NaF 对 CdO-B2O3 玻璃体系的电气和辐射屏蔽性能的影响

IF 1.7 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Journal of Radiation Research and Applied Sciences Pub Date : 2024-10-24 DOI:10.1016/j.jrras.2024.101156
Sheik Ahammed , E.O. Echeweozo , B. Srinivas , A.V. Lalitha Phani , G. Bhikshamaiah , Md Shareefuddin , Norah Alomayrah , M.S. Al-Buriahi
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引用次数: 0

摘要

采用熔体淬火技术制备了 xNaF-(40-x)CdO-60B2O3 玻璃体系(NFCBx),其中 x = 5、10、15、20、25、30 35 mol %。所有制备的样品都使用阻抗光谱进行了表征,频率范围为 50Hz 至 5 MHz。此外,还使用 WinCOM 计算机程序在较宽的光子能量范围内对这些样品进行了伽马辐射屏蔽测试。记录了从室温到 623K 的阻抗光谱,增量为 50K。对体积电阻 (Rb)、体积电容 (Cb)、弛豫时间、活化能、质量衰减系数和有效原子序数等参数进行了评估。在较低频率下,制备的玻璃样品的电导率与频率无关。但在较高频率下,电导率会发生变化。体电容随着温度和 NaF 浓度的增加而增加。活化能值随着 NaF 浓度的增加而降低。在大多数能量范围内,NFCB3 样品的质量衰减系数和有效原子序数值明显高于其他商用 SCHOTT 玻璃。因此,建议将 NFCB3 玻璃材料用于医疗和核领域的特殊应用,因为在这些应用中,出色的介电、阻抗、辐射衰减特性和透明度至关重要。
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Impact of NaF on electrical and radiation shielding properties of CdO-B2O3 glass system
xNaF-(40-x)CdO-60B2O3 glass system (NFCBx) was prepared using the melt quenching technique, where x = 5, 10, 15. 20, 25, 30 35 mol %. All prepared samples were characterized using impedance spectroscopy in the frequency range of 50Hz to 5 MHz. Moreover, these samples were subjected to a gamma radiation shielding test using the WinCOM computer program across a wide photon energy range. The impedance spectra from room temperature to 623K with an increment of 50K were recorded. Parameters like bulk resistance (Rb), bulk capacitance (Cb), relaxation time, activation energies, mass attenuation coefficient and Effective Atomic Number were evaluated. The conductivity of the prepared glass samples was independent of frequency at lower frequencies. Still, it varied at higher frequencies. The bulk capacitance increases with an increase in temperature and NaF concentration. Activation energy values are found to decrease as NaF concentration rises. The NFCB3 sample exhibited significantly higher mass attenuation coefficient and Effective Atomic Number values than other commercial SCHOTT glasses across most energy ranges. Hence, NFCB3 glass material is recommended for specialized applications in medical and nuclear settings where excellent dielectric, impedance, radiation attenuation properties and transparency are crucial.
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来源期刊
自引率
5.90%
发文量
130
审稿时长
16 weeks
期刊介绍: Journal of Radiation Research and Applied Sciences provides a high quality medium for the publication of substantial, original and scientific and technological papers on the development and applications of nuclear, radiation and isotopes in biology, medicine, drugs, biochemistry, microbiology, agriculture, entomology, food technology, chemistry, physics, solid states, engineering, environmental and applied sciences.
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