用于光电设备的新型 α-萘酚发光体的制备与表征。

IF 2.6 4区 化学 Q2 BIOCHEMICAL RESEARCH METHODS Journal of Fluorescence Pub Date : 2024-10-13 DOI:10.1007/s10895-024-04003-1
Vasanti B Shabade, Amarsinh R Mainak, Sidram R Pujari
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引用次数: 0

摘要

通过传统的固态反应方法制备了掺杂不同浓度蒽和苝的α-萘酚发光体,以探索其荧光特性。双组分和三组分发光体的荧光光谱揭示了荧光激发能量转移(FRET)过程。制备的双组分和三组分发光体在 290 纳米波长处激发,该波长与宿主激发波长一致。在双组分发光体系统中,宿主α-萘酚的微弱紫色荧光被淬灭,并发出类似蒽的荧光。在含有α-萘酚的蒽发光体中进一步掺入第二宿主--苝,在 605 纳米波长处观察到红移发射。利用 X 射线衍射、TGA-DSC 和循环伏安法分别研究了掺杂发光体的结构参数、热稳定性和电性能。通过扫描电子显微镜(SEM)确认了所制备发光体的粒度。
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Preparation and Characterization of Novel α-Naphthol Luminophors for Optoelectronic Devices.

Luminophors of α-Naphthol doped with varying concentrations of anthracene and perylene were prepared by conventional solid state reaction method to explore its fluorescence characteristics. The fluorescence spectra of bicomponent and tricomponent luminophors reveals the fluorescence excitation energy transfer (FRET) process. The prepared bi and tri component luminophors were excited at 290 nm which corresponds to host excitation wavelength. The weak violet fluorescence of host, α-Naphthol, gets quenched and give anthracene like emission in bicomponent luminophor systems. Further doping with second host, perylene, in anthracene containing α-Naphthol luminophors, red shifted emission was observed at 605 nm. The structural parameters, thermal stability and electrical properties of doped luminophors were studied by using X-ray diffraction, TGA-DSC and Cyclic Voltammetry respectively. The particle size of the prepared luminophors was confirmed by scanning electron microscopy (SEM).

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来源期刊
Journal of Fluorescence
Journal of Fluorescence 化学-分析化学
CiteScore
4.60
自引率
7.40%
发文量
203
审稿时长
5.4 months
期刊介绍: Journal of Fluorescence is an international forum for the publication of peer-reviewed original articles that advance the practice of this established spectroscopic technique. Topics covered include advances in theory/and or data analysis, studies of the photophysics of aromatic molecules, solvent, and environmental effects, development of stationary or time-resolved measurements, advances in fluorescence microscopy, imaging, photobleaching/recovery measurements, and/or phosphorescence for studies of cell biology, chemical biology and the advanced uses of fluorescence in flow cytometry/analysis, immunology, high throughput screening/drug discovery, DNA sequencing/arrays, genomics and proteomics. Typical applications might include studies of macromolecular dynamics and conformation, intracellular chemistry, and gene expression. The journal also publishes papers that describe the synthesis and characterization of new fluorophores, particularly those displaying unique sensitivities and/or optical properties. In addition to original articles, the Journal also publishes reviews, rapid communications, short communications, letters to the editor, topical news articles, and technical and design notes.
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