{"title":"La3+、Eu3+ 和 Sm3+ 离子对 RE1.90Y0.10Zr2O7（RE：Eu、Sm，Y：La、Sm、Eu）热沸石基多功能智能先进材料的光致发光和压电行为的影响研究","authors":"Esra Öztürk, Nilgun Kalaycioglu Ozpozan, Volkan Kalem","doi":"10.1002/bio.4925","DOIUrl":null,"url":null,"abstract":"<p>A series of compounds with the general formula RE<sub>1.90</sub>Y<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub> (where RE includes Eu, Sm and Y includes La, Sm, Eu) were synthesized using a solid-state reaction method. These compounds were analyzed through differential thermal analysis (DTA), thermogravimetric analysis (TG), X-ray powder diffraction (XRD), and scanning electron microscopy (SEM). Additionally, their dielectric constant, loss tangent, piezoelectric charge constant, and Curie temperature were measured using an LCR meter, d<sub>33</sub> meter, and TG/DTA. X-ray diffraction results indicated that all samples crystallize in a cubic pyrochlore structure. Photoluminescence studies revealed that Eu<sup>3+</sup> ions predominantly contribute to the emission, whether as activators or co-activators. Among the phosphors, Eu<sub>1.90</sub>La<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub> exhibited a significantly longer afterglow compared to Sm<sub>1.90</sub>Eu<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub> and Eu<sub>1.90</sub>Sm<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub>. Conversely, Sm<sub>1.90</sub>Eu<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub> demonstrated luminescence intensity that was 20 times greater than that of Eu<sub>1.90</sub>La<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub> and Eu<sub>1.90</sub>Sm<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub>. Furthermore, all samples with characteristic Eu<sup>3+</sup> emissions also exhibited piezoelectric properties. Curie temperature (T<sub>c</sub>) of Eu<sub>1.90</sub>La<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub>, Sm<sub>1.90</sub>Eu<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub>, and Eu<sub>1.90</sub>Sm<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub> are 770°C, 830°C, and 845°C, respectively. Therefore, Sm<sup>3+</sup> ion improves piezoelectric properties and Curie temperature when doping into the Eu<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub> host crystal.</p>","PeriodicalId":49902,"journal":{"name":"Luminescence","volume":"39 10","pages":""},"PeriodicalIF":3.2000,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bio.4925","citationCount":"0","resultStr":"{\"title\":\"The Investigation of the Effect of La3+, Eu3+, and Sm3+ Ions on Photoluminescence and Piezoelectric Behavior of RE1.90Y0.10Zr2O7 (RE: Eu, Sm and Y: La, Sm, Eu) Pyrochlore-Based Multifunctional Smart Advanced Materials\",\"authors\":\"Esra Öztürk, Nilgun Kalaycioglu Ozpozan, Volkan Kalem\",\"doi\":\"10.1002/bio.4925\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A series of compounds with the general formula RE<sub>1.90</sub>Y<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub> (where RE includes Eu, Sm and Y includes La, Sm, Eu) were synthesized using a solid-state reaction method. These compounds were analyzed through differential thermal analysis (DTA), thermogravimetric analysis (TG), X-ray powder diffraction (XRD), and scanning electron microscopy (SEM). Additionally, their dielectric constant, loss tangent, piezoelectric charge constant, and Curie temperature were measured using an LCR meter, d<sub>33</sub> meter, and TG/DTA. X-ray diffraction results indicated that all samples crystallize in a cubic pyrochlore structure. Photoluminescence studies revealed that Eu<sup>3+</sup> ions predominantly contribute to the emission, whether as activators or co-activators. Among the phosphors, Eu<sub>1.90</sub>La<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub> exhibited a significantly longer afterglow compared to Sm<sub>1.90</sub>Eu<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub> and Eu<sub>1.90</sub>Sm<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub>. Conversely, Sm<sub>1.90</sub>Eu<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub> demonstrated luminescence intensity that was 20 times greater than that of Eu<sub>1.90</sub>La<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub> and Eu<sub>1.90</sub>Sm<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub>. Furthermore, all samples with characteristic Eu<sup>3+</sup> emissions also exhibited piezoelectric properties. Curie temperature (T<sub>c</sub>) of Eu<sub>1.90</sub>La<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub>, Sm<sub>1.90</sub>Eu<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub>, and Eu<sub>1.90</sub>Sm<sub>0.10</sub>Zr<sub>2</sub>O<sub>7</sub> are 770°C, 830°C, and 845°C, respectively. Therefore, Sm<sup>3+</sup> ion improves piezoelectric properties and Curie temperature when doping into the Eu<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub> host crystal.</p>\",\"PeriodicalId\":49902,\"journal\":{\"name\":\"Luminescence\",\"volume\":\"39 10\",\"pages\":\"\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2024-10-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bio.4925\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Luminescence\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/bio.4925\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Luminescence","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/bio.4925","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
The Investigation of the Effect of La3+, Eu3+, and Sm3+ Ions on Photoluminescence and Piezoelectric Behavior of RE1.90Y0.10Zr2O7 (RE: Eu, Sm and Y: La, Sm, Eu) Pyrochlore-Based Multifunctional Smart Advanced Materials
A series of compounds with the general formula RE1.90Y0.10Zr2O7 (where RE includes Eu, Sm and Y includes La, Sm, Eu) were synthesized using a solid-state reaction method. These compounds were analyzed through differential thermal analysis (DTA), thermogravimetric analysis (TG), X-ray powder diffraction (XRD), and scanning electron microscopy (SEM). Additionally, their dielectric constant, loss tangent, piezoelectric charge constant, and Curie temperature were measured using an LCR meter, d33 meter, and TG/DTA. X-ray diffraction results indicated that all samples crystallize in a cubic pyrochlore structure. Photoluminescence studies revealed that Eu3+ ions predominantly contribute to the emission, whether as activators or co-activators. Among the phosphors, Eu1.90La0.10Zr2O7 exhibited a significantly longer afterglow compared to Sm1.90Eu0.10Zr2O7 and Eu1.90Sm0.10Zr2O7. Conversely, Sm1.90Eu0.10Zr2O7 demonstrated luminescence intensity that was 20 times greater than that of Eu1.90La0.10Zr2O7 and Eu1.90Sm0.10Zr2O7. Furthermore, all samples with characteristic Eu3+ emissions also exhibited piezoelectric properties. Curie temperature (Tc) of Eu1.90La0.10Zr2O7, Sm1.90Eu0.10Zr2O7, and Eu1.90Sm0.10Zr2O7 are 770°C, 830°C, and 845°C, respectively. Therefore, Sm3+ ion improves piezoelectric properties and Curie temperature when doping into the Eu2Zr2O7 host crystal.
期刊介绍：
Luminescence provides a forum for the publication of original scientific papers, short communications, technical notes and reviews on fundamental and applied aspects of all forms of luminescence, including bioluminescence, chemiluminescence, electrochemiluminescence, sonoluminescence, triboluminescence, fluorescence, time-resolved fluorescence and phosphorescence. Luminescence publishes papers on assays and analytical methods, instrumentation, mechanistic and synthetic studies, basic biology and chemistry.
Luminescence also publishes details of forthcoming meetings, information on new products, and book reviews. A special feature of the Journal is surveys of the recent literature on selected topics in luminescence.
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