From biomass waste to bioaerogels - An alternative sustainable approach for wastewater remediation.

The generation of municipal solid waste is projected to increase from 2.1 billion tonnes in 2023 to 3.8 billion tonnes by 2050. In 2020, the direct global cost of managing this waste was approximately USD 252 billion. When considering additional hidden costs-such as those arising from pollution, adverse health effects, and climate change due to inadequate waste disposal-the total cost escalates to USD 361 billion. Without significant improvements in waste management practices, this figure could nearly double by 2050, reaching an estimated USD 640.3 billion annually. Among municipal solid waste, biowaste accounts for roughly 44 % of the global municipal solid waste, translating to about 840 million tonnes annually. They are widely accessible and economical, offering a cost-effective alternative to traditional treatment materials. Transforming biomass waste into carbon-based materials (e.g., bioaerogels) is a sustainable practice that reduces waste and repurposes it for environmental remediation. This approach not only decreases the volume of waste directed to landfills and mitigates harmful greenhouse gas emissions from decomposition but also aligns with the principles of a circular economy. Furthermore, it supports sustainable development goals by addressing issues such as water scarcity and pollution while promoting waste valorization and resource efficiency. The unique properties of bioaerogels-including their porosity, multi-layered structure, and chemical adaptability-make them highly effective for the remediation of different water pollutants from aquatic bodies. This review article comprehensively delves into multifaceted wastewater remediation strategies -based bioaerogels such as coagulation and flocculation, advanced oxidation processes, membrane filtration, catalytic processes, water disinfection, Oil-water separation, biodegradation, and adsorption. Additionally, it examines different mechanisms of interaction such as surface adsorption, electrostatic interaction, van der Waals forces, ion exchange, surface precipitation, complexation, pore-filling, hydrophobic interactions, and π-π stacking. Moreover, it conducts an integrated techno-economic evaluation to assess their feasibility in wastewater treatment. By valorizing biomass waste, a closed-loop system can be established, where waste is transformed into valuable bioaerogels. This approach not only addresses challenges related to effluent pollution but also generates economic, environmental, and social benefits. Ultimately, the review underscores the transformative potential of bioaerogels in wastewater treatment, emphasizing their crucial role in supporting long-term environmental goals and advancing the principles of resource circularity.