非晶/晶体异质结构硫化铟(III)/碳,具有良好的动力学特性和高容量锂存储能力

IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Advanced Composites and Hybrid Materials Pub Date : 2024-10-29 DOI:10.1007/s42114-024-01041-y
Yinghui Xue, Tianjie Xu, Yao Guo, Haixiang Song, Yuhua Wang, Zhanhu Guo, Jianxin Li, Huihui Zhao, Xiaojing Bai, Changwei Lai
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引用次数: 0

摘要

纳米结构金属硫化物(MSs)因其高比容量和地球上丰富的原材料而被认为是锂离子电池(LIBs)的前景阳极。然而,导电性差和体积膨胀阻碍了它们的应用。在此,我们报告了碳包覆非晶/晶体硫化铟纳米管的设计,其中使用了 MIL-68 (In) 金属有机框架 (MOF) 作为前驱体,通过溶热过程生成 In2S3/碳 (In2S3/C)。非晶/晶体结构的构建不仅结合了非晶结构离子通道丰富的优点,还具有高晶体传导性和促进离子传输的特点。在电流密度为 0.5 A g-1 的情况下,锂电池的 In2S3/C 阳极在循环 500 次后可达到 835 mAh g-1 的优异性能。In2S3/C 还显示出出色的长期性能,在 2 A g-1 电流密度下可达到 717 mAh g-1。通过动力学分析和原位 X 射线光电子能谱研究阐明了锂存储机制。进一步的密度泛函理论(DFT)计算表明,In2S3/C 电极具有低吸附能和快速扩散动力学。总之,MOF 衍生的非晶/晶体 In2S3/C 比商用 In2S3 具有更好的电化学性能。这项研究将激发人们对 MS 的探索,并发现潜在的 "璞玉"。
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Amorphous/crystalline heterostructured indium (III) sulfide/carbon with favorable kinetics and high capacity for lithium storage

Nanostructured metal sulfides (MSs) are considered prospective anodes for Li-ion batteries (LIBs) due to their high specific capacity and abundant raw materials on Earth. Nevertheless, the poor conductivity and volume expansion hinder their application. Here, we report the design of amorphous/crystalline indium sulfide nanotubes coated by carbon, in which MIL-68 (In) metal–organic frameworks (MOF) are used as a precursor to generate In2S3/carbon (In2S3/C) through a solvothermal process. The construction of amorphous/crystalline structure not only combines the advantages of abundant ion channels of amorphous structure, but also has high crystal conductivity and promotes ion transport. The In2S3/C anode of LIBs exhibits excellent performance of 835 mAh g−1 at the current density of 0.5 A g−1 after 500 cycles. In2S3/C also shows outstanding long-term performance with 717 mAh g−1 at 2 A g−1. The lithium storage mechanism is elucidated through kinetic analysis and ex situ X-ray photoelectron spectroscopy investigations. Further density functional theory (DFT) calculations indicate that In2S3/C electrodes have low adsorption energies and fast diffusion kinetics. In a word, the MOF-derived amorphous/crystalline In2S3/C exhibits better electrochemical performances than commercial In2S3. This research will inspire the exploration of MSs as well as detect potential “diamonds in the rough.”

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来源期刊
CiteScore
26.00
自引率
21.40%
发文量
185
期刊介绍: Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
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