{"title":"硼烷硫醇钯催化合成硼烷硫化物。","authors":"Natsuki Minematsu , Yuji Nishii , Koji Hirano","doi":"10.1039/d4cc03934c","DOIUrl":null,"url":null,"abstract":"<div><div>Carboranes are an interesting class of aromatic molecules with icosahedral geometry, high stability, and unique electronic effects. We herein report a Pd-catalysed coupling reaction of carborane thiols with aryl halides. This protocol was applicable to the controlled synthesis of di(carboranyl) sulfides, and their catalytic performance for aromatic halogenation was examined.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"60 92","pages":"Pages 13594-13597"},"PeriodicalIF":4.2000,"publicationDate":"2024-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Pd-Catalysed synthesis of carborane sulfides from carborane thiols†\",\"authors\":\"Natsuki Minematsu , Yuji Nishii , Koji Hirano\",\"doi\":\"10.1039/d4cc03934c\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Carboranes are an interesting class of aromatic molecules with icosahedral geometry, high stability, and unique electronic effects. We herein report a Pd-catalysed coupling reaction of carborane thiols with aryl halides. This protocol was applicable to the controlled synthesis of di(carboranyl) sulfides, and their catalytic performance for aromatic halogenation was examined.</div></div>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"60 92\",\"pages\":\"Pages 13594-13597\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2024-10-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1359734524022456\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/10/31 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734524022456","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/10/31 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Pd-Catalysed synthesis of carborane sulfides from carborane thiols†
Carboranes are an interesting class of aromatic molecules with icosahedral geometry, high stability, and unique electronic effects. We herein report a Pd-catalysed coupling reaction of carborane thiols with aryl halides. This protocol was applicable to the controlled synthesis of di(carboranyl) sulfides, and their catalytic performance for aromatic halogenation was examined.
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