在 NaFeZnMn 催化剂上将二氧化碳高选择性加氢转化为液体燃料

IF 2.3 4区 化学 Q3 CHEMISTRY, PHYSICAL Catalysis Letters Pub Date : 2024-11-08 DOI:10.1007/s10562-024-04869-7
Tong Zhang, Zhongrui Li, Juan Qiu, Jing Bai, Baowei Cao, Shihang Xu, Hanying Wang, Yunhua Xu, Lei Guo
{"title":"在 NaFeZnMn 催化剂上将二氧化碳高选择性加氢转化为液体燃料","authors":"Tong Zhang,&nbsp;Zhongrui Li,&nbsp;Juan Qiu,&nbsp;Jing Bai,&nbsp;Baowei Cao,&nbsp;Shihang Xu,&nbsp;Hanying Wang,&nbsp;Yunhua Xu,&nbsp;Lei Guo","doi":"10.1007/s10562-024-04869-7","DOIUrl":null,"url":null,"abstract":"<div><p>Direct synthesis of liquid fuel (C<sub>5+</sub> hydrocarbons) through CO<sub>2</sub> hydrogenation has attracted considerable interest. However, it is plagued by high selectivity of C<sub>1</sub> by-products (CO and CH<sub>4</sub>) and low reaction activity. Herein, we report that Na-FeZn catalysts promoted by a combination of metal additives and investigate their synergistic effect in the catalytic CO<sub>2</sub> hydrogenation reaction. The CO<sub>2</sub> conversion is high to 40.6% with the 68.3% C<sub>5+</sub> selectivity. The characteristic results reveal the specific surface area has a great influence on the catalytic performance. Furthermore, the synergistic effect of Mn in the catalyst enhances CO<sub>2</sub> adsorption while weakening H<sub>2</sub> adsorption, thus remarkably promoting the carbon chain growth and limiting the production of C<sub>1</sub> products. This study offers a promising approach to modulating the metal electronic environment and improving carbon efficiency for CO<sub>2</sub> hydrogenation reactions.</p><h3>Graphical Abstract</h3><p>We present a simple NaFeZnMn-S nanocatalyst that can effectively catalyze CO<sub>2</sub> hydrogenation to C<sub>5+</sub> hydrocarbons. The selectivity towards C<sub>5+</sub> hydrocarbons is as high as 68.3% at 40.6% CO<sub>2</sub> conversion.</p>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":508,"journal":{"name":"Catalysis Letters","volume":null,"pages":null},"PeriodicalIF":2.3000,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"High Selectivity CO2 Hydrogenation to Liquid Fuel Over NaFeZnMn Catalyst\",\"authors\":\"Tong Zhang,&nbsp;Zhongrui Li,&nbsp;Juan Qiu,&nbsp;Jing Bai,&nbsp;Baowei Cao,&nbsp;Shihang Xu,&nbsp;Hanying Wang,&nbsp;Yunhua Xu,&nbsp;Lei Guo\",\"doi\":\"10.1007/s10562-024-04869-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Direct synthesis of liquid fuel (C<sub>5+</sub> hydrocarbons) through CO<sub>2</sub> hydrogenation has attracted considerable interest. However, it is plagued by high selectivity of C<sub>1</sub> by-products (CO and CH<sub>4</sub>) and low reaction activity. Herein, we report that Na-FeZn catalysts promoted by a combination of metal additives and investigate their synergistic effect in the catalytic CO<sub>2</sub> hydrogenation reaction. The CO<sub>2</sub> conversion is high to 40.6% with the 68.3% C<sub>5+</sub> selectivity. The characteristic results reveal the specific surface area has a great influence on the catalytic performance. Furthermore, the synergistic effect of Mn in the catalyst enhances CO<sub>2</sub> adsorption while weakening H<sub>2</sub> adsorption, thus remarkably promoting the carbon chain growth and limiting the production of C<sub>1</sub> products. This study offers a promising approach to modulating the metal electronic environment and improving carbon efficiency for CO<sub>2</sub> hydrogenation reactions.</p><h3>Graphical Abstract</h3><p>We present a simple NaFeZnMn-S nanocatalyst that can effectively catalyze CO<sub>2</sub> hydrogenation to C<sub>5+</sub> hydrocarbons. The selectivity towards C<sub>5+</sub> hydrocarbons is as high as 68.3% at 40.6% CO<sub>2</sub> conversion.</p>\\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":508,\"journal\":{\"name\":\"Catalysis Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2024-11-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Letters\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10562-024-04869-7\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Letters","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10562-024-04869-7","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

