室温紫外线照射下用于超灵敏二氧化氮传感的 ZIF-8 衍生 In2O3-ZnO 纳米复合材料的制备与应用

IF 8 1区 化学 Q1 CHEMISTRY, ANALYTICAL Sensors and Actuators B: Chemical Pub Date : 2024-10-18 DOI:10.1016/j.snb.2024.136802
Xingyu Kang, Jianhui Lv, Lei Han, Bin Huang, Huizhang Zhao, Dong Wang, Hairui Fang
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摘要

氮氧化物(NO2)是工业生产中常见的副产品,对工人的健康构成重大威胁。因此,对二氧化氮进行实时监测至关重要。本研究通过电纺丝将 In2O3 与 ZIF-8 结合在一起,制备了创新的 In2O3-ZnO 纳米材料,用于在室温(RT)下检测痕量 NO2。与纯 In2O3 相比,含有 10% 重量比 ZIF-8 的 In2O3-ZnO 纳米材料(V2)在室温紫外线(UV)照射下对 NO2 的响应明显更高(389.99),响应时间更快(16.9 秒)。V2 纳米材料优异的气体传感性能归功于 n-n 异质结的形成、光吸收的增强、氧空位率的提高以及纳米材料之间良好的分散性。研究结果表明,V2 纳米材料能在实时环境中检测到十亿分之一(ppb)水平的二氧化氮,因此适用于监测开放环境中的痕量二氧化氮。此外,还利用 V2 作为传感材料、基于 LM358 的放大电路(用于数据采集)、STM32F103C8T6 微控制器作为主控单元以及蜂鸣器作为报警装置,构建了一个便携式 NO2 实时监测装置。与使用螺旋镍铬丝作为间接热源的设备相比,这种集成式二氧化氮检测设备能以更低的能耗提供实时报警。这一应用不仅提高了工业环境中工人的健康和安全,而且在实际应用中体现了更高的能效。
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Fabrication and Application of ZIF-8 Derived In2O3-ZnO Nanocomposites for Ultra-Sensitive NO2 Sensing under UV Irradiation at Room Temperature
Nitrogen oxide (NO2) is common by-products of industrial production, posing significant health risks to workers. Therefore, real-time monitoring of NO2 is crucial. In this study, innovative In2O3-ZnO nano-materials were prepared by combining In2O3 with ZIF-8 via electrospinning, for detecting trace amounts of NO2 at room temperature (RT). Compared to pure In2O3, the In2O3-ZnO nano-materials (V2) with a 10% weight ratio of ZIF-8 exhibited a significantly higher response (389.99) and a faster response time (16.9 s) to NO2 under ultraviolet (UV) irradiation at RT. The superior gas sensing performance of the V2 nano-materials is attributed to the formation of n-n heterojunctions, enhanced optical absorption, increased oxygen vacancy ratio, and excellent dispersion among the nano-materials. The results demonstrate that V2 nano-materials can detect NO2 at parts-per-billion (ppb) levels at RT, making them suitable for monitoring trace amounts of NO2 in open environments. Furthermore, a portable real-time NO2 monitoring device was constructed using V2 as the sensing material, an LM358-based amplifier circuit for data acquisition, an STM32F103C8T6 microcontroller as the main control unit, and a buzzer as an alarm device. Compared to devices using a helical Ni-Cr wire as an indirect heat source, this integrated NO2 detection device offers real-time alarms with lower energy consumption. This application not only enhances worker health and safety in industrial environments but also demonstrates higher energy efficiency in practical application.
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来源期刊
Sensors and Actuators B: Chemical
Sensors and Actuators B: Chemical 工程技术-电化学
CiteScore
14.60
自引率
11.90%
发文量
1776
审稿时长
3.2 months
期刊介绍: Sensors & Actuators, B: Chemical is an international journal focused on the research and development of chemical transducers. It covers chemical sensors and biosensors, chemical actuators, and analytical microsystems. The journal is interdisciplinary, aiming to publish original works showcasing substantial advancements beyond the current state of the art in these fields, with practical applicability to solving meaningful analytical problems. Review articles are accepted by invitation from an Editor of the journal.
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