Gang Ni","doi":"10.1007/s11270-024-07470-1","DOIUrl":null,"url":null,"abstract":"<div><p>MnO<sub>2</sub>/CoMoO<sub>4</sub>/ NF (Nickel foam) was obtained by loading MnO<sub>2</sub> onto the surface of CoMoO<sub>4</sub>/NF using electrodeposition. The results of degradation experiments showed that the degradation efficiency of levofloxacin (LVF) (15 ppm, pH = 6.12) over MnO<sub>2</sub>/CoMoO<sub>4</sub>//NF reached 80.4% in 30 min when the PMS concentration was 0.08 mM. When the pH was lower or higher than the pH value of the original solution, the performance of the material significantly decreased due to the repulsive effect between the catalyst and SO<sub>5</sub><sup>2−</sup>. Cobalt and manganese ions exhibited a synergistic effect on the activation of PMS. The HCO<sub>3</sub><sup>−</sup> ions showed the most significant inhibitory effect on the degradation of LVF. The free radical trapping experiments indicated that ·OH, and O<sub>2</sub><sup><b>·</b>−</sup> were the main active species in the degradation process of levofloxacin. The cyclic stability experiments proved the MnO<sub>2</sub>/CoMoO<sub>4</sub>/NF catalysts were efficient, stable and easy to recover.</p><h3>Graphical Abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"235 12","pages":""},"PeriodicalIF":3.8000,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Peroxymonosulfate Activation by MnO2/CoMoO4/NF for Degradation of Levofloxacin\",\"authors\":\"Yonglei Xing, Huijuan Liu, Yu Ha, Xiaoyong Jin, Beibei Kou, Rui Yang, Gang Ni\",\"doi\":\"10.1007/s11270-024-07470-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>MnO<sub>2</sub>/CoMoO<sub>4</sub>/ NF (Nickel foam) was obtained by loading MnO<sub>2</sub> onto the surface of CoMoO<sub>4</sub>/NF using electrodeposition. The results of degradation experiments showed that the degradation efficiency of levofloxacin (LVF) (15 ppm, pH = 6.12) over MnO<sub>2</sub>/CoMoO<sub>4</sub>//NF reached 80.4% in 30 min when the PMS concentration was 0.08 mM. When the pH was lower or higher than the pH value of the original solution, the performance of the material significantly decreased due to the repulsive effect between the catalyst and SO<sub>5</sub><sup>2−</sup>. Cobalt and manganese ions exhibited a synergistic effect on the activation of PMS. The HCO<sub>3</sub><sup>−</sup> ions showed the most significant inhibitory effect on the degradation of LVF. The free radical trapping experiments indicated that ·OH, and O<sub>2</sub><sup><b>·</b>−</sup> were the main active species in the degradation process of levofloxacin. The cyclic stability experiments proved the MnO<sub>2</sub>/CoMoO<sub>4</sub>/NF catalysts were efficient, stable and easy to recover.</p><h3>Graphical Abstract</h3>\\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":808,\"journal\":{\"name\":\"Water, Air, & Soil Pollution\",\"volume\":\"235 12\",\"pages\":\"\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2024-10-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Water, Air, & Soil Pollution\",\"FirstCategoryId\":\"6\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11270-024-07470-1\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Water, Air, & Soil Pollution","FirstCategoryId":"6","ListUrlMain":"https://link.springer.com/article/10.1007/s11270-024-07470-1","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
Peroxymonosulfate Activation by MnO2/CoMoO4/NF for Degradation of Levofloxacin
MnO2/CoMoO4/ NF (Nickel foam) was obtained by loading MnO2 onto the surface of CoMoO4/NF using electrodeposition. The results of degradation experiments showed that the degradation efficiency of levofloxacin (LVF) (15 ppm, pH = 6.12) over MnO2/CoMoO4//NF reached 80.4% in 30 min when the PMS concentration was 0.08 mM. When the pH was lower or higher than the pH value of the original solution, the performance of the material significantly decreased due to the repulsive effect between the catalyst and SO52−. Cobalt and manganese ions exhibited a synergistic effect on the activation of PMS. The HCO3− ions showed the most significant inhibitory effect on the degradation of LVF. The free radical trapping experiments indicated that ·OH, and O2·− were the main active species in the degradation process of levofloxacin. The cyclic stability experiments proved the MnO2/CoMoO4/NF catalysts were efficient, stable and easy to recover.
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Water, Air, & Soil Pollution is an international, interdisciplinary journal on all aspects of pollution and solutions to pollution in the biosphere. This includes chemical, physical and biological processes affecting flora, fauna, water, air and soil in relation to environmental pollution. Because of its scope, the subject areas are diverse and include all aspects of pollution sources, transport, deposition, accumulation, acid precipitation, atmospheric pollution, metals, aquatic pollution including marine pollution and ground water, waste water, pesticides, soil pollution, sewage, sediment pollution, forestry pollution, effects of pollutants on humans, vegetation, fish, aquatic species, micro-organisms, and animals, environmental and molecular toxicology applied to pollution research, biosensors, global and climate change, ecological implications of pollution and pollution models. Water, Air, & Soil Pollution also publishes manuscripts on novel methods used in the study of environmental pollutants, environmental toxicology, environmental biology, novel environmental engineering related to pollution, biodiversity as influenced by pollution, novel environmental biotechnology as applied to pollution (e.g. bioremediation), environmental modelling and biorestoration of polluted environments.
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Water, Air, & Soil Pollution publishes research papers; review articles; mini-reviews; and book reviews.
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