利用 EDS/EDX 评估水源中的重金属污染

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摘要

研究的目的是评估砖窑在印度旁遮普邦水体重金属污染中的作用。能量色散 X 射线光谱仪(EDS/EDX)有效地检测了水样中的重金属。研究结果表明,砖窑附近的地表水广泛受到重金属污染。其污染负荷指数(PLI)值介于 2.83 和 52.98 之间,污染程度为 "逐渐恶化"。地下水的污染负荷指数值介于 0.089 和 3.68 之间,污染程度从 "污染物基线水平 "到 "逐步恶化 "不等。总体而言,研究区域地下水的 PLI 值为 0.477(污染物基准水平),而地表水的 PLI 值为 11.453(逐步恶化)。地下水的水质指数(WQI)受重金属影响很大,特别是来自岩层的砷(As)和来自砖窑燃料燃烧的铅(Pb)。从高到低的顺序依次是铅>锌>砷>铬>镍,相关矩阵表明,重金属的存在与 PLI 和 WQI 值相关。因此,有证据表明砖窑对水体造成了重金属污染。EDS 被证明是评估水中化学元素的仪器之一。建议执行关于使用生物质的法律,以减少烧砖时使用的大量煤炭。
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Use of EDS/EDX to evaluate heavy metals pollution in water sources
The objective of the study was to evaluate the role of brick kilns in contaminating water bodies with heavy metals in Punjab, India. The energy-dispersive x-ray spectroscopy (EDS/EDX) machine effectively tested heavy metals in water samples. The research revealed that the surface water near the brick kilns was extensively polluted with heavy metals. Their Pollution Load Index (PLI) values varied between 2.83 and 52.98, and their degree of contamination was “Progressive deterioration”. The PLI values for groundwater ranged between 0.089 and 3.68, and the degree of contamination varied from “Baseline levels of pollutants” to “Progressive deterioration”. In general, the groundwater of the studied area had a PLI value of 0.477 (Baseline levels of pollutants), whereas the surface water had a PLI value of 11.453 (Progressive deterioration). The Water Quality Index (WQI) of groundwater was highly influenced by heavy metals, notably Arsenic (As) from lithologic origins, and Lead (Pb) from the burning of fuels in the brick kilns. In descending order, Pb>Zn>As>Cr>Ni metals were influencing the PLI, and the correlation matrixes demonstrated that the presence of heavy metals was associated with the PLI and WQI values. Therefore, there is evidence that brick kilns are polluting water bodies with heavy metals. EDS proved to be one of the instruments to evaluate the chemical elements in water. It was recommended to enforce the law governing the use of biomass to reduce vast quantities of coal used in baking bricks.
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