{"title":"FeIII/g-C3N4 作为光催化剂在将糠醛转化为琥珀酸和马来酸过程中的协同效应：有望实现可持续化学转化和先进环境修复的方法","authors":"Mohammad Bashiri, Mona Hosseini-Sarvari","doi":"10.1016/j.biombioe.2024.107456","DOIUrl":null,"url":null,"abstract":"<div><div>Furfural is one of the biomass compounds <em>via</em> potential applications in the production of value-added chemicals. However, its conversion to valuable products is challenging due to its complex structure. In this study, Fe<sup>III</sup>/g-C<sub>3</sub>N<sub>4</sub>, a promising photocatalyst, is employed to facilitate the conversion of furfural under visible light conditions. The results demonstrate that the catalyst effectively promotes the switchable alteration of furfural into maleic acid, succinic acid, and furan. The production of maleic acid, succinic acid, and furan using a photocatalyst holds significant importance in the field of sustainable chemistry and renewable energy. These chemical compounds have various industrial applications and can be derived from renewable resources, making them environmentally friendly alternatives to traditional petrochemical-based products. By using electrochemical and photoelectrochemical analyses as well as various control experiments including reaction atmosphere and radical scavengers, a precise mechanism for the production of an active oxygen radical species has been presented.</div></div>","PeriodicalId":253,"journal":{"name":"Biomass & Bioenergy","volume":"191 ","pages":"Article 107456"},"PeriodicalIF":5.8000,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synergic effect of FeIII/g-C3N4 as photocatalyst for switchable alteration of furfural to succinic acid as well as maleic acid: A promising approach for sustainable chemical conversion and advanced environmental remediation\",\"authors\":\"Mohammad Bashiri, Mona Hosseini-Sarvari\",\"doi\":\"10.1016/j.biombioe.2024.107456\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Furfural is one of the biomass compounds <em>via</em> potential applications in the production of value-added chemicals. However, its conversion to valuable products is challenging due to its complex structure. In this study, Fe<sup>III</sup>/g-C<sub>3</sub>N<sub>4</sub>, a promising photocatalyst, is employed to facilitate the conversion of furfural under visible light conditions. The results demonstrate that the catalyst effectively promotes the switchable alteration of furfural into maleic acid, succinic acid, and furan. The production of maleic acid, succinic acid, and furan using a photocatalyst holds significant importance in the field of sustainable chemistry and renewable energy. These chemical compounds have various industrial applications and can be derived from renewable resources, making them environmentally friendly alternatives to traditional petrochemical-based products. By using electrochemical and photoelectrochemical analyses as well as various control experiments including reaction atmosphere and radical scavengers, a precise mechanism for the production of an active oxygen radical species has been presented.</div></div>\",\"PeriodicalId\":253,\"journal\":{\"name\":\"Biomass & Bioenergy\",\"volume\":\"191 \",\"pages\":\"Article 107456\"},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2024-10-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Biomass & Bioenergy\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0961953424004094\",\"RegionNum\":2,\"RegionCategory\":\"生物学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"AGRICULTURAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Biomass & Bioenergy","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0961953424004094","RegionNum":2,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"AGRICULTURAL ENGINEERING","Score":null,"Total":0}
Synergic effect of FeIII/g-C3N4 as photocatalyst for switchable alteration of furfural to succinic acid as well as maleic acid: A promising approach for sustainable chemical conversion and advanced environmental remediation
Furfural is one of the biomass compounds via potential applications in the production of value-added chemicals. However, its conversion to valuable products is challenging due to its complex structure. In this study, FeIII/g-C3N4, a promising photocatalyst, is employed to facilitate the conversion of furfural under visible light conditions. The results demonstrate that the catalyst effectively promotes the switchable alteration of furfural into maleic acid, succinic acid, and furan. The production of maleic acid, succinic acid, and furan using a photocatalyst holds significant importance in the field of sustainable chemistry and renewable energy. These chemical compounds have various industrial applications and can be derived from renewable resources, making them environmentally friendly alternatives to traditional petrochemical-based products. By using electrochemical and photoelectrochemical analyses as well as various control experiments including reaction atmosphere and radical scavengers, a precise mechanism for the production of an active oxygen radical species has been presented.
期刊介绍：
Biomass & Bioenergy is an international journal publishing original research papers and short communications, review articles and case studies on biological resources, chemical and biological processes, and biomass products for new renewable sources of energy and materials.
The scope of the journal extends to the environmental, management and economic aspects of biomass and bioenergy.
Key areas covered by the journal:
• Biomass: sources, energy crop production processes, genetic improvements, composition. Please note that research on these biomass subjects must be linked directly to bioenergy generation.
• Biological Residues: residues/rests from agricultural production, forestry and plantations (palm, sugar etc), processing industries, and municipal sources (MSW). Papers on the use of biomass residues through innovative processes/technological novelty and/or consideration of feedstock/system sustainability (or unsustainability) are welcomed. However waste treatment processes and pollution control or mitigation which are only tangentially related to bioenergy are not in the scope of the journal, as they are more suited to publications in the environmental arena. Papers that describe conventional waste streams (ie well described in existing literature) that do not empirically address ''new'' added value from the process are not suitable for submission to the journal.
• Bioenergy Processes: fermentations, thermochemical conversions, liquid and gaseous fuels, and petrochemical substitutes
• Bioenergy Utilization: direct combustion, gasification, electricity production, chemical processes, and by-product remediation
• Biomass and the Environment: carbon cycle, the net energy efficiency of bioenergy systems, assessment of sustainability, and biodiversity issues.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
