用于光催化转化苄胺的聚酰亚胺光催化材料

IF 0.9 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Russian Journal of General Chemistry Pub Date : 2024-10-29 DOI:10.1134/S1070363224090263
H. Chen, G.-S. Wang, Y. -X. Xue, X. Zhang
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引用次数: 0

摘要

采用一锅热聚合法在不同温度下制备了掺硫聚酰亚胺。通过 SEM、XRD 和 FT-IR 进行的相分析表明,合成的聚酰亚胺具有良好的结构和结晶度。采用一锅热聚合法在不同温度下制备了掺硫聚酰亚胺。通过扫描电镜、X 射线衍射和傅立叶变换红外光谱进行的相分析表明,合成的聚酰亚胺具有良好的结构和结晶度。紫外漫反射、交流阻抗、荧光光谱和光电流测试结果表明,在 325°C 下合成的聚酰亚胺具有更好的光电性能。它被应用于光催化苄胺偶联实验,在 8.5 小时的光照下具有良好的产率和选择性。紫外漫反射、交流阻抗、荧光光谱和光电流测试结果表明,在 325°C 下合成的聚酰亚胺具有更好的光电性能。它被应用于光催化苄胺偶联实验,在 8.5 小时的光照下具有良好的产率和选择性。
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Polyimide Photocatalytic Material for Photocatalytic Conversion of Benzylamine

The sulfur-doped polyimides were prepared at different temperatures by one-pot hot polymerization method. Phase analysis by SEM, XRD and FT-IR showed that the synthesized polyimides had good structure and crystallinity. The sulfur-doped polyimides were prepared at different temperatures by one-pot hot polymerization method. Phase analysis by SEM, XRD and FT-IR showed that the synthesized polyimides had good structure and crystallinity. The results of UV diffuse reflection, AC impedance, fluorescence spectrum and photocurrent test show that the polyimide synthesized at 325°C has better photoelectric performance. It has been applied to the photocatalytic benzylamine coupling experiment and has good yield and selectivity under 8.5 hours of illumination. The results of UV diffuse reflection, AC impedance, fluorescence spectrum and photocurrent test show that the polyimide synthesized at 325°C has better photoelectric performance. It has been applied to the photocatalytic benzylamine coupling experiment and has good yield and selectivity under 8.5 h of illumination.

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来源期刊
CiteScore
1.40
自引率
22.20%
发文量
252
审稿时长
2-4 weeks
期刊介绍: Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.
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