石墨表面在环境和水下条件下的纳米级摩擦和磨损

IF 3.1 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Carbon Trends Pub Date : 2024-10-13 DOI:10.1016/j.cartre.2024.100414
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引用次数: 0

摘要

石墨的摩擦学特性对周围环境极为敏感,这会影响其使用寿命和减摩性能。本研究旨在全面了解液体环境对滑动界面相互作用的影响,从而影响石墨表面的纳米级摩擦学特性。我们结合原子力显微镜实验和分子动力学模拟,对石墨在环境(空气)和水下两种不同环境条件下的摩擦和磨损行为进行了比较分析。我们的研究同时探索了石墨的阶梯边缘和内部(无阶梯)表面。实验结果表明,在这两种环境下,纳米级石墨的摩擦和磨损行为形成了明显的对比。在环境和水下条件下,内表面与金刚石涂层表面的摩擦系数(COF)分别约为 0.003 和 0.006。有趣的是,与周围环境相比,水下环境不仅增加了摩擦力,还大大降低了石墨表面附近石墨烯层的耐磨性,这一点在阶梯边缘和内部无阶梯区域都有体现。内部区域在环境条件下可承受高达 ∼7400 nN 的载荷,但在水下则在∼1500 nN 时失效。同样,在环境和水下条件下,阶梯边缘分别在 375 和 187.5 nN 下失效。我们的模拟结果表明,水下条件下摩擦力增大的原因是尖端滑动时周围水分子的阻力。水在尖端与石墨的接触界面上产生了巨大的局部应力,导致了磨损的开始,并揭示了水在水下条件下对石墨磨损特性的明显影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Nanoscale friction and wear of graphite surface in ambient and underwater conditions
The tribological properties of graphite are extremely sensitive to surrounding environment, which affects its longevity and friction reduction performance. This study aims to develop a comprehensive understanding of the effects of a liquid environment on interactions at the sliding interface, thereby influencing the nanoscale tribological properties of graphite surfaces. By combining atomic force microscopy experiments and molecular dynamics simulations, we conducted a comparative analysis of friction and wear behavior of graphite under two different environmental conditions: ambient (air) and underwater condition. Our investigations explored both the step edge and interior (step-free) graphite surfaces. The experimental results revealed a notable contrast in the frictional and wear behavior of graphite at nanoscale in these two environments. The interior surface exhibited a friction coefficient (COF) of approximately 0.003 and 0.006 against a diamond-coated surface in ambient and underwater conditions, respectively. Interestingly, the underwater environment not only increased friction but also significantly compromised the wear resistance of graphene layers near the graphite surface compared to the ambient environment, as evidenced in both step edge and interior step-free regions. The interior region sustained up to ∼7400 nN load in ambient condition but failed at ∼1500 nN under water. Similarly, the step edge failed at ∼375 and ∼187.5 nN in ambient and underwater conditions, respectively. Our simulations revealed that the increased friction in underwater condition is due to resistance of surrounding water molecules during tip sliding. The presence of water at tip-graphite contact interface generated substantial localized stress, leading to the initiation of wear and revealing the pronounced effect of water on the wear characteristics of graphite in underwater condition.
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来源期刊
Carbon Trends
Carbon Trends Materials Science-Materials Science (miscellaneous)
CiteScore
4.60
自引率
0.00%
发文量
88
审稿时长
77 days
期刊最新文献
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