{"title":"构建 COF/COF 有机 S-Scheme 异质结构以提高整体水分离效果","authors":"Bing-Bing Luan, Xiaoyu Chu, Ya Wang, Xiu Qiao, Yanxia Jiang, Feng-Ming Zhang","doi":"10.1002/adma.202412653","DOIUrl":null,"url":null,"abstract":"Covalent organic frameworks (COFs) as a new type of photocatalysts have shown unique advantages in visible-light-driven hydrogen evolution, while the reported overall water-splitting systems are still very rare among various COF-based photocatalysts. Herein, two COFs are integrated to construct a type of organic S-scheme heterojunction for improved overall water splitting. In this system, TpBpy-COF and COF-316 serve as H<sub>2</sub>- and O<sub>2</sub>-evolving components, respectively, which are combined through π–π interaction between conjugated aromatic rings. By introducing ultra-small Pt nanoparticles (NPs) into the pores of the TpBpy-COF nanosheets (NS), the resultant COF-316/Pt@TpBpy-COF NS heterostructure achieves extremely high H<sub>2</sub> and O<sub>2</sub> evolution rates of 220.4 and 110.2 µmol g<sup>−1</sup> h<sup>−1</sup>, respectively, under visible light irradiation (<i>λ</i> ≥ 420 nm). The results of transient absorption spectra (TAS) and photoelectronic measurements indicate that the organic heterojunction interface notably facilitates the separation and transfer of photogenerated electron-hole pairs. Further, theoretical calculations and in situ experiments confirm the spontaneous formation of the COF/COF heterojunction interface and the active sites for overall water splitting.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":null,"pages":null},"PeriodicalIF":27.4000,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Construction of COF/COF Organic S-Scheme Heterostructure for Enhanced Overall Water Splitting\",\"authors\":\"Bing-Bing Luan, Xiaoyu Chu, Ya Wang, Xiu Qiao, Yanxia Jiang, Feng-Ming Zhang\",\"doi\":\"10.1002/adma.202412653\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Covalent organic frameworks (COFs) as a new type of photocatalysts have shown unique advantages in visible-light-driven hydrogen evolution, while the reported overall water-splitting systems are still very rare among various COF-based photocatalysts. Herein, two COFs are integrated to construct a type of organic S-scheme heterojunction for improved overall water splitting. In this system, TpBpy-COF and COF-316 serve as H<sub>2</sub>- and O<sub>2</sub>-evolving components, respectively, which are combined through π–π interaction between conjugated aromatic rings. By introducing ultra-small Pt nanoparticles (NPs) into the pores of the TpBpy-COF nanosheets (NS), the resultant COF-316/Pt@TpBpy-COF NS heterostructure achieves extremely high H<sub>2</sub> and O<sub>2</sub> evolution rates of 220.4 and 110.2 µmol g<sup>−1</sup> h<sup>−1</sup>, respectively, under visible light irradiation (<i>λ</i> ≥ 420 nm). The results of transient absorption spectra (TAS) and photoelectronic measurements indicate that the organic heterojunction interface notably facilitates the separation and transfer of photogenerated electron-hole pairs. Further, theoretical calculations and in situ experiments confirm the spontaneous formation of the COF/COF heterojunction interface and the active sites for overall water splitting.\",\"PeriodicalId\":114,\"journal\":{\"name\":\"Advanced Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":27.4000,\"publicationDate\":\"2024-10-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1002/adma.202412653\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adma.202412653","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Construction of COF/COF Organic S-Scheme Heterostructure for Enhanced Overall Water Splitting
Covalent organic frameworks (COFs) as a new type of photocatalysts have shown unique advantages in visible-light-driven hydrogen evolution, while the reported overall water-splitting systems are still very rare among various COF-based photocatalysts. Herein, two COFs are integrated to construct a type of organic S-scheme heterojunction for improved overall water splitting. In this system, TpBpy-COF and COF-316 serve as H2- and O2-evolving components, respectively, which are combined through π–π interaction between conjugated aromatic rings. By introducing ultra-small Pt nanoparticles (NPs) into the pores of the TpBpy-COF nanosheets (NS), the resultant COF-316/Pt@TpBpy-COF NS heterostructure achieves extremely high H2 and O2 evolution rates of 220.4 and 110.2 µmol g−1 h−1, respectively, under visible light irradiation (λ ≥ 420 nm). The results of transient absorption spectra (TAS) and photoelectronic measurements indicate that the organic heterojunction interface notably facilitates the separation and transfer of photogenerated electron-hole pairs. Further, theoretical calculations and in situ experiments confirm the spontaneous formation of the COF/COF heterojunction interface and the active sites for overall water splitting.
期刊介绍:
Advanced Materials, one of the world's most prestigious journals and the foundation of the Advanced portfolio, is the home of choice for best-in-class materials science for more than 30 years. Following this fast-growing and interdisciplinary field, we are considering and publishing the most important discoveries on any and all materials from materials scientists, chemists, physicists, engineers as well as health and life scientists and bringing you the latest results and trends in modern materials-related research every week.