作为多功能材料的金属有机框架(MOFs)的研究进展:设计、合成和防腐性能技术

IF 20.3 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Coordination Chemistry Reviews Pub Date : 2024-10-29 DOI:10.1016/j.ccr.2024.216294
Kashif Rahmani Ansari , Ambrish Singh , Muhammad Younas , Ismat H. Ali , Yuanhua Lin
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引用次数: 0

摘要

在过去几年中,研究人员重点开发了金属有机框架(MOFs),它由金属离子和作为配体的有机化合物组成。MOFs 具有固有的显著特点,包括巨大的有效面积、孔径可调、可改变的行为和分子框架以及广泛的潜在活性域,因此作为缓蚀纳米材料具有广泛的潜在应用。本综述重点关注利用金属有机框架作为防腐蚀材料的最新研究。本综述重点介绍了基于 MOF 的防腐材料的最新研究进展及其防腐性能,包括人们普遍关注的 MOFs 防腐合成方法及其各自的优缺点、不同的防腐应用领域、用于筛选 MOF 缓蚀性能的最新技术以及在实际应用中需要克服的挑战。同时,我们还解释了 MOFs 作为抑制剂、纳米容器和表面保护涂层时的腐蚀保护机制。在综述的最后,我们对MOFs在腐蚀防护领域的未来发展进行了展望,希望这篇综述能阐明高性能防腐MOFs所取得的成就,并为MOF基材料在未来腐蚀防护应用领域的发展提供新思路。
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Progress in metal-organic frameworks (MOFs) as multifunctional material: Design, synthesis and anticorrosion performance techniques
In the past few years, researchers have emphasized the development of metal-organic frameworks (MOFs), which are made up of metallic ions and organic compounds as ligands. MOFs have an extensive list of potential applications as corrosion-inhibiting nanomaterials due to inherent notable characteristics, which include an enormous effective area, pore size manipulation, changeable behavior and molecular framework, and a wide range of potentially active domains. The current review focuses on the latest research on the utilization of metal-organic frameworks as anti-corrosive material. Herein, this review focuses on the latest research progress of MOF-based corrosion protection materials and reviews their anticorrosion performance, including the commonly concerned synthesis approaches of MOFs for corrosion protection with their respective advantages and shortcomings, the different anticorrosion applications, latest techniques used for screening MOF corrosion inhibition performance and the presented challenges that need to be conquered in practical applications. Meanwhile, we explained the corrosion protection mechanisms of MOFs when serve as inhibitors, nano-containers, and surface protecting coatings. At the end of this review, the future outlooks of MOFs for corrosion protection is provided, we hope this review will illuminate the achievement of high performed anticorrosion MOFs and offer new ideas for the development of MOF-based materials for future corrosion protection application.
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来源期刊
Coordination Chemistry Reviews
Coordination Chemistry Reviews 化学-无机化学与核化学
CiteScore
34.30
自引率
5.30%
发文量
457
审稿时长
54 days
期刊介绍: Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers. The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.
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