{"title":"基于四氨基酞菁铜氧化石墨烯共价化合物的光电化学传感器,用于灵敏检测头孢唑啉钠","authors":"Shaohua Luo , Xinman Tu , Jun Li","doi":"10.1016/j.ijoes.2024.100844","DOIUrl":null,"url":null,"abstract":"<div><div>In the present research, a novel photoelectrochemical (PEC) sensor was built to detect cefazolin sodium. A copper tetraamino phthalocyanine (CuTAPc) covalently linked graphene oxide compound (CuTAPc-GO) was fabricated successfully by covalent bonding of CuTAPc with graphene oxide (GO). The novel PEC sensing platform was prepared using CuTAPc-GO as a photoelectric material. The prepared PEC sensor showed a higher PEC efficiency under red light. In the perfect conditions, the PEC sensor exhibited a linear correlation in detecting cefazolin sodium concentrations between 0.25 and 12.5 μM, featuring a detection limit at 0.15 μM. Furthermore, the manufacturing sensor was employed to detect cefazolin sodium in a real-world sample, demonstrating commendable sensitivity and stability. Thus, our study provides a new method for cefazolin sodium detection.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"19 12","pages":"Article 100844"},"PeriodicalIF":1.3000,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Photoelectrochemical sensor based on copper tetraamino phthalocyanine graphene oxide covalent compound for sensitive detection of cefazolin sodium\",\"authors\":\"Shaohua Luo , Xinman Tu , Jun Li\",\"doi\":\"10.1016/j.ijoes.2024.100844\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In the present research, a novel photoelectrochemical (PEC) sensor was built to detect cefazolin sodium. A copper tetraamino phthalocyanine (CuTAPc) covalently linked graphene oxide compound (CuTAPc-GO) was fabricated successfully by covalent bonding of CuTAPc with graphene oxide (GO). The novel PEC sensing platform was prepared using CuTAPc-GO as a photoelectric material. The prepared PEC sensor showed a higher PEC efficiency under red light. In the perfect conditions, the PEC sensor exhibited a linear correlation in detecting cefazolin sodium concentrations between 0.25 and 12.5 μM, featuring a detection limit at 0.15 μM. Furthermore, the manufacturing sensor was employed to detect cefazolin sodium in a real-world sample, demonstrating commendable sensitivity and stability. Thus, our study provides a new method for cefazolin sodium detection.</div></div>\",\"PeriodicalId\":13872,\"journal\":{\"name\":\"International Journal of Electrochemical Science\",\"volume\":\"19 12\",\"pages\":\"Article 100844\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2024-10-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Electrochemical Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1452398124003869\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Electrochemical Science","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1452398124003869","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
Photoelectrochemical sensor based on copper tetraamino phthalocyanine graphene oxide covalent compound for sensitive detection of cefazolin sodium
In the present research, a novel photoelectrochemical (PEC) sensor was built to detect cefazolin sodium. A copper tetraamino phthalocyanine (CuTAPc) covalently linked graphene oxide compound (CuTAPc-GO) was fabricated successfully by covalent bonding of CuTAPc with graphene oxide (GO). The novel PEC sensing platform was prepared using CuTAPc-GO as a photoelectric material. The prepared PEC sensor showed a higher PEC efficiency under red light. In the perfect conditions, the PEC sensor exhibited a linear correlation in detecting cefazolin sodium concentrations between 0.25 and 12.5 μM, featuring a detection limit at 0.15 μM. Furthermore, the manufacturing sensor was employed to detect cefazolin sodium in a real-world sample, demonstrating commendable sensitivity and stability. Thus, our study provides a new method for cefazolin sodium detection.
期刊介绍:
International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry