各种烯丙基化剂对醛的烯丙基化作用

IF 2.5 Q2 CHEMISTRY, MULTIDISCIPLINARY Results in Chemistry Pub Date : 2024-10-01 DOI:10.1016/j.rechem.2024.101847
Yavar Ahmadi
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引用次数: 0

摘要

醛的烯丙基化是最重要的有机转化之一,有助于合成具有特殊骨架和独特药用性质的化合物。从 2001 年到 2024 年,人们使用不同的催化剂在这一领域进行了广泛的研究,这一有机技术正日趋成熟。大多数研究都是基于使用不同催化剂和各种配体来获得最大的非对映选择性和对映选择性。在本综述中,我们总结了使用各种烯丙基化剂对醛进行烯丙基化的最新研究,包括醋酸烯丙基酯、三氯硅烷烯丙基酯、三丁基锡烯丙基酯、烯丙基溴化物、烯丙基氯化物、环烯丙基卤化物和烯丙基硼酸频哪醇酯。此外,我们还回顾了 2001 年至今的研究。本综述的主要重点是该领域的总体进展。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Allylation of aldehydes with various allylation agents
Allylation of aldehydes is one of the most important organic transformations that helps in the synthesis of compounds with special skeletons with unique medicinal properties. From 2001 to 2024, extensive research has been done in this field using different catalysts, and this organic technology is maturing. Most of the studies are based on the use of different catalysts and various ligands to obtain maximum diastereoselectivity and enantioselectivity. In this review, we have summarized recent research on the allylation of aldehydes using various allylation agents, including allyl acetate, allyl trichlorosilane, allyltributyltin, allylbromides, allylchlorides, cyclic allylic halides, and allylboronic acid pinacol ester. Additionally, we have reviewed studies from 2001 to the present. The primary focus of this review is the overall progress in this field.
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来源期刊
Results in Chemistry
Results in Chemistry Chemistry-Chemistry (all)
CiteScore
2.70
自引率
8.70%
发文量
380
审稿时长
56 days
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