{"title":"含硫和磷的生物基高折射率聚合物：取代基对聚合物光学特性的影响。","authors":"Zongao Dou, Hemin Zhang, Jiajun Li, Jing Sun, Qiang Fang","doi":"10.1021/acs.biomac.4c01291","DOIUrl":null,"url":null,"abstract":"<p><p>Four biobased phosphate-containing aryl monomers with methoxy, allyl, and vinyl groups as substituents have been successfully synthesized. Copolymerizing these monomers with thiophenol or mercaptans via the photoclick thiol-ene reaction gives the polymers with refractive indices (<i>n</i><sub>D</sub>) of 1.63-1.70 and Abbe numbers (<i>v</i><sub>D</sub>) of 12.8-38.5. An investigation of the relationship of the <i>v</i><sub>D</sub> values with the substituents on the benzene rings of the monomers indicates that methoxy and vinyl groups can collectively increase the <i>v</i><sub>D</sub> values. In comparison with allyl groups, vinyl groups endow the polymers with both higher <i>n</i><sub>D</sub> and <i>v</i><sub>D</sub>. Moreover, these polymers also display high transmittance, high thermostability, and low haze values in the visible-light region, suggesting that these biobased functional monomers are satisfactory precursors used in the fabrication of optical devices.</p>","PeriodicalId":30,"journal":{"name":"Biomacromolecules","volume":" ","pages":""},"PeriodicalIF":5.5000,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Biobased Sulfur- and Phosphate-Containing High-Refractive-Index Polymers: Substituent Effects on Optical Properties of Polymers.\",\"authors\":\"Zongao Dou, Hemin Zhang, Jiajun Li, Jing Sun, Qiang Fang\",\"doi\":\"10.1021/acs.biomac.4c01291\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Four biobased phosphate-containing aryl monomers with methoxy, allyl, and vinyl groups as substituents have been successfully synthesized. Copolymerizing these monomers with thiophenol or mercaptans via the photoclick thiol-ene reaction gives the polymers with refractive indices (<i>n</i><sub>D</sub>) of 1.63-1.70 and Abbe numbers (<i>v</i><sub>D</sub>) of 12.8-38.5. An investigation of the relationship of the <i>v</i><sub>D</sub> values with the substituents on the benzene rings of the monomers indicates that methoxy and vinyl groups can collectively increase the <i>v</i><sub>D</sub> values. In comparison with allyl groups, vinyl groups endow the polymers with both higher <i>n</i><sub>D</sub> and <i>v</i><sub>D</sub>. Moreover, these polymers also display high transmittance, high thermostability, and low haze values in the visible-light region, suggesting that these biobased functional monomers are satisfactory precursors used in the fabrication of optical devices.</p>\",\"PeriodicalId\":30,\"journal\":{\"name\":\"Biomacromolecules\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":5.5000,\"publicationDate\":\"2024-11-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Biomacromolecules\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.biomac.4c01291\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"BIOCHEMISTRY & MOLECULAR BIOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Biomacromolecules","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.biomac.4c01291","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"BIOCHEMISTRY & MOLECULAR BIOLOGY","Score":null,"Total":0}
Biobased Sulfur- and Phosphate-Containing High-Refractive-Index Polymers: Substituent Effects on Optical Properties of Polymers.
Four biobased phosphate-containing aryl monomers with methoxy, allyl, and vinyl groups as substituents have been successfully synthesized. Copolymerizing these monomers with thiophenol or mercaptans via the photoclick thiol-ene reaction gives the polymers with refractive indices (nD) of 1.63-1.70 and Abbe numbers (vD) of 12.8-38.5. An investigation of the relationship of the vD values with the substituents on the benzene rings of the monomers indicates that methoxy and vinyl groups can collectively increase the vD values. In comparison with allyl groups, vinyl groups endow the polymers with both higher nD and vD. Moreover, these polymers also display high transmittance, high thermostability, and low haze values in the visible-light region, suggesting that these biobased functional monomers are satisfactory precursors used in the fabrication of optical devices.
期刊介绍：
Biomacromolecules is a leading forum for the dissemination of cutting-edge research at the interface of polymer science and biology. Submissions to Biomacromolecules should contain strong elements of innovation in terms of macromolecular design, synthesis and characterization, or in the application of polymer materials to biology and medicine.
Topics covered by Biomacromolecules include, but are not exclusively limited to: sustainable polymers, polymers based on natural and renewable resources, degradable polymers, polymer conjugates, polymeric drugs, polymers in biocatalysis, biomacromolecular assembly, biomimetic polymers, polymer-biomineral hybrids, biomimetic-polymer processing, polymer recycling, bioactive polymer surfaces, original polymer design for biomedical applications such as immunotherapy, drug delivery, gene delivery, antimicrobial applications, diagnostic imaging and biosensing, polymers in tissue engineering and regenerative medicine, polymeric scaffolds and hydrogels for cell culture and delivery.
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