L. N. Krasil’nikova, Ya. A. Khamidulin, V. I. Voshchikov, E. D. Vasilieva, A. K. Kychkin, Chi Van Nguyen, A. M. Nikolaev, Yu. E. Gorshkova, O. A. Shilova
{"title":"耐候性更强的有机硅涂料","authors":"L. N. Krasil’nikova, Ya. A. Khamidulin, V. I. Voshchikov, E. D. Vasilieva, A. K. Kychkin, Chi Van Nguyen, A. M. Nikolaev, Yu. E. Gorshkova, O. A. Shilova","doi":"10.1134/S1061933X24600593","DOIUrl":null,"url":null,"abstract":"<p>Currently, composites based on glass fibers and epoxy resins are successfully used to produce various structural elements. Such structures often serve under extreme conditions of both the Far North and the tropics, with such conditions having a destructive effect on the materials causing degradation of their properties. In this case, water resistance is an important characteristic of the materials. One of the ways to protect such materials is the use of organosilicate coatings (OSCs) obtained on the basis of organosilicon varnishes and highly dispersed hydrosilicates. This article presents the results of laboratory studies and field tests carried out in areas with very cold, as well as tropical savannah and subequatorial climates, of composite and metallic materials protected with OSCs. The objects of the studies are OSCs based on a binder, KO-921 varnish modified with the aim to improve weather resistance, primarily, moisture resistance, with poly(dimethylsiloxane) and epoxy resin. Water absorption, contact angle, and hardness of OSCs have been studied as depending on the composition of the polymer binders, and the optimal concentrations of the precursors have been determined. The results of field tests have shown that the developed OSCs retain their water-repellent properties during long-term exposure in different climatic conditions, thereby confirming their applicability to protecting various materials under the conditions of both tropics and the Far North.</p>","PeriodicalId":521,"journal":{"name":"Colloid Journal","volume":"86 5","pages":"719 - 729"},"PeriodicalIF":1.4000,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Weather-Resistant Organosilicate Coatings with Improved Water Resistance\",\"authors\":\"L. N. Krasil’nikova, Ya. A. Khamidulin, V. I. Voshchikov, E. D. Vasilieva, A. K. Kychkin, Chi Van Nguyen, A. M. Nikolaev, Yu. E. Gorshkova, O. A. Shilova\",\"doi\":\"10.1134/S1061933X24600593\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Currently, composites based on glass fibers and epoxy resins are successfully used to produce various structural elements. Such structures often serve under extreme conditions of both the Far North and the tropics, with such conditions having a destructive effect on the materials causing degradation of their properties. In this case, water resistance is an important characteristic of the materials. One of the ways to protect such materials is the use of organosilicate coatings (OSCs) obtained on the basis of organosilicon varnishes and highly dispersed hydrosilicates. This article presents the results of laboratory studies and field tests carried out in areas with very cold, as well as tropical savannah and subequatorial climates, of composite and metallic materials protected with OSCs. The objects of the studies are OSCs based on a binder, KO-921 varnish modified with the aim to improve weather resistance, primarily, moisture resistance, with poly(dimethylsiloxane) and epoxy resin. Water absorption, contact angle, and hardness of OSCs have been studied as depending on the composition of the polymer binders, and the optimal concentrations of the precursors have been determined. The results of field tests have shown that the developed OSCs retain their water-repellent properties during long-term exposure in different climatic conditions, thereby confirming their applicability to protecting various materials under the conditions of both tropics and the Far North.</p>\",\"PeriodicalId\":521,\"journal\":{\"name\":\"Colloid Journal\",\"volume\":\"86 5\",\"pages\":\"719 - 729\"},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-11-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Colloid Journal\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1061933X24600593\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Colloid Journal","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1061933X24600593","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Weather-Resistant Organosilicate Coatings with Improved Water Resistance
Currently, composites based on glass fibers and epoxy resins are successfully used to produce various structural elements. Such structures often serve under extreme conditions of both the Far North and the tropics, with such conditions having a destructive effect on the materials causing degradation of their properties. In this case, water resistance is an important characteristic of the materials. One of the ways to protect such materials is the use of organosilicate coatings (OSCs) obtained on the basis of organosilicon varnishes and highly dispersed hydrosilicates. This article presents the results of laboratory studies and field tests carried out in areas with very cold, as well as tropical savannah and subequatorial climates, of composite and metallic materials protected with OSCs. The objects of the studies are OSCs based on a binder, KO-921 varnish modified with the aim to improve weather resistance, primarily, moisture resistance, with poly(dimethylsiloxane) and epoxy resin. Water absorption, contact angle, and hardness of OSCs have been studied as depending on the composition of the polymer binders, and the optimal concentrations of the precursors have been determined. The results of field tests have shown that the developed OSCs retain their water-repellent properties during long-term exposure in different climatic conditions, thereby confirming their applicability to protecting various materials under the conditions of both tropics and the Far North.
期刊介绍:
Colloid Journal (Kolloidnyi Zhurnal) is the only journal in Russia that publishes the results of research in the area of chemical science dealing with the disperse state of matter and surface phenomena in disperse systems. The journal covers experimental and theoretical works on a great variety of colloid and surface phenomena: the structure and properties of interfaces; adsorption phenomena and structure of adsorption layers of surfactants; capillary phenomena; wetting films; wetting and spreading; and detergency. The formation of colloid systems, their molecular-kinetic and optical properties, surface forces, interaction of colloidal particles, stabilization, and criteria of stability loss of different disperse systems (lyosols and aerosols, suspensions, emulsions, foams, and micellar systems) are also topics of the journal. Colloid Journal also includes the phenomena of electro- and diffusiophoresis, electro- and thermoosmosis, and capillary and reverse osmosis, i.e., phenomena dealing with the existence of diffusion layers of molecules and ions in the vicinity of the interface.