Zifang Chi , Wenjing Li , Pengdong Zhang , Huai Li
{"title":"在两级垂直流构造湿地中同时去除钒和氮:性能和机制。","authors":"Zifang Chi , Wenjing Li , Pengdong Zhang , Huai Li","doi":"10.1016/j.chemosphere.2024.143663","DOIUrl":null,"url":null,"abstract":"<div><div>Vanadium (V(V)) and nitrate, as co-concomitant pollutants in water bodies, pose potential threats to the eco-environment and human health. This study was to reveal the feasibility of simultaneous removal of V(V) and nitrate in the series-wound vertical flow constructed wetlands (CWs) with iron ore (B-CWs)/manganese ore (C-CWs)-wood substrates. The results showed that B-CWs could achieve efficient V(V) and NO<sub>3</sub><sup>−</sup>-N removal with the influent of 2 and 10 mg/L (V(V)/NO<sub>3</sub><sup>−</sup>-N = 1:5), respectively. With the increase of V(V)/NO<sub>3</sub><sup>−</sup>-N ratio (V(V)/NO<sub>3</sub><sup>−</sup>-N = 1:1), B/C-CWs exhibited better combined pollution removal. Even when nitrate was removed (V(V)/NO<sub>3</sub><sup>−</sup>-N = 1:0), the systems could maintain a good capacity for V(V) removal. High V(V) (20 mg/L) significantly inhibited V(V) removal, with a slight recovery of the performance as the decrease of V(V) influent. High NO<sub>3</sub><sup>−</sup>-N concentration (10 mg/L) effectively enhanced V(V) removal and restored C-CWs to the better level. V(IV) precipitates/oxides were the main reducing end-products. High abundance of V(V)-reducing bacteria and iron/manganese cycling pumps ensured efficient V(V) removal.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":null,"pages":null},"PeriodicalIF":8.1000,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Simultaneous removal of vanadium and nitrogen in two-stage vertical flow constructed wetlands: Performance and mechanisms\",\"authors\":\"Zifang Chi , Wenjing Li , Pengdong Zhang , Huai Li\",\"doi\":\"10.1016/j.chemosphere.2024.143663\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Vanadium (V(V)) and nitrate, as co-concomitant pollutants in water bodies, pose potential threats to the eco-environment and human health. This study was to reveal the feasibility of simultaneous removal of V(V) and nitrate in the series-wound vertical flow constructed wetlands (CWs) with iron ore (B-CWs)/manganese ore (C-CWs)-wood substrates. The results showed that B-CWs could achieve efficient V(V) and NO<sub>3</sub><sup>−</sup>-N removal with the influent of 2 and 10 mg/L (V(V)/NO<sub>3</sub><sup>−</sup>-N = 1:5), respectively. With the increase of V(V)/NO<sub>3</sub><sup>−</sup>-N ratio (V(V)/NO<sub>3</sub><sup>−</sup>-N = 1:1), B/C-CWs exhibited better combined pollution removal. Even when nitrate was removed (V(V)/NO<sub>3</sub><sup>−</sup>-N = 1:0), the systems could maintain a good capacity for V(V) removal. High V(V) (20 mg/L) significantly inhibited V(V) removal, with a slight recovery of the performance as the decrease of V(V) influent. High NO<sub>3</sub><sup>−</sup>-N concentration (10 mg/L) effectively enhanced V(V) removal and restored C-CWs to the better level. V(IV) precipitates/oxides were the main reducing end-products. High abundance of V(V)-reducing bacteria and iron/manganese cycling pumps ensured efficient V(V) removal.</div></div>\",\"PeriodicalId\":276,\"journal\":{\"name\":\"Chemosphere\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":8.1000,\"publicationDate\":\"2024-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemosphere\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0045653524025633\",\"RegionNum\":2,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemosphere","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0045653524025633","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
Simultaneous removal of vanadium and nitrogen in two-stage vertical flow constructed wetlands: Performance and mechanisms
Vanadium (V(V)) and nitrate, as co-concomitant pollutants in water bodies, pose potential threats to the eco-environment and human health. This study was to reveal the feasibility of simultaneous removal of V(V) and nitrate in the series-wound vertical flow constructed wetlands (CWs) with iron ore (B-CWs)/manganese ore (C-CWs)-wood substrates. The results showed that B-CWs could achieve efficient V(V) and NO3−-N removal with the influent of 2 and 10 mg/L (V(V)/NO3−-N = 1:5), respectively. With the increase of V(V)/NO3−-N ratio (V(V)/NO3−-N = 1:1), B/C-CWs exhibited better combined pollution removal. Even when nitrate was removed (V(V)/NO3−-N = 1:0), the systems could maintain a good capacity for V(V) removal. High V(V) (20 mg/L) significantly inhibited V(V) removal, with a slight recovery of the performance as the decrease of V(V) influent. High NO3−-N concentration (10 mg/L) effectively enhanced V(V) removal and restored C-CWs to the better level. V(IV) precipitates/oxides were the main reducing end-products. High abundance of V(V)-reducing bacteria and iron/manganese cycling pumps ensured efficient V(V) removal.
期刊介绍:
Chemosphere, being an international multidisciplinary journal, is dedicated to publishing original communications and review articles on chemicals in the environment. The scope covers a wide range of topics, including the identification, quantification, behavior, fate, toxicology, treatment, and remediation of chemicals in the bio-, hydro-, litho-, and atmosphere, ensuring the broad dissemination of research in this field.