以大蒜粉和共晶溶剂为原料、掺杂杂原子的碳为载体的 Co-Ni 纳米粒子：在硝基烯烃还原中的应用

IF 4.3 3区材料科学 Q2 MATERIALS SCIENCE, COATINGS & FILMS Diamond and Related Materials Pub Date : 2024-10-16 DOI:10.1016/j.diamond.2024.111662

Kosar Azizi, Firouzeh Nemati, Marzie Sadat Mirhosseyni

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引用次数: 0

摘要

本文介绍了一种新型异相催化剂 PSN-C600-Co2:Ni1的合成过程，该催化剂设计用于硝基芳香族化合物的氢化反应。该催化剂是一种氮、硫、磷三重掺杂的多孔碳基质，其中含有双金属 Co 和 Ni 纳米颗粒。合成过程中使用了天然前体大蒜生物炭和生物可降解共晶溶剂。各种表征技术包括扫描电子显微镜（SEM）、X 射线能量衍射光谱（EDX）、元素图谱测量（MAP）、热重分析（TGA）、X 射线衍射（XRD）、红外光谱仪（FTIR）、透射电子显微镜 (TEM)、拉曼光谱以及氮吸附和解吸模式（N2 吸附-解吸等温线），来研究合成的 PSN-C600-Co2：Ni1 催化剂的特征和特性。

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Co–Ni nanoparticle supported on heteroatom-doped carbon derived from garlic powder and eutectic solvent: Its application in Nitroarenes reduction

This paper presents the synthesis of a novel heterogeneous catalyst, PSN-C600-Co2:Ni1, designed for the hydrogenation of nitroaromatic compounds. The catalyst is a porous carbon substrate triply doped with nitrogen, sulfur, and phosphorus, incorporating bimetallic Co and Ni nanoparticles. A natural precursor, garlic biochar, and a biodegradable eutectic solvent were used in the synthesis. Various characterization techniques, including Scanning Electron Microscope (SEM), X-Ray Energy Diffraction Spectroscopy (EDX), Elemental Mapping Measurements (MAP), Thermogravimetric Analysis (TGA), X-Ray Diffraction (XRD), Infrared Spectrometer (FTIR), Transmission Electron Microscope (TEM), Raman Spectroscopy, and Nitrogen Adsorption and Desorption Pattern (N₂ adsorption-desorption isotherm), were utilized to examine the features and properties of the synthesized PSN-C600-Co2:Ni1 catalyst.

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来源期刊

Diamond and Related Materials 工程技术-材料科学：综合

CiteScore

6.00

自引率

14.60%

发文量

702

审稿时长

2.1 months

期刊介绍： DRM is a leading international journal that publishes new fundamental and applied research on all forms of diamond, the integration of diamond with other advanced materials and development of technologies exploiting diamond. The synthesis, characterization and processing of single crystal diamond, polycrystalline films, nanodiamond powders and heterostructures with other advanced materials are encouraged topics for technical and review articles. In addition to diamond, the journal publishes manuscripts on the synthesis, characterization and application of other related materials including diamond-like carbons, carbon nanotubes, graphene, and boron and carbon nitrides. Articles are sought on the chemical functionalization of diamond and related materials as well as their use in electrochemistry, energy storage and conversion, chemical and biological sensing, imaging, thermal management, photonic and quantum applications, electron emission and electronic devices. The International Conference on Diamond and Carbon Materials has evolved into the largest and most well attended forum in the field of diamond, providing a forum to showcase the latest results in the science and technology of diamond and other carbon materials such as carbon nanotubes, graphene, and diamond-like carbon. Run annually in association with Diamond and Related Materials the conference provides junior and established researchers the opportunity to exchange the latest results ranging from fundamental physical and chemical concepts to applied research focusing on the next generation carbon-based devices.