摘要

通过 CO2 加氢直接合成液体燃料(C5+ 碳氢化合物)引起了广泛关注。然而,C1 副产物(CO 和 CH4)的高选择性和低反应活性使其备受困扰。在此,我们报告了由金属添加剂组合促进的 Na-FeZn 催化剂,并研究了它们在催化 CO2 加氢反应中的协同效应。二氧化碳转化率高达 40.6%,C5+ 选择性为 68.3%。特征结果表明,比表面积对催化性能有很大影响。此外,催化剂中 Mn 的协同作用增强了对 CO2 的吸附,同时削弱了对 H2 的吸附,从而显著促进了碳链的生长,限制了 C1 产物的产生。这项研究为调节金属电子环境和提高 CO2 加氢反应的碳效率提供了一种很有前景的方法。在 CO2 转化率为 40.6% 时,对 C5+ 碳氢化合物的选择性高达 68.3%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
High Selectivity CO2 Hydrogenation to Liquid Fuel Over NaFeZnMn Catalyst

Direct synthesis of liquid fuel (C5+ hydrocarbons) through CO2 hydrogenation has attracted considerable interest. However, it is plagued by high selectivity of C1 by-products (CO and CH4) and low reaction activity. Herein, we report that Na-FeZn catalysts promoted by a combination of metal additives and investigate their synergistic effect in the catalytic CO2 hydrogenation reaction. The CO2 conversion is high to 40.6% with the 68.3% C5+ selectivity. The characteristic results reveal the specific surface area has a great influence on the catalytic performance. Furthermore, the synergistic effect of Mn in the catalyst enhances CO2 adsorption while weakening H2 adsorption, thus remarkably promoting the carbon chain growth and limiting the production of C1 products. This study offers a promising approach to modulating the metal electronic environment and improving carbon efficiency for CO2 hydrogenation reactions.

Graphical Abstract

We present a simple NaFeZnMn-S nanocatalyst that can effectively catalyze CO2 hydrogenation to C5+ hydrocarbons. The selectivity towards C5+ hydrocarbons is as high as 68.3% at 40.6% CO2 conversion.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Catalysis Letters
Catalysis Letters 化学-物理化学
CiteScore
5.70
自引率
3.60%
发文量
327
审稿时长
1 months
期刊介绍: Catalysis Letters aim is the rapid publication of outstanding and high-impact original research articles in catalysis. The scope of the journal covers a broad range of topics in all fields of both applied and theoretical catalysis, including heterogeneous, homogeneous and biocatalysis. The high-quality original research articles published in Catalysis Letters are subject to rigorous peer review. Accepted papers are published online first and subsequently in print issues. All contributions must include a graphical abstract. Manuscripts should be written in English and the responsibility lies with the authors to ensure that they are grammatically and linguistically correct. Authors for whom English is not the working language are encouraged to consider using a professional language-editing service before submitting their manuscripts.
期刊最新文献
Ruthenium Cluster Decorated Titanium Dioxide Nanowire Arrays for Alkaline Hydrogen Evolution First Principles Study of Photocatalytic Water Splitting Hydrogen Production by SiI2 Nanotubes Plasma-Synthesized Combined Nitrogen and Cationic Species Doped-MnO2: Impact on Texture, Optical Properties, and Photocatalytic Activity Microscopic Investigation of CO Oxidation Reaction by Copper–Manganese Oxide Catalysts Sonochemical Synthesis of Ti1−x−yFexPbyO2 (with x and y = 0, 0.01, 0.03, 0.07): Structural Analysis, Influence of Radiation Type on Photocatalytic Activity and Assessment of Antimicrobial Properties
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1