T. P. Trofimova, V. A. Tafeenko, A. S. Borodkov, A. N. Proshin, A. A. Evdokimov, M. A. Orlova
{"title":"氯化铋(iii)与 N-(5,6-二氢-4H-1,3-噻嗪-2-基)苯甲酰胺的反应","authors":"T. P. Trofimova, V. A. Tafeenko, A. S. Borodkov, A. N. Proshin, A. A. Evdokimov, M. A. Orlova","doi":"10.1007/s11172-024-4378-4","DOIUrl":null,"url":null,"abstract":"<div><p>A new bismuth complex with the <i>N</i>-(5,6-dihydro-4<i>H</i>-1,3-thiazin-2-yl)benzamide ligand (L = C<sub>11</sub>H<sub>13</sub>N<sub>2</sub>OS) was synthesized for further medical use. The complex and the ligand exhibit anticancer activity. The structure of the complex was characterized by NMR spectroscopy, inductively coupled plasma atomic emission spectroscopy (ICP-AES), and laser-induced electron transfer desorption/ionization (LETDI) mass spectrometry. The Bi: L ratio is 1: 1; the components are connected by an ionic (ion-dipole) interaction. The reaction of bismuth(<span>iii</span>) chloride with ligand hydrobromide (L•HBr) affords the complex {(C<sub>11</sub>H<sub>13</sub>N<sub>2</sub>OS)<sub>3</sub>[Bi<sub>2</sub>Cl<sub>9</sub>]}. The composition of this complex was confirmed by X-ray diffraction, ICP-AES, and LETDI methods.</p></div>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":"73 9","pages":"2660 - 2666"},"PeriodicalIF":1.7000,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Reaction of bismuth(iii) chloride with N-(5,6-dihydro-4H-1,3-thiazin-2-yl)benzamide\",\"authors\":\"T. P. Trofimova, V. A. Tafeenko, A. S. Borodkov, A. N. Proshin, A. A. Evdokimov, M. A. Orlova\",\"doi\":\"10.1007/s11172-024-4378-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A new bismuth complex with the <i>N</i>-(5,6-dihydro-4<i>H</i>-1,3-thiazin-2-yl)benzamide ligand (L = C<sub>11</sub>H<sub>13</sub>N<sub>2</sub>OS) was synthesized for further medical use. The complex and the ligand exhibit anticancer activity. The structure of the complex was characterized by NMR spectroscopy, inductively coupled plasma atomic emission spectroscopy (ICP-AES), and laser-induced electron transfer desorption/ionization (LETDI) mass spectrometry. The Bi: L ratio is 1: 1; the components are connected by an ionic (ion-dipole) interaction. The reaction of bismuth(<span>iii</span>) chloride with ligand hydrobromide (L•HBr) affords the complex {(C<sub>11</sub>H<sub>13</sub>N<sub>2</sub>OS)<sub>3</sub>[Bi<sub>2</sub>Cl<sub>9</sub>]}. The composition of this complex was confirmed by X-ray diffraction, ICP-AES, and LETDI methods.</p></div>\",\"PeriodicalId\":756,\"journal\":{\"name\":\"Russian Chemical Bulletin\",\"volume\":\"73 9\",\"pages\":\"2660 - 2666\"},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2024-10-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Chemical Bulletin\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11172-024-4378-4\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11172-024-4378-4","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Reaction of bismuth(iii) chloride with N-(5,6-dihydro-4H-1,3-thiazin-2-yl)benzamide
A new bismuth complex with the N-(5,6-dihydro-4H-1,3-thiazin-2-yl)benzamide ligand (L = C11H13N2OS) was synthesized for further medical use. The complex and the ligand exhibit anticancer activity. The structure of the complex was characterized by NMR spectroscopy, inductively coupled plasma atomic emission spectroscopy (ICP-AES), and laser-induced electron transfer desorption/ionization (LETDI) mass spectrometry. The Bi: L ratio is 1: 1; the components are connected by an ionic (ion-dipole) interaction. The reaction of bismuth(iii) chloride with ligand hydrobromide (L•HBr) affords the complex {(C11H13N2OS)3[Bi2Cl9]}. The composition of this complex was confirmed by X-ray diffraction, ICP-AES, and LETDI methods.
期刊介绍：
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.
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