过渡金属/相转移催化剂的联合不对称催化研究进展

IF 2.5 3区 化学 Q2 CHEMISTRY, ORGANIC European Journal of Organic Chemistry Pub Date : 2024-10-29 DOI:10.1002/ejoc.202401088
Yi-Fan Dong, Si-Ru Wang, Zhi-Yong Han, Xiang Wu
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引用次数: 0

摘要

相转移催化剂(PTC)是一种化学制剂,可促进分子或离子在不同反应相之间的转移,从而加速异相反应过程。过渡金属催化剂在打破惰性化学键和形成新的碳-碳键方面具有多功能性,因而享有盛誉。在过去的二十年里,将金属催化剂与相转移催化剂相结合已成为现代有机合成中一种极具价值和适应性的策略。这种组合催化方法凸显了增强的合成能力,并展示了这两种催化体系合并的好处。本综述概述了利用金属催化剂和相转移催化剂之间的协同作用进行不对称催化的最新进展,重点介绍它们在快速、高效合成具有精确立体化学性质的复杂有机分子中的作用。
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Advances in Combined Asymmetric Catalysis of Transition Metal/Phase Transfer Catalysts
Phase-transfer catalysts (PTCs) are chemical agents that facilitate the transfer of molecules or ions between different reaction phases, thereby accelerating heterogeneous reaction processes. Transition metal catalysts are renowned for their versatility in breaking inert chemical bonds and forming new carbon-carbon bonds. Over the past two decades, integrating metal catalysts with phase-transfer catalysts has emerged as a highly valuable and adaptable strategy in modern organic synthesis. This combined catalytic approach highlights the enhanced synthetic capabilities and demonstrates the benefits of merging these two catalytic systems. This review provides an overview of recent advancements in asymmetric catalysis that utilize the synergy between metal and phase-transfer catalysts, focusing on their role in the rapid and efficient synthesis of complex organic molecules with precise stereochemistry.
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来源期刊
CiteScore
5.40
自引率
3.60%
发文量
752
审稿时长
1 months
期刊介绍: The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.
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