碳化硅增强聚合物生物复合材料板式热交换器的热特性分析

IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Journal of Thermal Analysis and Calorimetry Pub Date : 2024-10-21 DOI:10.1007/s10973-024-13624-4
Asih Melati, Abdelhakim Settar, Mounir Sahli, Khaled Chetehouna
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引用次数: 0

摘要

天然基复合材料的热性能仍然是其工业应用中的一个重大挑战,尤其是在板式热交换器(PHE)中。本研究旨在通过开发一种使用香蕉纤维(Bn-GBC)和碳化硅(SiC)作为填料增强的绿色环氧生物可降解树脂生物复合材料来应对这一挑战,目的是提高其导热性,并用于制造基于 PHE 聚合物的生物复合材料。研究探讨了在 Bn-GBC 中添加 2% 和 8% 碳化硅的效果,并在 Bn-GBC/SiC 样品上涂抹了由 29% 聚磷酸铵 (APP) 和 1% 硼酸组成的膨胀阻燃 (IFR) 涂料。制造过程采用了真空袋树脂传递模塑(VBRTM)技术。研究在氧气环境下进行了热重分析(TGA)测试,温度和加热速率变化等加工参数分别设定为 303-1173 K 和 5、10 和 15 °C min-1。通过计算动力学参数,研究了材料的动力学机制。活化能(Ea)采用无模型(弗里德曼和 KAS 方法)和扩展普鲁特-汤普金斯(Bna)拟合模型进行评估。总之,所有样品都确定了其动力学参数,使用 IFR 表明 Ea 值增加了约 10-14%。TGA 和锥形量热计的结果表明,与 2 质量%的 SiC 相比,使用 8 质量%的 SiC 提高了复合材料的热稳定性。此外,这两项热测试表明,使用 16 质量%的 IFR(29Exolit/1BA)涂层有助于保持热稳定性和延迟分解过程。因此,开发出了添加 8 质量%SiC 和不添加 SiC 的 PHE 原型。实验和数值热评估分析表明,与 PHE/0SiC 相比,PHE/8SiC 具有更高的传热性。
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Thermal characterization of plat heat exchanger made from polymer biocomposite reinforced by silicon carbide

The thermal performance of natural-based composites remains a significant challenge in their industrial applications, especially in plat heat exchanger (PHE). This study aims to address this challenge by developing a bio-composite material using Green-epoxy biodegradable resin reinforced with banana fibre (Bn-GBC) and silicon carbide (SiC) as a filler, with the goal of improving its thermal conductivity and for fabrication PHE polymer biocomposite based. The study explores the effects of adding 2 mass% and 8 mass% SiC to the Bn-GBC, and an intumescent fire retardant (IFR) coating consisting of 29 mass% ammonium polyphosphate (APP) and 1 mass% boric acid was applied to the Bn-GBC/SiC samples. The manufacturing process involved the use of vacuum bag resin transfer moulding (VBRTM) technique. The study conducted Thermogravimetric analysis (TGA) tests under an O2 atmosphere, with processing parameters such as temperature and variation in heating rates set at 303–1173 K and 5, 10, and 15 °C min−1, respectively. The kinetic mechanism in the material was examined by calculating the kinetic parameters. The activation energy (Ea) was evaluated using model-free (the Friedman and KAS approaches) and fitting model of the Expanded Prout-Tompkins (Bna). In conclusion, all samples defined their kinetic parameter, the use of IFR reveals that increases Ea value by approximately 10–14%. TGA and cone calorimeter results indicated that the use of 8 mass% SiC improved the thermal stability of the composite compared to 2 mass% SiC. Moreover, from both thermal tests indicate that the application of a 16 mass% IFR (29Exolit/1BA) coating helped maintain the thermal stability and delay decomposition process. Thus, the PHE prototype was developed with 8 mass% SiC addition and without SiC addition. The Experimental and numerical heat assessment analysis was performed, it is proven that PHE/8SiC has a higher heat transfer compared to PHE/0SiC.

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来源期刊
CiteScore
8.50
自引率
9.10%
发文量
577
审稿时长
3.8 months
期刊介绍: Journal of Thermal Analysis and Calorimetry is a fully peer reviewed journal publishing high quality papers covering all aspects of thermal analysis, calorimetry, and experimental thermodynamics. The journal publishes regular and special issues in twelve issues every year. The following types of papers are published: Original Research Papers, Short Communications, Reviews, Modern Instruments, Events and Book reviews. The subjects covered are: thermogravimetry, derivative thermogravimetry, differential thermal analysis, thermodilatometry, differential scanning calorimetry of all types, non-scanning calorimetry of all types, thermometry, evolved gas analysis, thermomechanical analysis, emanation thermal analysis, thermal conductivity, multiple techniques, and miscellaneous thermal methods (including the combination of the thermal method with various instrumental techniques), theory and instrumentation for thermal analysis and calorimetry.
期刊最新文献
Thermal characterization of plat heat exchanger made from polymer biocomposite reinforced by silicon carbide Recent advances in thermal analysis and calorimetry presented at the 3rd Journal of Thermal Analysis and Calorimetry Conference and 9th V4 (Joint Czech–Hungarian–Polish–Slovakian) Thermoanalytical Conference (2023) Spalling behavior of high-strength polypropylene fiber-reinforced concrete subjected to elevated temperature Review about the history of thermal analysis in Hungary Study of thermal behavior and crystallization kinetics of glass microspheres in the Y3Al5O12-Al2O3 system
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