Succulent inspired grown g-C3N4@lithium sodium niobate for supercapacitors and piezo-tuned electrochemical potential controlled smart electromagnetic shielding management†

A synchronous way of energy generation and storage in a single portable device is in high demand for the development of high-end electromagnetic interference (EMI) free modern electronics. Thus, this study highlights the devising of a piezoelectrically self-chargeable symmetric supercapacitor (PSCS) device using a polyvinyl alcohol (PVA)/succulent inspired grown g-C₃N₄@lithium sodium niobate (GNLNN)/potassium hydroxide (KOH) based piezo separator with GNLNN electrode. The GNLNN electrode exhibits a surface capacitive controlled specific capacitance of 503 F g⁻¹. The PSCS device exhibits an energy density of 15.3 W h kg⁻¹ and a power density of 4.2 kW kg⁻¹ with an impressive capacitive retention capability of 93.2% after 6000 cycles of charging–discharging. The PSCS device can be charged up to 393 mV within 180 s under 14.2 N of cyclic pressing by human finger imparting. The fabricated PSCS device was also investigated for self-charging potential regulated smart EMI shielding applications. The smart PSCS device achieves an 88.3 dB increment from 40.9 dB of EMI shielding under charging from 0 mV to 300 mV. The increased charging potential of the PSCS device enhances the destructive interference and leads to boosted absorption and decreased reflection of incident EM radiation.