{"title":"三氟甲基化吡咯烷酮的光催化区域选择性串联环化协议","authors":"Panpan Wang, Yuting Leng, Kaixia Sui, Shiliang Jiang, Ning Ma, Yangjie Wu","doi":"10.1002/ejoc.202401023","DOIUrl":null,"url":null,"abstract":"A new environmentally friendly and efficient strategy for preparing trifluoromethylated pyrrolidones has been developed. The process involves using visible light to induce radical cyclization of 1,5-dienes with CF3SO2Na, resulting in excellent regioselectivity. This method uses less expensive and easy-to-store trifluoromethylation reagents, making it an attractive option. Additionally, the resulting trifluoromethylated pyrrolidones can be easily modified and preliminary mechanistic studies have been presented.","PeriodicalId":167,"journal":{"name":"European Journal of Organic Chemistry","volume":"12 1","pages":""},"PeriodicalIF":2.5000,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Photocatalytic Regioselective Tandem Cyclization Protocol to Trifluoromethylated Pyrrolidones\",\"authors\":\"Panpan Wang, Yuting Leng, Kaixia Sui, Shiliang Jiang, Ning Ma, Yangjie Wu\",\"doi\":\"10.1002/ejoc.202401023\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A new environmentally friendly and efficient strategy for preparing trifluoromethylated pyrrolidones has been developed. The process involves using visible light to induce radical cyclization of 1,5-dienes with CF3SO2Na, resulting in excellent regioselectivity. This method uses less expensive and easy-to-store trifluoromethylation reagents, making it an attractive option. Additionally, the resulting trifluoromethylated pyrrolidones can be easily modified and preliminary mechanistic studies have been presented.\",\"PeriodicalId\":167,\"journal\":{\"name\":\"European Journal of Organic Chemistry\",\"volume\":\"12 1\",\"pages\":\"\"},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2024-10-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"European Journal of Organic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/ejoc.202401023\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Organic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/ejoc.202401023","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Photocatalytic Regioselective Tandem Cyclization Protocol to Trifluoromethylated Pyrrolidones
A new environmentally friendly and efficient strategy for preparing trifluoromethylated pyrrolidones has been developed. The process involves using visible light to induce radical cyclization of 1,5-dienes with CF3SO2Na, resulting in excellent regioselectivity. This method uses less expensive and easy-to-store trifluoromethylation reagents, making it an attractive option. Additionally, the resulting trifluoromethylated pyrrolidones can be easily modified and preliminary mechanistic studies have been presented.
期刊介绍:
The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry:
Liebigs Annalen
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry.