{"title":"热处理木材表面 Ce/TiO2/BTA-HALS 涂层的制备和人工风化特性","authors":"Dong Xing , Boshuai Fan","doi":"10.1016/j.indcrop.2024.119936","DOIUrl":null,"url":null,"abstract":"<div><div>Heat-treated wood has only short-term weathering resistance, while wood cracking, discoloring and other problems will appear in long-term outdoor environments. Therefore, it is necessary to enhance the anti-weathering properties of heat-treated wood. In this study, organic ultraviolet absorbers, light stabilizers and inorganic Cerium/Titanium dioxide (Ce/TiO<sub>2</sub>) ultraviolet shielding agents were compounded by the simple physical blending method, and the modifiers were loaded on the surface of heat-treated wood by brushing method. The UV-Vis spectrum showed the high transparency and UV shielding of the composite coating. After artificial weathering, the color difference (<em>ΔE</em>) of Ce/TiO<sub>2</sub>/BTA-HALS coated sample was only 1.64 and 2.68, which is significantly lower than 2.3 and 6.1 of the heat-treated sample. The surface roughness, scanning electron microscope and X-ray energy spectrum also showed that the stability of the coating was significantly improved, and the loss of inorganic particles has decreased. Fourier transform infrared spectroscopy and electron paramagnetic resonance proved that the modifier was successfully grafted on the surface of heat-treated wood. The composite coating has a certain synergistic effect in improving the weathering resistance of heat-treated wood and improves the film-forming property of the modifier and the stability of the coating during weathering.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":"222 ","pages":"Article 119936"},"PeriodicalIF":5.6000,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation and artificial weathering properties of Ce/TiO2/BTA-HALS coating on heat-treated wood surface\",\"authors\":\"Dong Xing , Boshuai Fan\",\"doi\":\"10.1016/j.indcrop.2024.119936\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Heat-treated wood has only short-term weathering resistance, while wood cracking, discoloring and other problems will appear in long-term outdoor environments. Therefore, it is necessary to enhance the anti-weathering properties of heat-treated wood. In this study, organic ultraviolet absorbers, light stabilizers and inorganic Cerium/Titanium dioxide (Ce/TiO<sub>2</sub>) ultraviolet shielding agents were compounded by the simple physical blending method, and the modifiers were loaded on the surface of heat-treated wood by brushing method. The UV-Vis spectrum showed the high transparency and UV shielding of the composite coating. After artificial weathering, the color difference (<em>ΔE</em>) of Ce/TiO<sub>2</sub>/BTA-HALS coated sample was only 1.64 and 2.68, which is significantly lower than 2.3 and 6.1 of the heat-treated sample. The surface roughness, scanning electron microscope and X-ray energy spectrum also showed that the stability of the coating was significantly improved, and the loss of inorganic particles has decreased. Fourier transform infrared spectroscopy and electron paramagnetic resonance proved that the modifier was successfully grafted on the surface of heat-treated wood. The composite coating has a certain synergistic effect in improving the weathering resistance of heat-treated wood and improves the film-forming property of the modifier and the stability of the coating during weathering.</div></div>\",\"PeriodicalId\":13581,\"journal\":{\"name\":\"Industrial Crops and Products\",\"volume\":\"222 \",\"pages\":\"Article 119936\"},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2024-11-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Industrial Crops and Products\",\"FirstCategoryId\":\"97\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0926669024019137\",\"RegionNum\":1,\"RegionCategory\":\"农林科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"AGRICULTURAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Industrial Crops and Products","FirstCategoryId":"97","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0926669024019137","RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"AGRICULTURAL ENGINEERING","Score":null,"Total":0}
引用次数: 0
摘要
经过热处理的木材只有短期的耐候性,而在长期的户外环境中会出现木材开裂、褪色等问题。因此,有必要提高热处理木材的抗风化性能。本研究采用简单的物理混合方法,将有机紫外线吸收剂、光稳定剂和无机二氧化铈/二氧化钛(Ce/TiO2)紫外线屏蔽剂复配,并通过刷涂方法将改性剂涂覆在热处理木材表面。紫外可见光谱显示,复合涂层具有很高的透明度和紫外线屏蔽性能。人工风化后,Ce/TiO2/BTA-HALS 涂层样品的色差(ΔE)仅为 1.64 和 2.68,明显低于热处理样品的 2.3 和 6.1。表面粗糙度、扫描电子显微镜和 X 射线能谱也表明,涂层的稳定性明显提高,无机颗粒的损失减少。傅立叶变换红外光谱和电子顺磁共振证明改性剂成功接枝到了热处理木材的表面。该复合涂层对提高热处理木材的耐候性有一定的协同作用,改善了改性剂的成膜性和涂层在风化过程中的稳定性。
Preparation and artificial weathering properties of Ce/TiO2/BTA-HALS coating on heat-treated wood surface
Heat-treated wood has only short-term weathering resistance, while wood cracking, discoloring and other problems will appear in long-term outdoor environments. Therefore, it is necessary to enhance the anti-weathering properties of heat-treated wood. In this study, organic ultraviolet absorbers, light stabilizers and inorganic Cerium/Titanium dioxide (Ce/TiO2) ultraviolet shielding agents were compounded by the simple physical blending method, and the modifiers were loaded on the surface of heat-treated wood by brushing method. The UV-Vis spectrum showed the high transparency and UV shielding of the composite coating. After artificial weathering, the color difference (ΔE) of Ce/TiO2/BTA-HALS coated sample was only 1.64 and 2.68, which is significantly lower than 2.3 and 6.1 of the heat-treated sample. The surface roughness, scanning electron microscope and X-ray energy spectrum also showed that the stability of the coating was significantly improved, and the loss of inorganic particles has decreased. Fourier transform infrared spectroscopy and electron paramagnetic resonance proved that the modifier was successfully grafted on the surface of heat-treated wood. The composite coating has a certain synergistic effect in improving the weathering resistance of heat-treated wood and improves the film-forming property of the modifier and the stability of the coating during weathering.
期刊介绍:
Industrial Crops and Products is an International Journal publishing academic and industrial research on industrial (defined as non-food/non-feed) crops and products. Papers concern both crop-oriented and bio-based materials from crops-oriented research, and should be of interest to an international audience, hypothesis driven, and where comparisons are made statistics performed.