Zhiheng Zhou , Qingyong Luo , Arka Rudra , Henrik Ingermann Petersen , Niels Hemmingsen Schovsbo , Hamed Sanei
{"title":"丹麦北海云雀地层陆生植物和海洋藻类有机物质的有机岩石学和地球化学见解","authors":"Zhiheng Zhou , Qingyong Luo , Arka Rudra , Henrik Ingermann Petersen , Niels Hemmingsen Schovsbo , Hamed Sanei","doi":"10.1016/j.coal.2024.104627","DOIUrl":null,"url":null,"abstract":"<div><div>Climatic fluctuations from the Eocene to the Miocene highlight the importance of investigating the paleoenvironment of the latest Eocene to the Middle Miocene Lark Formation in the Danish North Sea. This study investigates immature sedimentary organic matter in the Lark Formation using 54 cuttings samples and one core sample collected from seven wells in the eastern North Sea Basin. Organic petrography and molecular geochemistry analyses were performed to determine the variations in the quantity and origin of allochthonous and autochthonous organic matter. Additionally, the study assesses the impact of climate fluctuations on marine productivity in the eastern North Sea Basin and land plant vegetation at the basin margins during the latest Eocene to the Middle Miocene.</div><div>The organic matter in the Lark Formation originated from mixed sources, primarily land plants, with a secondary contribution from marine algae. This is indicated by the maceral composition and the types and abundance of aliphatic and aromatic hydrocarbon biomarker compounds. Moreover, the presence of diterpenoids (gymnosperm biomarkers) and non-hopanoid triterpenoids (angiosperm biomarkers) reveals that the allochthonous organic matter originated from conifers and angiosperms.</div><div>Climatic impacts on land plants and marine algae during the latest Eocene to the Middle Miocene are revealed by several parameters: the Averaged Chain Length (ACL) of land plant waxes, the proportion of coniferous contribution (C/(C + A)), and the whole rock volume percentages of huminite, inertinite (H + I, vol%) and liptinite (L, vol%). The shifts to cooler and drier climates highlighted the cold adaptation of onshore conifers and resulted in the input of higher molecular weight waxy components into the sediments. However, under these conditions, reduced precipitation and runoff resulted in lower amounts of terrigenous organic matter supplied to the basin. Additionally, the drop in water temperature and the warm-affinity of local algae assemblage led to reduced marine productivity. Together, these factors contributed to an overall decrease in organic richness. In contrast, during shifts to warmer and more humid climates, the trend reversed. The contribution of conifers to the floral assemblage diminished, but higher amounts of terrigenous organic matter were transported to the basin due to increased precipitation and runoff. This was accompanied by warmer water temperatures, boosting the productivity of organic-walled microplankton in the marine environment and contributing to greater organic richness.</div></div>","PeriodicalId":13864,"journal":{"name":"International Journal of Coal Geology","volume":"295 ","pages":"Article 104627"},"PeriodicalIF":5.6000,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Organic petrographic and geochemical insights into organic matter derived from land plants and marine algae in the Lark Formation, Danish North Sea\",\"authors\":\"Zhiheng Zhou , Qingyong Luo , Arka Rudra , Henrik Ingermann Petersen , Niels Hemmingsen Schovsbo , Hamed Sanei\",\"doi\":\"10.1016/j.coal.2024.104627\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Climatic fluctuations from the Eocene to the Miocene highlight the importance of investigating the paleoenvironment of the latest Eocene to the Middle Miocene Lark Formation in the Danish North Sea. This study investigates immature sedimentary organic matter in the Lark Formation using 54 cuttings samples and one core sample collected from seven wells in the eastern North Sea Basin. Organic petrography and molecular geochemistry analyses were performed to determine the variations in the quantity and origin of allochthonous and autochthonous organic matter. Additionally, the study assesses the impact of climate fluctuations on marine productivity in the eastern North Sea Basin and land plant vegetation at the basin margins during the latest Eocene to the Middle Miocene.</div><div>The organic matter in the Lark Formation originated from mixed sources, primarily land plants, with a secondary contribution from marine algae. This is indicated by the maceral composition and the types and abundance of aliphatic and aromatic hydrocarbon biomarker compounds. Moreover, the presence of diterpenoids (gymnosperm biomarkers) and non-hopanoid triterpenoids (angiosperm biomarkers) reveals that the allochthonous organic matter originated from conifers and angiosperms.