{"title":"基于 BODIPY 的荧光传感器材料对空气中的丙酮和苯具有聚集驱动选择性","authors":"Alexander Bobrov , Sergey Usoltsev , Natalya Moleva , Yuriy Marfin","doi":"10.1016/j.optmat.2024.116267","DOIUrl":null,"url":null,"abstract":"<div><div>Paper highlights advances in design of fluorescent sensors for solvent vapors with boron-dipyrromethene (BODIPY) as a model active component. The present study demonstrates that BODIPY-based fluorescent materials could be successfully utilized for detection of benzene and acetone in gas phase. Concentration of luminophore was found to affect sensory response to benzene (up to 3-fold increase in adjusted conditions). At the same time, sensory response to acetone is concentration-independent, suggesting different underlying response mechanisms and allowing to tune selectivity with choice of concentration. Detection limits achieved for sensory materials are 1.2<strong>·</strong>10<sup>4</sup> mg/m<sup>3</sup> for acetone and 0.94<strong>·</strong>10<sup>4</sup> mg/m<sup>3</sup> for benzene. Ultimately, obtained sensor materials could be completely regenerated without need for inert gas purge.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"157 ","pages":"Article 116267"},"PeriodicalIF":3.8000,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"BODIPY-based fluorescent sensor material for airborne acetone and benzene with aggregation-driven selectivity\",\"authors\":\"Alexander Bobrov , Sergey Usoltsev , Natalya Moleva , Yuriy Marfin\",\"doi\":\"10.1016/j.optmat.2024.116267\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Paper highlights advances in design of fluorescent sensors for solvent vapors with boron-dipyrromethene (BODIPY) as a model active component. The present study demonstrates that BODIPY-based fluorescent materials could be successfully utilized for detection of benzene and acetone in gas phase. Concentration of luminophore was found to affect sensory response to benzene (up to 3-fold increase in adjusted conditions). At the same time, sensory response to acetone is concentration-independent, suggesting different underlying response mechanisms and allowing to tune selectivity with choice of concentration. Detection limits achieved for sensory materials are 1.2<strong>·</strong>10<sup>4</sup> mg/m<sup>3</sup> for acetone and 0.94<strong>·</strong>10<sup>4</sup> mg/m<sup>3</sup> for benzene. Ultimately, obtained sensor materials could be completely regenerated without need for inert gas purge.</div></div>\",\"PeriodicalId\":19564,\"journal\":{\"name\":\"Optical Materials\",\"volume\":\"157 \",\"pages\":\"Article 116267\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2024-10-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Optical Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0925346724014502\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Optical Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0925346724014502","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
BODIPY-based fluorescent sensor material for airborne acetone and benzene with aggregation-driven selectivity
Paper highlights advances in design of fluorescent sensors for solvent vapors with boron-dipyrromethene (BODIPY) as a model active component. The present study demonstrates that BODIPY-based fluorescent materials could be successfully utilized for detection of benzene and acetone in gas phase. Concentration of luminophore was found to affect sensory response to benzene (up to 3-fold increase in adjusted conditions). At the same time, sensory response to acetone is concentration-independent, suggesting different underlying response mechanisms and allowing to tune selectivity with choice of concentration. Detection limits achieved for sensory materials are 1.2·104 mg/m3 for acetone and 0.94·104 mg/m3 for benzene. Ultimately, obtained sensor materials could be completely regenerated without need for inert gas purge.
期刊介绍：
Optical Materials has an open access mirror journal Optical Materials: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
The purpose of Optical Materials is to provide a means of communication and technology transfer between researchers who are interested in materials for potential device applications. The journal publishes original papers and review articles on the design, synthesis, characterisation and applications of optical materials.
OPTICAL MATERIALS focuses on:
• Optical Properties of Material Systems;
• The Materials Aspects of Optical Phenomena;
• The Materials Aspects of Devices and Applications.
Authors can submit separate research elements describing their data to Data in Brief and methods to Methods X.
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