{"title":"PSN-PIN-PT 铁电陶瓷在 MPB 附近的相结构演化和电学特性","authors":"Menghao Wang, Pinyang Fang, Xiaoshuai Zuo, Feifei Guo, Wei Long, Xiaojuan Li, Zengzhe Xi","doi":"10.1007/s10971-024-06545-z","DOIUrl":null,"url":null,"abstract":"<div><p>In order to explore the ceramic composition in the morphotropic phase boundary suitable for the high temperature electronic components, Pb(Sc<sub>1/2</sub>Nb<sub>1/2</sub>)O<sub>3</sub>-Pb(In<sub>1/2</sub>Nb<sub>1/2</sub>)O<sub>3</sub>-PbTiO<sub>3</sub>(PSN-PIN-PT) ceramics were designed and prepared by using the solid-state reaction method. Effect of the ceramic composition on the phase structure and electric properties of the PSN-PIN-PT ceramics were investigated. For 0.40PSN-(0.60-<i>x</i>)PIN-<i>x</i>PT(<i>x</i> = 0.360, 0.375, 0.390, 0.405), the increase in the PT could improve gradually Curie temperature <i>T</i><sub>c</sub> (262–292°C), but will reduce the phase transition <i>T</i><sub>R-T</sub> (94–181 °C). Maximum of piezoelectric coefficient <i>d</i><sub>33</sub> (578 pC/N) could be obtained in the 0.40PSN-0.21PIN-0.39PT ceramics, together with large residual polarization <i>P</i><sub>r</sub> (~36.7 µC/cm<sup>2</sup>) and high coercive field <i>E</i><sub>c</sub> (~9.3 kV/cm). These performances make the PSN-PIN-PT ceramics have great potential applications in the high temperature device.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":664,"journal":{"name":"Journal of Sol-Gel Science and Technology","volume":"112 2","pages":"614 - 623"},"PeriodicalIF":2.3000,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Phase structure evolution and electric properties of PSN-PIN-PT ferroelectric ceramics near MPB\",\"authors\":\"Menghao Wang, Pinyang Fang, Xiaoshuai Zuo, Feifei Guo, Wei Long, Xiaojuan Li, Zengzhe Xi\",\"doi\":\"10.1007/s10971-024-06545-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In order to explore the ceramic composition in the morphotropic phase boundary suitable for the high temperature electronic components, Pb(Sc<sub>1/2</sub>Nb<sub>1/2</sub>)O<sub>3</sub>-Pb(In<sub>1/2</sub>Nb<sub>1/2</sub>)O<sub>3</sub>-PbTiO<sub>3</sub>(PSN-PIN-PT) ceramics were designed and prepared by using the solid-state reaction method. Effect of the ceramic composition on the phase structure and electric properties of the PSN-PIN-PT ceramics were investigated. For 0.40PSN-(0.60-<i>x</i>)PIN-<i>x</i>PT(<i>x</i> = 0.360, 0.375, 0.390, 0.405), the increase in the PT could improve gradually Curie temperature <i>T</i><sub>c</sub> (262–292°C), but will reduce the phase transition <i>T</i><sub>R-T</sub> (94–181 °C). Maximum of piezoelectric coefficient <i>d</i><sub>33</sub> (578 pC/N) could be obtained in the 0.40PSN-0.21PIN-0.39PT ceramics, together with large residual polarization <i>P</i><sub>r</sub> (~36.7 µC/cm<sup>2</sup>) and high coercive field <i>E</i><sub>c</sub> (~9.3 kV/cm). These performances make the PSN-PIN-PT ceramics have great potential applications in the high temperature device.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":664,\"journal\":{\"name\":\"Journal of Sol-Gel Science and Technology\",\"volume\":\"112 2\",\"pages\":\"614 - 623\"},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2024-09-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Sol-Gel Science and Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10971-024-06545-z\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Sol-Gel Science and Technology","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s10971-024-06545-z","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Phase structure evolution and electric properties of PSN-PIN-PT ferroelectric ceramics near MPB
In order to explore the ceramic composition in the morphotropic phase boundary suitable for the high temperature electronic components, Pb(Sc1/2Nb1/2)O3-Pb(In1/2Nb1/2)O3-PbTiO3(PSN-PIN-PT) ceramics were designed and prepared by using the solid-state reaction method. Effect of the ceramic composition on the phase structure and electric properties of the PSN-PIN-PT ceramics were investigated. For 0.40PSN-(0.60-x)PIN-xPT(x = 0.360, 0.375, 0.390, 0.405), the increase in the PT could improve gradually Curie temperature Tc (262–292°C), but will reduce the phase transition TR-T (94–181 °C). Maximum of piezoelectric coefficient d33 (578 pC/N) could be obtained in the 0.40PSN-0.21PIN-0.39PT ceramics, together with large residual polarization Pr (~36.7 µC/cm2) and high coercive field Ec (~9.3 kV/cm). These performances make the PSN-PIN-PT ceramics have great potential applications in the high temperature device.
期刊介绍：
The primary objective of the Journal of Sol-Gel Science and Technology (JSST), the official journal of the International Sol-Gel Society, is to provide an international forum for the dissemination of scientific, technological, and general knowledge about materials processed by chemical nanotechnologies known as the "sol-gel" process. The materials of interest include gels, gel-derived glasses, ceramics in form of nano- and micro-powders, bulk, fibres, thin films and coatings as well as more recent materials such as hybrid organic-inorganic materials and composites. Such materials exhibit a wide range of optical, electronic, magnetic, chemical, environmental, and biomedical properties and functionalities. Methods for producing sol-gel-derived materials and the industrial uses of these materials are also of great interest.
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