{"title":"掺杂 Zr 的 Li4Ti5O12 粒子涂有还原氧化石墨烯纳米层,可用作高倍率锂离子电池的负极","authors":"","doi":"10.1016/j.est.2024.114165","DOIUrl":null,"url":null,"abstract":"<div><div>Lithium titanate (Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub>/LTO) has been widely recognized for its superior stability and long cycle life as a negative electrode material for lithium-ion batteries. However, its limited specific capacity and poor rate performance have hindered broader applications. This study introduces an innovative approach to address these limitations by preparing Zr-doped Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub> coated with reduced graphene oxide (rGO) (LTO-0.1Zr@rGO) using a wet chemical method combined with freeze-drying technology. The incorporation of Zr ions into the LTO lattice resulted in an increase in the lattice parameter and the unit cell volume. This increase facilitated the transmission of lithium ions and enhanced the material's conductivity. Furthermore, the rGO coating was found to significantly enhance the rate performance and cycle stability of the material. The LTO-0.1Zr@rGO composite demonstrated a high rate capacity ranging from 396.5 to 263.6 mAh g<sup>−1</sup> at current densities varying from 0.2 to 5.0 A g<sup>−1</sup>, with a stable capacity of 310.2 mAh g<sup>−1</sup> maintained after 1000 cycles at a current density of 1.0 A g<sup>−1</sup>. These results indicate the potential of LTO-0.1Zr@rGO as a promising anode material for high-rate and stable lithium-ion batteries.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":null,"pages":null},"PeriodicalIF":8.9000,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Zr-doped Li4Ti5O12 particles coated with reduced graphene oxide nanolayer as anode for high-rate lithium-ion batteries\",\"authors\":\"\",\"doi\":\"10.1016/j.est.2024.114165\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Lithium titanate (Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub>/LTO) has been widely recognized for its superior stability and long cycle life as a negative electrode material for lithium-ion batteries. However, its limited specific capacity and poor rate performance have hindered broader applications. This study introduces an innovative approach to address these limitations by preparing Zr-doped Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub> coated with reduced graphene oxide (rGO) (LTO-0.1Zr@rGO) using a wet chemical method combined with freeze-drying technology. The incorporation of Zr ions into the LTO lattice resulted in an increase in the lattice parameter and the unit cell volume. This increase facilitated the transmission of lithium ions and enhanced the material's conductivity. Furthermore, the rGO coating was found to significantly enhance the rate performance and cycle stability of the material. The LTO-0.1Zr@rGO composite demonstrated a high rate capacity ranging from 396.5 to 263.6 mAh g<sup>−1</sup> at current densities varying from 0.2 to 5.0 A g<sup>−1</sup>, with a stable capacity of 310.2 mAh g<sup>−1</sup> maintained after 1000 cycles at a current density of 1.0 A g<sup>−1</sup>. These results indicate the potential of LTO-0.1Zr@rGO as a promising anode material for high-rate and stable lithium-ion batteries.</div></div>\",\"PeriodicalId\":15942,\"journal\":{\"name\":\"Journal of energy storage\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":8.9000,\"publicationDate\":\"2024-10-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of energy storage\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2352152X24037514\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of energy storage","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2352152X24037514","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
摘要
钛酸锂(Li4Ti5O12/LTO)作为锂离子电池的负极材料,以其卓越的稳定性和较长的循环寿命而得到广泛认可。然而,其有限的比容量和较差的速率性能阻碍了其更广泛的应用。本研究采用湿化学方法结合冷冻干燥技术制备了掺杂 Zr 的 Li4Ti5O12,并在其表面涂覆了还原型氧化石墨烯(rGO)(LTO-0.1Zr@rGO),从而引入了一种创新方法来解决这些局限性。在 LTO 晶格中加入 Zr 离子后,晶格参数和单胞体积都有所增加。这种增加促进了锂离子的传输并提高了材料的导电性。此外,研究还发现 rGO 涂层能显著提高材料的速率性能和循环稳定性。LTO-0.1Zr@rGO 复合材料在 0.2 至 5.0 A g-1 的电流密度下显示出 396.5 至 263.6 mAh g-1 的高倍率容量,在 1.0 A g-1 的电流密度下循环 1000 次后仍能保持 310.2 mAh g-1 的稳定容量。这些结果表明,LTO-0.1Zr@rGO 有潜力成为高倍率、稳定的锂离子电池负极材料。
Zr-doped Li4Ti5O12 particles coated with reduced graphene oxide nanolayer as anode for high-rate lithium-ion batteries
Lithium titanate (Li4Ti5O12/LTO) has been widely recognized for its superior stability and long cycle life as a negative electrode material for lithium-ion batteries. However, its limited specific capacity and poor rate performance have hindered broader applications. This study introduces an innovative approach to address these limitations by preparing Zr-doped Li4Ti5O12 coated with reduced graphene oxide (rGO) (LTO-0.1Zr@rGO) using a wet chemical method combined with freeze-drying technology. The incorporation of Zr ions into the LTO lattice resulted in an increase in the lattice parameter and the unit cell volume. This increase facilitated the transmission of lithium ions and enhanced the material's conductivity. Furthermore, the rGO coating was found to significantly enhance the rate performance and cycle stability of the material. The LTO-0.1Zr@rGO composite demonstrated a high rate capacity ranging from 396.5 to 263.6 mAh g−1 at current densities varying from 0.2 to 5.0 A g−1, with a stable capacity of 310.2 mAh g−1 maintained after 1000 cycles at a current density of 1.0 A g−1. These results indicate the potential of LTO-0.1Zr@rGO as a promising anode material for high-rate and stable lithium-ion batteries.
期刊介绍:
Journal of energy storage focusses on all aspects of energy storage, in particular systems integration, electric grid integration, modelling and analysis, novel energy storage technologies, sizing and management strategies, business models for operation of storage systems and energy storage developments worldwide.