利用改良化学气相沉积技术直接生长生物石墨烯以实现直接表征

IF 9.7 1区 环境科学与生态学 Q1 AGRICULTURAL ENGINEERING Bioresource Technology Pub Date : 2024-10-15 DOI:10.1016/j.biortech.2024.131637
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引用次数: 0

摘要

油棕壳(OPS)经过加热后会释放出气态化合物。这些化合物沉积在基底上,生成生物石墨烯。通过化学气相沉积 (CVD),生产过程中的生长环境参数对工艺进行了优化。该工艺包括在氧化铝舟的两个不同位置(ABC-1 和 ABC-2)下将气态化合物受控沉积到基底上。直接沉积在硅晶片上省去了蚀刻和转移过程,简化了生物石墨烯的表征。研究人员利用场发射扫描电子显微镜、原子力显微镜、拉曼光谱、X 射线衍射和 I-V 测量来表征生物石墨烯。研究结果表明,封闭性更好的设置(ABC-2)有利于高质量生物石墨烯的生长,具有更好的结晶度、可检测到的生长突增、估计的几层厚度、更大的生长面积和更低的表面粗糙度。在 ABC-2 下优化沉积环境可显著提高来自 OPS 的生物石墨烯的质量和结晶度,为未来的应用铺平道路。
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Direct Growth of Bio-Graphene Using Modified-Chemical Vapor Deposition For Straight-Forward Characterization
Oil Palm Shell (OPS) is subjected to heating, resulting in gaseous compound release. These compounds are deposited on the substrate to produce Bio-Graphene. Through Chemical Vapor Deposition (CVD), the process is optimized by growing environment parameters during the production process. This process involves the controlled deposition of gaseous compounds onto a substrate under two different positions of the alumina boat (ABC-1 and ABC-2). Direct deposition on silicon wafers eliminated etching and transfer sequences, simplifying Bio-Graphene characterization. Field Emission Scanning Electron Microscope, Atomic Force Microscope, Raman Spectroscopy, X-ray diffraction, and I-V measurement were employed to characterize the Bio-Graphene. The findings revealed that the better-closed settings (ABC-2) facilitated the growth of high-quality Bio-Graphene with better crystallinity, detectable growth spurt, estimated few-layer thickness, larger growth area, and lower surface roughness. Optimizing the deposition environment at ABC-2 significantly enhances the quality and crystallinity of Bio-Graphene from OPS, paving the way for future applications.
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来源期刊
Bioresource Technology
Bioresource Technology 工程技术-能源与燃料
CiteScore
20.80
自引率
19.30%
发文量
2013
审稿时长
12 days
期刊介绍: Bioresource Technology publishes original articles, review articles, case studies, and short communications covering the fundamentals, applications, and management of bioresource technology. The journal seeks to advance and disseminate knowledge across various areas related to biomass, biological waste treatment, bioenergy, biotransformations, bioresource systems analysis, and associated conversion or production technologies. Topics include: • Biofuels: liquid and gaseous biofuels production, modeling and economics • Bioprocesses and bioproducts: biocatalysis and fermentations • Biomass and feedstocks utilization: bioconversion of agro-industrial residues • Environmental protection: biological waste treatment • Thermochemical conversion of biomass: combustion, pyrolysis, gasification, catalysis.
期刊最新文献
Simultaneous CO2 and biogas slurry treatment using a newly isolated microalga with high CO2 tolerance Maximization of Micractinium sp., biomass and use of Dual-Purpose reduced graphene supported vanadium oxide nanoparticles for harvesting and subsequent biodiesel production Advanced bacteria-based biomaterials for environmental applications Unique ecology of biofilms and flocs: Bacterial composition, assembly, interaction, and nitrogen metabolism within deteriorated bioreactor inoculated with mature partial nitrification-anammox sludge Direct Growth of Bio-Graphene Using Modified-Chemical Vapor Deposition For Straight-Forward Characterization
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