{"title":"利用氨/煤二元燃料气化-燃烧技术帮助脱硝和强化燃烧:注入位置和空气分布的影响","authors":"","doi":"10.1016/j.energy.2024.133609","DOIUrl":null,"url":null,"abstract":"<div><div>The direct co-firing of ammonia (NH<sub>3</sub>) with coal is an effective approach for reducing carbon emissions from coal-fired plants. However, the limitations of NH<sub>3</sub> combustion, such as its high ignition energy requirement and high NO<sub><em>x</em></sub> emissions, restrict its large-scale co-combustion in coal-fired units. In this study, a self-sustaining gasification–combustion experimental system was employed, and its denitrification performance and combustion strengthening capability for NH<sub>3</sub>/coal binary fuel under different NH<sub>3</sub> injection positions and air distribution methods were evaluated. The results of co-firing 20 % NH<sub>3</sub> in the gasifier revealed that its operating temperature can be flexibly controlled within the optimal reaction temperature window of SNCR by adjusting the primary air ratio (λ<sub>1</sub>). Increasing λ<sub>1</sub> was beneficial for NH<sub>3</sub> and coal conversion and denitrification in the gasifier; at λ<sub>1</sub> = 0.53, the conversion rate of NH<sub>3</sub> and N<sub>2</sub> reached 86.37 % and 83.59 %, respectively, with no NO<sub><em>x</em></sub> being detected at the gasifier outlet. Furthermore, increasing λ<sub>1</sub> promoted the development of gasified char pore structure, thereby improving reactivity. After entering the down-fired combustor (DFC), increasing λ<sub>1</sub> promoted NH<sub>3</sub> and coal burnout and effectively controlled NO<sub><em>x</em></sub> emissions, reaching a level similar with that of pure coal under λ<sub>1</sub> = 0.53. Co-firing 20 % NH<sub>3</sub> in the DFC also demonstrated that the introduction of inner secondary air was conducive to char burnout, however, increased NH<sub>3</sub> slip. The outer secondary air promoted NH<sub>3</sub> combustion, however, exacerbated NO<sub><em>x</em></sub> emissions and inhibited gasified char combustion. The uniform air distribution method balanced the combustion of NH<sub>3</sub> and gasified char, and effectively controlled NO<sub><em>x</em></sub> emissions. When the same air distribution method was used, co-firing NH<sub>3</sub> in the gasifier was more favourable for NO<sub><em>x</em></sub> control, whereas co-firing NH<sub>3</sub> in the DFC benefited coal burnout. This study provides innovative ideas and serves as a reference for developing enhanced combustion and low NO<sub><em>x</em></sub> emission technologies for large-scale NH<sub>3</sub> co-firing in coal-fired units.</div></div>","PeriodicalId":11647,"journal":{"name":"Energy","volume":null,"pages":null},"PeriodicalIF":9.0000,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Assisting denitrification and strengthening combustion by using ammonia/coal binary fuel gasification-combustion: Effects of injecting position and air distribution\",\"authors\":\"\",\"doi\":\"10.1016/j.energy.2024.133609\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The direct co-firing of ammonia (NH<sub>3</sub>) with coal is an effective approach for reducing carbon emissions from coal-fired plants. However, the limitations of NH<sub>3</sub> combustion, such as its high ignition energy requirement and high NO<sub><em>x</em></sub> emissions, restrict its large-scale co-combustion in coal-fired units. In this study, a self-sustaining gasification–combustion experimental system was employed, and its denitrification performance and combustion strengthening capability for NH<sub>3</sub>/coal binary fuel under different NH<sub>3</sub> injection positions and air distribution methods were evaluated. The results of co-firing 20 % NH<sub>3</sub> in the gasifier revealed that its operating temperature can be flexibly controlled within the optimal reaction temperature window of SNCR by adjusting the primary air ratio (λ<sub>1</sub>). Increasing λ<sub>1</sub> was beneficial for NH<sub>3</sub> and coal conversion and denitrification in the gasifier; at λ<sub>1</sub> = 0.53, the conversion rate of NH<sub>3</sub> and N<sub>2</sub> reached 86.37 % and 83.59 %, respectively, with no NO<sub><em>x</em></sub> being detected at the gasifier outlet. Furthermore, increasing λ<sub>1</sub> promoted the development of gasified char pore structure, thereby improving reactivity. After entering the down-fired combustor (DFC), increasing λ<sub>1</sub> promoted NH<sub>3</sub> and coal burnout and effectively controlled NO<sub><em>x</em></sub> emissions, reaching a level similar with that of pure coal under λ<sub>1</sub> = 0.53. Co-firing 20 % NH<sub>3</sub> in the DFC also demonstrated that the introduction of inner secondary air was conducive to char burnout, however, increased NH<sub>3</sub> slip. The outer secondary air promoted NH<sub>3</sub> combustion, however, exacerbated NO<sub><em>x</em></sub> emissions and inhibited gasified char combustion. The uniform air distribution method balanced the combustion of NH<sub>3</sub> and gasified char, and effectively controlled NO<sub><em>x</em></sub> emissions. When the same air distribution method was used, co-firing NH<sub>3</sub> in the gasifier was more favourable for NO<sub><em>x</em></sub> control, whereas co-firing NH<sub>3</sub> in the DFC benefited coal burnout. This study provides innovative ideas and serves as a reference for developing enhanced combustion and low NO<sub><em>x</em></sub> emission technologies for large-scale NH<sub>3</sub> co-firing in coal-fired units.</div></div>\",\"PeriodicalId\":11647,\"journal\":{\"name\":\"Energy\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":9.0000,\"publicationDate\":\"2024-10-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Energy\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0360544224033875\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0360544224033875","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Assisting denitrification and strengthening combustion by using ammonia/coal binary fuel gasification-combustion: Effects of injecting position and air distribution
The direct co-firing of ammonia (NH3) with coal is an effective approach for reducing carbon emissions from coal-fired plants. However, the limitations of NH3 combustion, such as its high ignition energy requirement and high NOx emissions, restrict its large-scale co-combustion in coal-fired units. In this study, a self-sustaining gasification–combustion experimental system was employed, and its denitrification performance and combustion strengthening capability for NH3/coal binary fuel under different NH3 injection positions and air distribution methods were evaluated. The results of co-firing 20 % NH3 in the gasifier revealed that its operating temperature can be flexibly controlled within the optimal reaction temperature window of SNCR by adjusting the primary air ratio (λ1). Increasing λ1 was beneficial for NH3 and coal conversion and denitrification in the gasifier; at λ1 = 0.53, the conversion rate of NH3 and N2 reached 86.37 % and 83.59 %, respectively, with no NOx being detected at the gasifier outlet. Furthermore, increasing λ1 promoted the development of gasified char pore structure, thereby improving reactivity. After entering the down-fired combustor (DFC), increasing λ1 promoted NH3 and coal burnout and effectively controlled NOx emissions, reaching a level similar with that of pure coal under λ1 = 0.53. Co-firing 20 % NH3 in the DFC also demonstrated that the introduction of inner secondary air was conducive to char burnout, however, increased NH3 slip. The outer secondary air promoted NH3 combustion, however, exacerbated NOx emissions and inhibited gasified char combustion. The uniform air distribution method balanced the combustion of NH3 and gasified char, and effectively controlled NOx emissions. When the same air distribution method was used, co-firing NH3 in the gasifier was more favourable for NOx control, whereas co-firing NH3 in the DFC benefited coal burnout. This study provides innovative ideas and serves as a reference for developing enhanced combustion and low NOx emission technologies for large-scale NH3 co-firing in coal-fired units.
期刊介绍:
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