</div><div>Climatic impacts on land plants and marine algae during the latest Eocene to the Middle Miocene are revealed by several parameters: the Averaged Chain Length (ACL) of land plant waxes, the proportion of coniferous contribution (C/(C + A)), and the whole rock volume percentages of huminite, inertinite (H + I, vol%) and liptinite (L, vol%). The shifts to cooler and drier climates highlighted the cold adaptation of onshore conifers and resulted in the input of higher molecular weight waxy components into the sediments. However, under these conditions, reduced precipitation and runoff resulted in lower amounts of terrigenous organic matter supplied to the basin. Additionally, the drop in water temperature and the warm-affinity of local algae assemblage led to reduced marine productivity. Together, these factors contributed to an overall decrease in organic richness. In contrast, during shifts to warmer and more humid climates, the trend reversed. The contribution of conifers to the floral assemblage diminished, but higher amounts of terrigenous organic matter were transported to the basin due to increased precipitation and runoff. This was accompanied by warmer water temperatures, boosting the productivity of organic-walled microplankton in the marine environment and contributing to greater organic richness.</div></div>\",\"PeriodicalId\":13864,\"journal\":{\"name\":\"International Journal of Coal Geology\",\"volume\":\"295 \",\"pages\":\"Article 104627\"},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2024-10-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Coal Geology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0166516224001848\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Coal Geology","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0166516224001848","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Organic petrographic and geochemical insights into organic matter derived from land plants and marine algae in the Lark Formation, Danish North Sea
Climatic fluctuations from the Eocene to the Miocene highlight the importance of investigating the paleoenvironment of the latest Eocene to the Middle Miocene Lark Formation in the Danish North Sea. This study investigates immature sedimentary organic matter in the Lark Formation using 54 cuttings samples and one core sample collected from seven wells in the eastern North Sea Basin. Organic petrography and molecular geochemistry analyses were performed to determine the variations in the quantity and origin of allochthonous and autochthonous organic matter. Additionally, the study assesses the impact of climate fluctuations on marine productivity in the eastern North Sea Basin and land plant vegetation at the basin margins during the latest Eocene to the Middle Miocene.
The organic matter in the Lark Formation originated from mixed sources, primarily land plants, with a secondary contribution from marine algae. This is indicated by the maceral composition and the types and abundance of aliphatic and aromatic hydrocarbon biomarker compounds. Moreover, the presence of diterpenoids (gymnosperm biomarkers) and non-hopanoid triterpenoids (angiosperm biomarkers) reveals that the allochthonous organic matter originated from conifers and angiosperms.
Climatic impacts on land plants and marine algae during the latest Eocene to the Middle Miocene are revealed by several parameters: the Averaged Chain Length (ACL) of land plant waxes, the proportion of coniferous contribution (C/(C + A)), and the whole rock volume percentages of huminite, inertinite (H + I, vol%) and liptinite (L, vol%). The shifts to cooler and drier climates highlighted the cold adaptation of onshore conifers and resulted in the input of higher molecular weight waxy components into the sediments. However, under these conditions, reduced precipitation and runoff resulted in lower amounts of terrigenous organic matter supplied to the basin. Additionally, the drop in water temperature and the warm-affinity of local algae assemblage led to reduced marine productivity. Together, these factors contributed to an overall decrease in organic richness. In contrast, during shifts to warmer and more humid climates, the trend reversed. The contribution of conifers to the floral assemblage diminished, but higher amounts of terrigenous organic matter were transported to the basin due to increased precipitation and runoff. This was accompanied by warmer water temperatures, boosting the productivity of organic-walled microplankton in the marine environment and contributing to greater organic richness.
期刊介绍:
The International Journal of Coal Geology deals with fundamental and applied aspects of the geology and petrology of coal, oil/gas source rocks and shale gas resources. The journal aims to advance the exploration, exploitation and utilization of these resources, and to stimulate environmental awareness as well as advancement of engineering for effective resource management.