{"title":"用于降解四环素的 CaCO3 活性掺氮硅藻生物炭","authors":"","doi":"10.1016/j.molliq.2024.126260","DOIUrl":null,"url":null,"abstract":"<div><div>In this study, a N-doped diatom biochar (DBC) was prepared by one-step pyrolysis, where CaCO<sub>3</sub> formed by marine diatom-mediated calcification was employed as an activator. Due to the activation effect of CaCO<sub>3</sub>, the specific surface area of the obtained DBC increased by more than 10 times, and the nitrogen presented as pyrrolic nitrogen (58.9%), pyridinic nitrogen (29.7%), and graphitic nitrogen (11.4%) in the DBC. In addition, the effects of important parameters and co-existing ions on the catalytic decomposition of tetracycline (TC) by DBC were investigated by using TC as a typical pollutant and PDS as an oxidant. The DBC/PDS system exhibited high activity over a broad pH range. Through radical scavenging experiments, electron spin resonance, and electrochemical results analysis, it was found that the degradation of TC in the system included both radical and nonradical pathways, and the most dominant reactive species was <sup>1</sup>O<sub>2</sub>. Furthermore, the surficial reactive complexes formed by PDS on the catalysts also played an important role in attacking the adsorbed TC molecules. This study proposes an eco-friendly and economical technique to construct a clean advanced oxidation process capable of treating TC wastewater by utilizing the native biomass of diatom as a metal-free and efficient biochar catalyst while simultaneously reducing the use of chemical reagents.</div></div>","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":null,"pages":null},"PeriodicalIF":5.3000,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"CaCO3-activited N-doped diatom biochar for the degradation of tetracycline\",\"authors\":\"\",\"doi\":\"10.1016/j.molliq.2024.126260\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this study, a N-doped diatom biochar (DBC) was prepared by one-step pyrolysis, where CaCO<sub>3</sub> formed by marine diatom-mediated calcification was employed as an activator. Due to the activation effect of CaCO<sub>3</sub>, the specific surface area of the obtained DBC increased by more than 10 times, and the nitrogen presented as pyrrolic nitrogen (58.9%), pyridinic nitrogen (29.7%), and graphitic nitrogen (11.4%) in the DBC. In addition, the effects of important parameters and co-existing ions on the catalytic decomposition of tetracycline (TC) by DBC were investigated by using TC as a typical pollutant and PDS as an oxidant. The DBC/PDS system exhibited high activity over a broad pH range. Through radical scavenging experiments, electron spin resonance, and electrochemical results analysis, it was found that the degradation of TC in the system included both radical and nonradical pathways, and the most dominant reactive species was <sup>1</sup>O<sub>2</sub>. Furthermore, the surficial reactive complexes formed by PDS on the catalysts also played an important role in attacking the adsorbed TC molecules. This study proposes an eco-friendly and economical technique to construct a clean advanced oxidation process capable of treating TC wastewater by utilizing the native biomass of diatom as a metal-free and efficient biochar catalyst while simultaneously reducing the use of chemical reagents.</div></div>\",\"PeriodicalId\":371,\"journal\":{\"name\":\"Journal of Molecular Liquids\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2024-10-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Molecular Liquids\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0167732224023195\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Molecular Liquids","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167732224023195","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
CaCO3-activited N-doped diatom biochar for the degradation of tetracycline
In this study, a N-doped diatom biochar (DBC) was prepared by one-step pyrolysis, where CaCO3 formed by marine diatom-mediated calcification was employed as an activator. Due to the activation effect of CaCO3, the specific surface area of the obtained DBC increased by more than 10 times, and the nitrogen presented as pyrrolic nitrogen (58.9%), pyridinic nitrogen (29.7%), and graphitic nitrogen (11.4%) in the DBC. In addition, the effects of important parameters and co-existing ions on the catalytic decomposition of tetracycline (TC) by DBC were investigated by using TC as a typical pollutant and PDS as an oxidant. The DBC/PDS system exhibited high activity over a broad pH range. Through radical scavenging experiments, electron spin resonance, and electrochemical results analysis, it was found that the degradation of TC in the system included both radical and nonradical pathways, and the most dominant reactive species was 1O2. Furthermore, the surficial reactive complexes formed by PDS on the catalysts also played an important role in attacking the adsorbed TC molecules. This study proposes an eco-friendly and economical technique to construct a clean advanced oxidation process capable of treating TC wastewater by utilizing the native biomass of diatom as a metal-free and efficient biochar catalyst while simultaneously reducing the use of chemical reagents.
期刊介绍:
The journal includes papers in the following areas:
– Simple organic liquids and mixtures
– Ionic liquids
– Surfactant solutions (including micelles and vesicles) and liquid interfaces
– Colloidal solutions and nanoparticles
– Thermotropic and lyotropic liquid crystals
– Ferrofluids
– Water, aqueous solutions and other hydrogen-bonded liquids
– Lubricants, polymer solutions and melts
– Molten metals and salts
– Phase transitions and critical phenomena in liquids and confined fluids
– Self assembly in complex liquids.– Biomolecules in solution
The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include:
– Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.)
– Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.)
– Light scattering (Rayleigh, Brillouin, PCS, etc.)
– Dielectric relaxation
– X-ray and neutron scattering and diffraction.
Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.