硅烷自由基参与的烯烃和炔烃硅烷官能化反应

IF 2.5 3区化学 Q2 CHEMISTRY, ORGANIC European Journal of Organic Chemistry Pub Date : 2024-10-31 DOI:10.1002/ejoc.202401018

Yang Zheng, Yi-Jie Zhu, Yi-Nan Zhang, Fei Chen

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引用次数: 0

摘要

烯和炔是廉价易得的基础化学品。硅自由基参与的烯烃和炔烃硅烷化反应为直接构建有机硅化合物提供了有力的工具。与氢化硅烷化反应相比，硅烷官能化反应在构建多种有机硅化合物方面更具吸引力和优势，因此成为有机合成领域的研究重点。在此，我们将全面综述硅自由基参与的烯烃和炔烃硅烷官能团化反应的最新进展。

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Silyl Radical-Participated Silylfunctionalization of Alkenes and Alkynes

Alkenes and alkynes are inexpensive and readily available basic chemicals. Silyl radical-participated silylation of alkenes and alkynes provides a powerful tool for the direct construction of organosilicon compounds. Compared to hydrosilylation reactions, silylfunctionalization reactions are more attractive and advantageous in building diverse organosilicon compounds, which has led to their becoming a research focus in organic synthesis. Herein, we provide a comprehensive overview of recent advances in silyl radical-participated silylfunctionalization of alkenes and alkynes.

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来源期刊

European Journal of Organic Chemistry 化学-有机化学

CiteScore

5.40

自引率

3.60%

发文量

752

审稿时长

1 months

期刊介绍： The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.