Yanxun Mu , Yongfeng Liang , Jiaqi Sheng , Chenyang Zhang , Zheng Guo , Gang Yang , Tielong Sun , Yongsheng Wang , Junpin Lin
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引用次数: 0
摘要
TiAl 合金的密度只有镍基超级合金的一半,非常适合需要轻质材料的航空航天应用。然而,在高温条件下,它们的表面往往会形成一层非保护性的混合氧化膜。这种氧化膜容易开裂,会导致长期高温氧化表面退化,从而降低其高温蠕变和抗疲劳性能。氧化膜上的表面裂纹进一步加剧了高温暴露后 TiAl 金属间化合物的脆性。虽然涂层通常是为了促进致密氧化物的形成以达到表面保护的目的,但其主要作用是增强抗氧化性。然而,这种改善是以降低 TiAl 合金的高温抗蠕变性、抗疲劳性和室温塑性为代价的。本研究引入了一种无电镀涂层方法,在钛铝合金表面沉积一层约 200 nm 厚的铂涂层。在高温应用过程中,铂以纳米颗粒的形式分散在氧化层中,增强了氧化物的可塑性。这种氧化物结构大大改善了钛铝合金的高温蠕变和疲劳性能,同时提高了氧化后的室温拉伸性能。这种方法为设计高温部件的表面涂层提供了一种新策略。
A novel approach to coating for improving the comprehensive high-temperature service performance of TiAl alloys
TiAl alloys, with half the density of nickel-based superalloys, are highly suitable for aerospace applications requiring lightweight materials. However, they tend to form a nonprotective mixed oxide film on their surface at high temperatures. This oxide film is prone to cracking, which can lead to long-term high-temperature oxidation surface degradation, thereby reducing their high-temperature creep and fatigue resistance. Surface cracks on the oxide film further aggravated the brittleness of the TiAl intermetallic compounds after high-temperature exposure. While coatings are typically applied to promote the formation of dense oxides for surface protection, they primarily enhance oxidation resistance. However, this improvement comes at the cost of reducing the high-temperature creep and fatigue resistance and the room-temperature plasticity of TiAl alloys. This study introduced an electroless coating method to deposit a Pt coating, approximately 200 nm thick, on the surface of TiAl alloys. During high-temperature applications, the Pt dispersed as nanoparticles within the oxide layer, enhancing the oxide's plasticity. This oxide structure considerably improved the high-temperature creep and fatigue properties of TiAl alloys, while enhancing their room-temperature tensile properties after oxidation. This approach offers a novel strategy for designing surface coatings for high-temperature components.
期刊介绍:
Acta Materialia serves as a platform for publishing full-length, original papers and commissioned overviews that contribute to a profound understanding of the correlation between the processing, structure, and properties of inorganic materials. The journal seeks papers with high impact potential or those that significantly propel the field forward. The scope includes the atomic and molecular arrangements, chemical and electronic structures, and microstructure of materials, focusing on their mechanical or functional behavior across all length scales, including nanostructures.