磷 (iv) 和原羧酸酯与苯甲醛和苯甲酰卤的反应：途径和催化作用

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Russian Chemical Bulletin Pub Date : 2024-10-26 DOI:10.1007/s11172-024-4382-8

M. B. Gazizov, R. A. Khairullin, S. Yu. Ivanova, R. F. Karimova, B. D. Nuriakhmetov, O. D. Khairullina, L. R. Shaikhutdinova, N. N. Gazizova

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引用次数: 0

摘要

苯甲醛和苯甲酰卤与磷(iv)酸酯反应的主要途径遵循脱卤膦酰基/膦酰基（氧化）过程，并导致相应的含羰基化合物或苯甲酰酯。发现了 α-氯醚和 O-烷基二乙基膦之间的新反应。在无水氯化锌的催化下，苄基卤化物与磷（iv）酯和正羧酸发生了反应。

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Reactions of phosphorus (iv) and orthocarboxylic acid esters with benzal and benzyl halides: pathways and catalysis

The main pathway of the reaction of benzal and benzyl halides with phosphorus(iv) acid esters followed the dehalophosphonyl/phosphinyl(oxylation) course and led to the corresponding carbonyl-containing compounds or benzyl esters. A new reaction between α-chloro ethers and O-alkyl diethylphosphinates was discovered. The reactions of benzyl halides with esters of phosphorus(iv) and orthocarboxylic acids were catalyzed by anhydrous zinc chloride.

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.