用于电子和光电设备的半有机双甘氨酸氯化钴二水单晶的光学、介电和热分析研究

IF 3.3 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Optical and Quantum Electronics Pub Date : 2024-10-26 DOI:10.1007/s11082-024-07713-9
P. Revathi, T. Balakrishnan, J. Thirupathy
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引用次数: 0

摘要

双甘氨酸氯化钴二水合物(BGCCD)半有机单晶是一种用于光子、电子和光电器件等非线性光学(NLO)应用的优质材料。本文介绍了利用慢速蒸发溶液技术(SEST)制备的高质量 BGCCD 单晶,它是一种著名的 NLO 材料。在 80 天的时间里,收集到了最大尺寸为 9 × 9 × 8 mm3 的透明 BGCCD 晶体。对生长出的晶体进行了各种分析,包括利用单晶 X 射线衍射找出单胞参数。利用傅立叶变换红外光谱分析官能团。利用紫外-可见光谱分析生长晶体的带隙和吸光度。通过微硬度确定机械稳定性。利用介电测量法确定生长晶体的介电损耗和介电常数。稳定性是通过热重分析和差热分析得出的。为了检测生长晶体的表面缺陷,采用了蚀刻分析法。使用扫描电子显微镜确定结构形态。使用能量色散 X 射线分析鉴定元素。激发光谱和发射光谱可通过光致发光来确定,而为了确定晶体的热扩散率,则采用了光声光谱法。有关热扩散率的研究结果表明,该晶体非常适合用于光电子器件。
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An investigation on optical, dielectric and thermal analysis of semiorganic bisglycine cobalt chloride dihydrate single crystal for electronic and opto-electronic devices

Semiorganic single crystal of bisglycine cobalt chloride dihydrate (BGCCD) is a superior material for non-linear optics (NLO) applications such as photonic, electronic and opto-electronic devices. This article presents high-quality BGCCD single crystals prepared using the slow evaporation solution technique (SEST), which are a famous NLO material. A transparent BGCCD crystal with a maximum size of 9 × 9 × 8 mm3 was collected over the period of 80 days. Various analyses were conducted on the grown crystals, including single crystal x-ray diffraction, which was utilized to find out the unit cell parameters. Analyses of functional groups using Fourier transform infrared spectroscopy. Finding the band gap and absorbance of the grown crystal is done using UV-Visible spectroscopy. Mechanical stability is determined by micro-hardness. The dielectric loss and dielectric constant of the grown crystal is found by utilizing dielectric measurements. The stability is found through thermo-gravimetric and differential thermal analyses. To detect surface flaws in the grown crystals, etching analysis was employed. Structure morphology was identified using a scanning electron microscope. The elements were identified using energy dispersive x-ray analysis. The excitation and emission spectra can be determined using photoluminescence, and in order to determine the crystal’s thermal diffusivity, photoacoustic spectroscopy was employed. The findings regarding thermal diffusivity indicate that it is well-suited for uses related to opto-electronic devices.

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来源期刊
Optical and Quantum Electronics
Optical and Quantum Electronics 工程技术-工程:电子与电气
CiteScore
4.60
自引率
20.00%
发文量
810
审稿时长
3.8 months
期刊介绍: Optical and Quantum Electronics provides an international forum for the publication of original research papers, tutorial reviews and letters in such fields as optical physics, optical engineering and optoelectronics. Special issues are published on topics of current interest. Optical and Quantum Electronics is published monthly. It is concerned with the technology and physics of optical systems, components and devices, i.e., with topics such as: optical fibres; semiconductor lasers and LEDs; light detection and imaging devices; nanophotonics; photonic integration and optoelectronic integrated circuits; silicon photonics; displays; optical communications from devices to systems; materials for photonics (e.g. semiconductors, glasses, graphene); the physics and simulation of optical devices and systems; nanotechnologies in photonics (including engineered nano-structures such as photonic crystals, sub-wavelength photonic structures, metamaterials, and plasmonics); advanced quantum and optoelectronic applications (e.g. quantum computing, memory and communications, quantum sensing and quantum dots); photonic sensors and bio-sensors; Terahertz phenomena; non-linear optics and ultrafast phenomena; green photonics.
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