{"title":"基于三种传质模型的微通道液-液萃取机理及强化方案的 CFD 仿真","authors":"","doi":"10.1016/j.cherd.2024.09.042","DOIUrl":null,"url":null,"abstract":"<div><div>Microreactors are highly efficient devices with a large specific surface area to improve the mass transfer efficiency. In this paper, a comprehensive three-dimensional CFD model was constructed based on three mass transfer theories to simulate the liquid-liquid two-phase flow and mass transfer process in a microchannel reactor, and two enhancement schemes were proposed. The multiphase flow and mass transfer characteristics were investigated by visualization and extraction experiments. The results indicated that the extraction efficiencies (<em>E</em>) and overall mass transfer coefficients (<span><math><mrow><msub><mrow><mi>K</mi></mrow><mrow><mi>L</mi></mrow></msub><mi>a</mi></mrow></math></span>) calculated by the penetration model and surface renewal model were within <span><math><mo>±</mo></math></span>15 % errors compared to the experimental values. Moreover, <em>E</em> primarily increases with the increase of fluid residence time, while <span><math><mrow><msub><mrow><mi>K</mi></mrow><mrow><mi>L</mi></mrow></msub><mi>a</mi></mrow></math></span> increases with increasing flow rate. As the flow rate increases from 0.3 ml/min to 1.5 ml/min, <em>E</em> decreases by 15 %, and <span><math><mrow><msub><mrow><mi>K</mi></mrow><mrow><mi>L</mi></mrow></msub><mi>a</mi></mrow></math></span> rises from 0.78 s⁻¹ to 2.65 s⁻¹. Whereas the channel width decreases from 0.8 mm to 0.3 mm, <em>E</em> decreases by 3 %, and <span><math><mrow><msub><mrow><mi>K</mi></mrow><mrow><mi>L</mi></mrow></msub><mi>a</mi></mrow></math></span> rises from 0.44 s⁻¹ to 2.77 s⁻¹. Finally, microchannel with necked structure and baffles in mixing zone both improve the mass transfer efficient to some extent.</div></div>","PeriodicalId":10019,"journal":{"name":"Chemical Engineering Research & Design","volume":null,"pages":null},"PeriodicalIF":3.7000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"CFD simulation of liquid-liquid extraction mechanism and enhancement schemes in microchannels based on three mass transfer models\",\"authors\":\"\",\"doi\":\"10.1016/j.cherd.2024.09.042\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Microreactors are highly efficient devices with a large specific surface area to improve the mass transfer efficiency. In this paper, a comprehensive three-dimensional CFD model was constructed based on three mass transfer theories to simulate the liquid-liquid two-phase flow and mass transfer process in a microchannel reactor, and two enhancement schemes were proposed. The multiphase flow and mass transfer characteristics were investigated by visualization and extraction experiments. The results indicated that the extraction efficiencies (<em>E</em>) and overall mass transfer coefficients (<span><math><mrow><msub><mrow><mi>K</mi></mrow><mrow><mi>L</mi></mrow></msub><mi>a</mi></mrow></math></span>) calculated by the penetration model and surface renewal model were within <span><math><mo>±</mo></math></span>15 % errors compared to the experimental values. Moreover, <em>E</em> primarily increases with the increase of fluid residence time, while <span><math><mrow><msub><mrow><mi>K</mi></mrow><mrow><mi>L</mi></mrow></msub><mi>a</mi></mrow></math></span> increases with increasing flow rate. As the flow rate increases from 0.3 ml/min to 1.5 ml/min, <em>E</em> decreases by 15 %, and <span><math><mrow><msub><mrow><mi>K</mi></mrow><mrow><mi>L</mi></mrow></msub><mi>a</mi></mrow></math></span> rises from 0.78 s⁻¹ to 2.65 s⁻¹. Whereas the channel width decreases from 0.8 mm to 0.3 mm, <em>E</em> decreases by 3 %, and <span><math><mrow><msub><mrow><mi>K</mi></mrow><mrow><mi>L</mi></mrow></msub><mi>a</mi></mrow></math></span> rises from 0.44 s⁻¹ to 2.77 s⁻¹. Finally, microchannel with necked structure and baffles in mixing zone both improve the mass transfer efficient to some extent.</div></div>\",\"PeriodicalId\":10019,\"journal\":{\"name\":\"Chemical Engineering Research & Design\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2024-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Engineering Research & Design\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0263876224005744\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Engineering Research & Design","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0263876224005744","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
CFD simulation of liquid-liquid extraction mechanism and enhancement schemes in microchannels based on three mass transfer models
Microreactors are highly efficient devices with a large specific surface area to improve the mass transfer efficiency. In this paper, a comprehensive three-dimensional CFD model was constructed based on three mass transfer theories to simulate the liquid-liquid two-phase flow and mass transfer process in a microchannel reactor, and two enhancement schemes were proposed. The multiphase flow and mass transfer characteristics were investigated by visualization and extraction experiments. The results indicated that the extraction efficiencies (E) and overall mass transfer coefficients () calculated by the penetration model and surface renewal model were within 15 % errors compared to the experimental values. Moreover, E primarily increases with the increase of fluid residence time, while increases with increasing flow rate. As the flow rate increases from 0.3 ml/min to 1.5 ml/min, E decreases by 15 %, and rises from 0.78 s⁻¹ to 2.65 s⁻¹. Whereas the channel width decreases from 0.8 mm to 0.3 mm, E decreases by 3 %, and rises from 0.44 s⁻¹ to 2.77 s⁻¹. Finally, microchannel with necked structure and baffles in mixing zone both improve the mass transfer efficient to some extent.
期刊介绍:
ChERD aims to be the principal international journal for publication of high quality, original papers in chemical engineering.
Papers showing how research results can be used in chemical engineering design, and accounts of experimental or theoretical research work bringing new perspectives to established principles, highlighting unsolved problems or indicating directions for future research, are particularly welcome. Contributions that deal with new developments in plant or processes and that can be given quantitative expression are encouraged. The journal is especially interested in papers that extend the boundaries of traditional chemical engineering.