{"title":"C-烷基取代的-1,5,10,14-四氮杂环十八碳-4,13-二烯与羧酸卤化物的相互作用是合成 C-和 N-酰基-2,3,6,7,8,9-六氢-1H-1,5-二氮杂蒽的新方法","authors":"N. A. Anisimova, V. V. Mikhailov","doi":"10.1134/S1070363224090044","DOIUrl":null,"url":null,"abstract":"<p>The reactions of 2,2,4,11,11,13-hexamethyl-1,5,10,14-tetraazacyclooctadeca-4,13-diene with carboxylic acid chlorohydrides produced <i>C</i>- and <i>N</i>-acyl substituted 2,3,6,7,8,9-hexahydro-1<i>H</i>-1,5-diazonines. The structure of the obtained <i>C</i>- and <i>N</i>-acyldiazonines was studied by <sup>1</sup>H and <sup>13</sup>C NMR spectroscopy using two-dimensional experiments <sup>1</sup>H-<sup>13</sup>C HMQC, HMBC, <sup>1</sup>H-<sup>1</sup>H COSY.</p>","PeriodicalId":761,"journal":{"name":"Russian Journal of General Chemistry","volume":"94 9","pages":"2248 - 2254"},"PeriodicalIF":0.9000,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Interaction of C-Alkylsubstituted-1,5,10,14-tetraazacyclooctadeca-4,13-diene with Carboxylic Acid Halides As a New Method for the Synthesis of C- and N-Acyl-2,3,6,7,8,9-hexahydro-1H-1,5-diazonines\",\"authors\":\"N. A. Anisimova, V. V. Mikhailov\",\"doi\":\"10.1134/S1070363224090044\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The reactions of 2,2,4,11,11,13-hexamethyl-1,5,10,14-tetraazacyclooctadeca-4,13-diene with carboxylic acid chlorohydrides produced <i>C</i>- and <i>N</i>-acyl substituted 2,3,6,7,8,9-hexahydro-1<i>H</i>-1,5-diazonines. The structure of the obtained <i>C</i>- and <i>N</i>-acyldiazonines was studied by <sup>1</sup>H and <sup>13</sup>C NMR spectroscopy using two-dimensional experiments <sup>1</sup>H-<sup>13</sup>C HMQC, HMBC, <sup>1</sup>H-<sup>1</sup>H COSY.</p>\",\"PeriodicalId\":761,\"journal\":{\"name\":\"Russian Journal of General Chemistry\",\"volume\":\"94 9\",\"pages\":\"2248 - 2254\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2024-10-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of General Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070363224090044\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of General Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070363224090044","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Interaction of C-Alkylsubstituted-1,5,10,14-tetraazacyclooctadeca-4,13-diene with Carboxylic Acid Halides As a New Method for the Synthesis of C- and N-Acyl-2,3,6,7,8,9-hexahydro-1H-1,5-diazonines
The reactions of 2,2,4,11,11,13-hexamethyl-1,5,10,14-tetraazacyclooctadeca-4,13-diene with carboxylic acid chlorohydrides produced C- and N-acyl substituted 2,3,6,7,8,9-hexahydro-1H-1,5-diazonines. The structure of the obtained C- and N-acyldiazonines was studied by 1H and 13C NMR spectroscopy using two-dimensional experiments 1H-13C HMQC, HMBC, 1H-1H COSY.
期刊介绍：
Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.
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