{"title":"热压烧结法制备 Mo25ZrB2 金属陶瓷及其静态氧化行为","authors":"Zhenjie Sun","doi":"10.1134/S106782122460008X","DOIUrl":null,"url":null,"abstract":"<p>In this paper, a kind of cermet with Mo25ZrB<sub>2</sub> component was prepared by hot pressing sintering method, and its phase composition and mechanical properties were characterized. The characteristics show that after hot pressing sintering, Mo metal and ZrB<sub>2</sub> ceramic react to generate a certain amount of MoB, which makes the powder bond closely, the bending strength is close to 250 MPa, and the fracture toughness is close to the fracture toughness of the casting die H13. In addition, the static oxidation behavior of the material at different temperatures was also characterized. The experimental results show that the composite with ZrB<sub>2</sub> ceramic powder can overcome the problem of melting failure of Mo matrix at 800°C. The results of static oxidation at 800°C show that the oxidation of Mo matrix is not obvious. This shows that the compound of ZrB<sub>2</sub> effectively protects the Mo matrix and makes the Mo matrix reach a higher operating temperature. The oxidation behavior at 1000°C also showed that zirconium boride would still combine with high temperature oxygen and consume it in the first step, which played a protective role on Mo matrix. This shows that the material still has good application potential at higher temperatures.</p>","PeriodicalId":765,"journal":{"name":"Russian Journal of Non-Ferrous Metals","volume":"64 4-6","pages":"25 - 30"},"PeriodicalIF":0.6000,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of Mo25ZrB2 Cermet by Hot Pressing Sintering and Its Static Oxidation Behavior\",\"authors\":\"Zhenjie Sun\",\"doi\":\"10.1134/S106782122460008X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In this paper, a kind of cermet with Mo25ZrB<sub>2</sub> component was prepared by hot pressing sintering method, and its phase composition and mechanical properties were characterized. The characteristics show that after hot pressing sintering, Mo metal and ZrB<sub>2</sub> ceramic react to generate a certain amount of MoB, which makes the powder bond closely, the bending strength is close to 250 MPa, and the fracture toughness is close to the fracture toughness of the casting die H13. In addition, the static oxidation behavior of the material at different temperatures was also characterized. The experimental results show that the composite with ZrB<sub>2</sub> ceramic powder can overcome the problem of melting failure of Mo matrix at 800°C. The results of static oxidation at 800°C show that the oxidation of Mo matrix is not obvious. This shows that the compound of ZrB<sub>2</sub> effectively protects the Mo matrix and makes the Mo matrix reach a higher operating temperature. The oxidation behavior at 1000°C also showed that zirconium boride would still combine with high temperature oxygen and consume it in the first step, which played a protective role on Mo matrix. This shows that the material still has good application potential at higher temperatures.</p>\",\"PeriodicalId\":765,\"journal\":{\"name\":\"Russian Journal of Non-Ferrous Metals\",\"volume\":\"64 4-6\",\"pages\":\"25 - 30\"},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2024-10-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Non-Ferrous Metals\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S106782122460008X\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Non-Ferrous Metals","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S106782122460008X","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
引用次数: 0
摘要
本文采用热压烧结法制备了一种含 Mo25ZrB2 成分的金属陶瓷,并对其相组成和力学性能进行了表征。特性表明,热压烧结后,金属 Mo 与 ZrB2 陶瓷反应生成一定量的 MoB,使粉末结合紧密,抗弯强度接近 250 MPa,断裂韧性接近铸造模具 H13 的断裂韧性。此外,还对材料在不同温度下的静态氧化行为进行了表征。实验结果表明,含有 ZrB2 陶瓷粉的复合材料可以克服 Mo 基体在 800°C 时熔化失效的问题。800°C 静态氧化的结果表明,Mo 基体的氧化并不明显。这表明 ZrB2 的化合物有效地保护了 Mo 基体,并使 Mo 基体达到了更高的工作温度。1000°C 时的氧化行为也表明,硼化锆仍会与高温氧结合,并在第一步消耗掉高温氧,这对 Mo 基体起到了保护作用。这表明该材料在更高温度下仍具有良好的应用潜力。
Preparation of Mo25ZrB2 Cermet by Hot Pressing Sintering and Its Static Oxidation Behavior
In this paper, a kind of cermet with Mo25ZrB2 component was prepared by hot pressing sintering method, and its phase composition and mechanical properties were characterized. The characteristics show that after hot pressing sintering, Mo metal and ZrB2 ceramic react to generate a certain amount of MoB, which makes the powder bond closely, the bending strength is close to 250 MPa, and the fracture toughness is close to the fracture toughness of the casting die H13. In addition, the static oxidation behavior of the material at different temperatures was also characterized. The experimental results show that the composite with ZrB2 ceramic powder can overcome the problem of melting failure of Mo matrix at 800°C. The results of static oxidation at 800°C show that the oxidation of Mo matrix is not obvious. This shows that the compound of ZrB2 effectively protects the Mo matrix and makes the Mo matrix reach a higher operating temperature. The oxidation behavior at 1000°C also showed that zirconium boride would still combine with high temperature oxygen and consume it in the first step, which played a protective role on Mo matrix. This shows that the material still has good application potential at higher temperatures.
期刊介绍:
Russian Journal of Non-Ferrous Metals is a journal the main goal of which is to achieve new knowledge in the following topics: extraction metallurgy, hydro- and pirometallurgy, casting, plastic deformation, metallography and heat treatment, powder metallurgy and composites, self-propagating high-temperature synthesis, surface engineering and advanced protected coatings, environments, and energy capacity in non-ferrous metallurgy.