Bronte Carr, Timothy D Christopher, Tilo Söhnel, Lawrence R Gahan, Cassandra L Fleming, Allan G Blackman
{"title":"含混合喹啉基和吡啶基配体的三足配体过渡金属配合物的结构变化。","authors":"Bronte Carr, Timothy D Christopher, Tilo Söhnel, Lawrence R Gahan, Cassandra L Fleming, Allan G Blackman","doi":"10.1002/open.202400304","DOIUrl":null,"url":null,"abstract":"<p><p>The syntheses of the tripodal tetraamine ligands 2-(pyridin-2-yl)-N,N-bis(quinolin-2-ylmethyl)ethan-1-amine (DQPEA), N-(pyridin-2-ylmethyl)-2-(quinolin-2-yl)-N-(2-(quinolin-2-yl)ethyl)ethan-1-amine (DQEPMA), 2-(pyridin-2-yl)-N,N-bis(2-(quinolin-2-yl)ethyl)ethan-1-amine (DQEPEA), N,N-bis(pyridin-2-ylmethyl)-2-(quinolin-2-yl)ethan-1-amine (QEDPMA), and 2-(pyridin-2-yl)-N-(2-(pyridin-2-yl)ethyl)-N-(2-(quinolin-2-yl)ethyl)ethan-1-amine (QEDPEA) containing mixed quinolyl and pyridyl moieties are reported, with 2-vinylquinoline being used to attach quinolylethyl arms to the aliphatic N atom. X-ray crystal structures of [(Mn(DQPEA))<sub>2</sub>O<sub>2</sub>](ClO<sub>4</sub>)<sub>2</sub> ⋅ (CH<sub>3</sub>CN)<sub>2</sub>, [Cu(DQPEA)NCCH<sub>3</sub>](ClO<sub>4</sub>)<sub>2</sub>, [Zn(DQPEA)NCCH<sub>3</sub>](ClO<sub>4</sub>)<sub>2</sub>, [Pd(DQEPEA)Cl]Cl ⋅ 11H<sub>2</sub>O are detailed, with four, five, and six-coordination observed. In addition, the dimeric complex [(DPEA)Co(μ-OH)<sub>3</sub>Co(DPEA)](ClO<sub>4</sub>)<sub>3</sub> ⋅ 0.5H<sub>2</sub>O ⋅ MeCN containing the tridentate DPEA ligand formed by N-dealkylation of QEDPEA is reported. Calculations suggest that the very short Co…Co distance of 2.5946(6) Å in this complex is unlikely to be due to a Co-Co bond.</p>","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":null,"pages":null},"PeriodicalIF":2.5000,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Structural Variety in Transition Metal Complexes of Tripodal Ligands Containing Mixed Quinolyl and Pyridyl Donors.\",\"authors\":\"Bronte Carr, Timothy D Christopher, Tilo Söhnel, Lawrence R Gahan, Cassandra L Fleming, Allan G Blackman\",\"doi\":\"10.1002/open.202400304\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The syntheses of the tripodal tetraamine ligands 2-(pyridin-2-yl)-N,N-bis(quinolin-2-ylmethyl)ethan-1-amine (DQPEA), N-(pyridin-2-ylmethyl)-2-(quinolin-2-yl)-N-(2-(quinolin-2-yl)ethyl)ethan-1-amine (DQEPMA), 2-(pyridin-2-yl)-N,N-bis(2-(quinolin-2-yl)ethyl)ethan-1-amine (DQEPEA), N,N-bis(pyridin-2-ylmethyl)-2-(quinolin-2-yl)ethan-1-amine (QEDPMA), and 2-(pyridin-2-yl)-N-(2-(pyridin-2-yl)ethyl)-N-(2-(quinolin-2-yl)ethyl)ethan-1-amine (QEDPEA) containing mixed quinolyl and pyridyl moieties are reported, with 2-vinylquinoline being used to attach quinolylethyl arms to the aliphatic N atom. X-ray crystal structures of [(Mn(DQPEA))<sub>2</sub>O<sub>2</sub>](ClO<sub>4</sub>)<sub>2</sub> ⋅ (CH<sub>3</sub>CN)<sub>2</sub>, [Cu(DQPEA)NCCH<sub>3</sub>](ClO<sub>4</sub>)<sub>2</sub>, [Zn(DQPEA)NCCH<sub>3</sub>](ClO<sub>4</sub>)<sub>2</sub>, [Pd(DQEPEA)Cl]Cl ⋅ 11H<sub>2</sub>O are detailed, with four, five, and six-coordination observed. In addition, the dimeric complex [(DPEA)Co(μ-OH)<sub>3</sub>Co(DPEA)](ClO<sub>4</sub>)<sub>3</sub> ⋅ 0.5H<sub>2</sub>O ⋅ MeCN containing the tridentate DPEA ligand formed by N-dealkylation of QEDPEA is reported. Calculations suggest that the very short Co…Co distance of 2.5946(6) Å in this complex is unlikely to be due to a Co-Co bond.</p>\",\"PeriodicalId\":9831,\"journal\":{\"name\":\"ChemistryOpen\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2024-10-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemistryOpen\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/open.202400304\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemistryOpen","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/open.202400304","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Structural Variety in Transition Metal Complexes of Tripodal Ligands Containing Mixed Quinolyl and Pyridyl Donors.
The syntheses of the tripodal tetraamine ligands 2-(pyridin-2-yl)-N,N-bis(quinolin-2-ylmethyl)ethan-1-amine (DQPEA), N-(pyridin-2-ylmethyl)-2-(quinolin-2-yl)-N-(2-(quinolin-2-yl)ethyl)ethan-1-amine (DQEPMA), 2-(pyridin-2-yl)-N,N-bis(2-(quinolin-2-yl)ethyl)ethan-1-amine (DQEPEA), N,N-bis(pyridin-2-ylmethyl)-2-(quinolin-2-yl)ethan-1-amine (QEDPMA), and 2-(pyridin-2-yl)-N-(2-(pyridin-2-yl)ethyl)-N-(2-(quinolin-2-yl)ethyl)ethan-1-amine (QEDPEA) containing mixed quinolyl and pyridyl moieties are reported, with 2-vinylquinoline being used to attach quinolylethyl arms to the aliphatic N atom. X-ray crystal structures of [(Mn(DQPEA))2O2](ClO4)2 ⋅ (CH3CN)2, [Cu(DQPEA)NCCH3](ClO4)2, [Zn(DQPEA)NCCH3](ClO4)2, [Pd(DQEPEA)Cl]Cl ⋅ 11H2O are detailed, with four, five, and six-coordination observed. In addition, the dimeric complex [(DPEA)Co(μ-OH)3Co(DPEA)](ClO4)3 ⋅ 0.5H2O ⋅ MeCN containing the tridentate DPEA ligand formed by N-dealkylation of QEDPEA is reported. Calculations suggest that the very short Co…Co distance of 2.5946(6) Å in this complex is unlikely to be due to a Co-Co bond.
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