{"title":"硼烷硫醇钯催化合成硼烷硫化物。","authors":"Natsuki Minematsu, Yuji Nishii and Koji Hirano","doi":"10.1039/D4CC03934C","DOIUrl":null,"url":null,"abstract":"<p >Carboranes are an interesting class of aromatic molecules with icosahedral geometry, high stability, and unique electronic effects. We herein report a Pd-catalysed coupling reaction of carborane thiols with aryl halides. This protocol was applicable to the controlled synthesis of di(carboranyl) sulfides, and their catalytic performance for aromatic halogenation was examined.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":null,"pages":null},"PeriodicalIF":4.3000,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Pd-Catalysed synthesis of carborane sulfides from carborane thiols†\",\"authors\":\"Natsuki Minematsu, Yuji Nishii and Koji Hirano\",\"doi\":\"10.1039/D4CC03934C\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Carboranes are an interesting class of aromatic molecules with icosahedral geometry, high stability, and unique electronic effects. We herein report a Pd-catalysed coupling reaction of carborane thiols with aryl halides. This protocol was applicable to the controlled synthesis of di(carboranyl) sulfides, and their catalytic performance for aromatic halogenation was examined.</p>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-10-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/cc/d4cc03934c\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/cc/d4cc03934c","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Pd-Catalysed synthesis of carborane sulfides from carborane thiols†
Carboranes are an interesting class of aromatic molecules with icosahedral geometry, high stability, and unique electronic effects. We herein report a Pd-catalysed coupling reaction of carborane thiols with aryl halides. This protocol was applicable to the controlled synthesis of di(carboranyl) sulfides, and their catalytic performance for aromatic halogenation was examined.
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