过渡金属催化构建轴向手性羰基化合物

IF 2.5 3区 化学 Q2 CHEMISTRY, ORGANIC European Journal of Organic Chemistry Pub Date : 2024-11-01 DOI:10.1002/ejoc.202400995
Yu Yan, Min Pan, Jialin Ming, Jun-Ping Yue, Xiao-Wang Chen, Yong-Yuan Gui, Da-Gang Yu
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引用次数: 0

摘要

由于轴向手性羰基化合物在天然产品和药物中的普遍存在,以及在材料科学和催化领域的实用性,它们的合成在有机合成中引起了极大的兴趣。过渡金属催化方法已成为构建手性羰基化合物的有力工具,在已开发的各种方法中具有高效性、选择性和多功能性。本概念旨在全面概述过渡金属催化轴向手性羰基化合物不对称合成的最新进展,整合不同催化体系的分散工作。这一专题概念根据所采用的策略分为四种反应类型:交叉耦合反应、环化反应、非对称反应和其他 C-H 活化反应。
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Transition‐Metal‐Catalyzed Construction of Axially Chiral Carbonyl Compounds
The synthesis of axially chiral carbonyl compounds has attracted considerable interest in organic synthesis due to their prevalence in natural products and pharmaceuticals, as well as their utility in material science and catalysis. Transition‐metal‐catalyzed approaches have become powerful tools for their construction, offering high efficiency, selectivity, and versatility among the various methods developed. This concept aims to provide a comprehensive overview of recent advances in the transition‐metal‐catalyzed asymmetric synthesis of axially chiral carbonyl compounds, integrating scattered work with different catalytic systems. This feature concept is divided into four types of reactions based on the strategies employed: cross‐coupling reactions, cycloaddition reactions, desymmetrization reactions, and other C‒H activation reactions.
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来源期刊
CiteScore
5.40
自引率
3.60%
发文量
752
审稿时长
1 months
期刊介绍: The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.
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