Han Zhang, Jinping Duan, Pengcheng Luo, Luxiang Zhu, Yanan Liu
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Degradation of Atrazine in Water by Dielectric Barrier Discharge Combined with Periodate Oxidation: Enhanced Performance, Degradation Pathways, and Toxicity Assessment.
The widespread occurrence of atrazine (ATZ) in water environments presents a considerable risk to human health and ecosystems. Herein, the performance of dielectric barrier discharge integrated with periodate (DBD/PI) for ATZ decomposition was evaluated. Results demonstrated that the DBD/PI system improved ATZ decomposition efficiency by 18.2-22.5% compared to the sole DBD system. After 10 min treatment, the decomposition efficiency attained 82.4% at a discharge power of 68 W, a PI dosage of 0.02 mM, and an initial ATZ concentration of 10 mg/L. As the PI dosage increased, the decomposition efficiency exhibited a trend of initially increasing, followed by a decrease. Acidic conditions were more favorable for ATZ removal compared to alkaline and neutral conditions. Electron paramagnetic resonance (EPR) was adopted for characterizing the active species produced in the DBD/PI system, and quenching experiments revealed their influence on ATZ decomposition following a sequence of 1O2 > O2-• > IO3• > OH•. The decomposition pathways were proposed based on the theoretical calculations and intermediate identification. Additionally, the toxic effects of ATZ and its intermediates were assessed. This study demonstrates that the DBD/PI treatment represents an effective strategy for the decomposition of ATZ in aquatic environments.
ToxicsChemical Engineering-Chemical Health and Safety
CiteScore
4.50
自引率
10.90%
发文量
681
审稿时长
6 weeks
期刊介绍:
The Journal accepts papers describing work that furthers our understanding of the exposure, effects, and risks of chemicals and materials in humans and the natural environment as well as approaches to assess and/or manage the toxicological and ecotoxicological risks of chemicals and materials. The journal covers a wide range of toxic substances, including metals, pesticides, pharmaceuticals, biocides, nanomaterials, and polymers such as micro- and mesoplastics. Toxics accepts papers covering:
The occurrence, transport, and fate of chemicals and materials in different systems (e.g., food, air, water, soil);
Exposure of humans and the environment to toxic chemicals and materials as well as modelling and experimental approaches for characterizing the exposure in, e.g., water, air, soil, food, and consumer products;
Uptake, metabolism, and effects of chemicals and materials in a wide range of systems including in-vitro toxicological assays, aquatic and terrestrial organisms and ecosystems, model mammalian systems, and humans;
Approaches to assess the risks of chemicals and materials to humans and the environment;
Methodologies to eliminate or reduce the exposure of humans and the environment to toxic chemicals and materials.