Jiang Guo , Yukun Sun , Xu Li , Shaohua Xi , Mohamed M. Ibrahim , Hua Qiu , Gaber A.M. Mersal , Zeinhom M. El-Bahy , Vignesh Murugadoss , Waras Abdul , Fujian Zhou , Juanna Ren , Zhanhu Guo , Jianfeng Zhu
{"title":"用于增强电磁波吸收的空心核壳结构 Fe3O4@Polypyrrole 复合材料","authors":"Jiang Guo , Yukun Sun , Xu Li , Shaohua Xi , Mohamed M. Ibrahim , Hua Qiu , Gaber A.M. Mersal , Zeinhom M. El-Bahy , Vignesh Murugadoss , Waras Abdul , Fujian Zhou , Juanna Ren , Zhanhu Guo , Jianfeng Zhu","doi":"10.1016/j.compscitech.2024.110917","DOIUrl":null,"url":null,"abstract":"<div><div>Due to the rapid development of electronic devices, the electromagnetic pollution has become increasingly serious. Developing electromagnetic wave absorption (EWA) materials with lightweight, strong absorption capacity and wide effective absorption bandwidth (EAB) becomes a research hotspot. In this work, the hollow-Fe<sub>3</sub>O<sub>4</sub>@polypyrrole (HFO@PPy) composites with core-shell structure were successfully synthesized by in situ polymerization method. The electromagnetic parameters could be adjusted by controlling the content of HFO in HFO@PPy. In addition, HFO@PPy composites show both dielectric and magnetic losses. The synergistic effect of both two losses contributes to an enhanced electromagnetic attenuation. The enhanced impedance matching is achieved by the composition (HFO and PPy) and designed unique structure (core-shell and hollow structure). The maximum reflection loss (RL) and EAB are −52.01 dB and 2.72 GHz at 3.1 mm for 60.0 wt% HFO@PPy composites. Therefore, by reasonably regulating the component content and optimizing the structural design, the EWA performance of HFO@PPy composites could be effectively improved, providing a significant inspiration for fabrication of microwave absorbers.</div></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":"258 ","pages":"Article 110917"},"PeriodicalIF":8.3000,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Hollow core-shell structured Fe3O4@Polypyrrole composites for enhanced electromagnetic wave absorption\",\"authors\":\"Jiang Guo , Yukun Sun , Xu Li , Shaohua Xi , Mohamed M. Ibrahim , Hua Qiu , Gaber A.M. Mersal , Zeinhom M. El-Bahy , Vignesh Murugadoss , Waras Abdul , Fujian Zhou , Juanna Ren , Zhanhu Guo , Jianfeng Zhu\",\"doi\":\"10.1016/j.compscitech.2024.110917\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Due to the rapid development of electronic devices, the electromagnetic pollution has become increasingly serious. Developing electromagnetic wave absorption (EWA) materials with lightweight, strong absorption capacity and wide effective absorption bandwidth (EAB) becomes a research hotspot. In this work, the hollow-Fe<sub>3</sub>O<sub>4</sub>@polypyrrole (HFO@PPy) composites with core-shell structure were successfully synthesized by in situ polymerization method. The electromagnetic parameters could be adjusted by controlling the content of HFO in HFO@PPy. In addition, HFO@PPy composites show both dielectric and magnetic losses. The synergistic effect of both two losses contributes to an enhanced electromagnetic attenuation. The enhanced impedance matching is achieved by the composition (HFO and PPy) and designed unique structure (core-shell and hollow structure). The maximum reflection loss (RL) and EAB are −52.01 dB and 2.72 GHz at 3.1 mm for 60.0 wt% HFO@PPy composites. Therefore, by reasonably regulating the component content and optimizing the structural design, the EWA performance of HFO@PPy composites could be effectively improved, providing a significant inspiration for fabrication of microwave absorbers.</div></div>\",\"PeriodicalId\":283,\"journal\":{\"name\":\"Composites Science and Technology\",\"volume\":\"258 \",\"pages\":\"Article 110917\"},\"PeriodicalIF\":8.3000,\"publicationDate\":\"2024-10-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Composites Science and Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0266353824004871\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, COMPOSITES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Composites Science and Technology","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0266353824004871","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
Hollow core-shell structured Fe3O4@Polypyrrole composites for enhanced electromagnetic wave absorption
Due to the rapid development of electronic devices, the electromagnetic pollution has become increasingly serious. Developing electromagnetic wave absorption (EWA) materials with lightweight, strong absorption capacity and wide effective absorption bandwidth (EAB) becomes a research hotspot. In this work, the hollow-Fe3O4@polypyrrole (HFO@PPy) composites with core-shell structure were successfully synthesized by in situ polymerization method. The electromagnetic parameters could be adjusted by controlling the content of HFO in HFO@PPy. In addition, HFO@PPy composites show both dielectric and magnetic losses. The synergistic effect of both two losses contributes to an enhanced electromagnetic attenuation. The enhanced impedance matching is achieved by the composition (HFO and PPy) and designed unique structure (core-shell and hollow structure). The maximum reflection loss (RL) and EAB are −52.01 dB and 2.72 GHz at 3.1 mm for 60.0 wt% HFO@PPy composites. Therefore, by reasonably regulating the component content and optimizing the structural design, the EWA performance of HFO@PPy composites could be effectively improved, providing a significant inspiration for fabrication of microwave absorbers.
期刊介绍:
Composites Science and Technology publishes refereed original articles on the fundamental and applied science of engineering composites. The focus of this journal is on polymeric matrix composites with reinforcements/fillers ranging from nano- to macro-scale. CSTE encourages manuscripts reporting unique, innovative contributions to the physics, chemistry, materials science and applied mechanics aspects of advanced composites.
Besides traditional fiber reinforced composites, novel composites with significant potential for engineering applications are encouraged.