基于 4-芳基-2-羟基-5,7,8-三甲基苯并[e][1,2]氧膦-2-氧化物的新型不对称笼状膦酸盐的合成

IF 0.9 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Russian Journal of General Chemistry Pub Date : 2024-10-29 DOI:10.1134/S107036322409007X
A. V. Zalaltdinova, Yu. M. Sadykova, A. S. Gazizov, A. K. Smailov, А. R. Burilov
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引用次数: 0

摘要

通过氧化膦与 β-resorcylic酸的反应获得了一种新的膦黄酮类化合物。以 4-芳基-2-羟基-5,7,8-三甲基苯并[e][1,2]氧化膦-2-氧化物为基础,通过分子内杂环合成新的不对称笼状膦酸盐。通过 1H、13С 和 31P NMR、IR 光谱和质谱数据证实了所有获得化合物的组成和结构。
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Synthesis of New Unsymmetrical Cage Phosphonates Based on 4-Aryl-2-hydroxy-5,7,8-trimethylbenzo[e][1,2]oxaphosphinine-2-oxides

A new phosphaneoflavonoid was obtained by the reaction oxaphosphinine with β-resorcylic acid. A method was proposed for the synthesis of new unsymmetrical cage phosphonates based on 4-aryl-2-hydroxy-5,7,8-trimethylbenzo[e][1,2]oxaphosphinine-2-oxides as a result of intramolecular heterocyclization. Composition and structure of all the obtained compounds were confirmed by 1H, 13С and 31P NMR, IR spectroscopy and mass spectrometry data.

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来源期刊
CiteScore
1.40
自引率
22.20%
发文量
252
审稿时长
2-4 weeks
期刊介绍: Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.
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