扩大生物质衍生有机酸的清洁生产,实现双碳目标:综述

IF 11.3 1区 化学 Q1 CHEMISTRY, PHYSICAL ACS Catalysis Pub Date : 2024-09-26 DOI:10.1039/D4GC03829K
Zulfiqar Ali, Jiliang Ma and Runcang Sun
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引用次数: 0

摘要

当今世界面临着与能源、环境和粮食安全有关的问题。使用碳捕集、封存和利用技术有助于减少化石燃料产生的二氧化碳排放,从而在实现双碳目标方面取得重大进展。除了促进环境友好型制造,化工行业还可以用可再生生物质取代化石燃料原料,用于合成有机酸和合成气。虽然目前正在开展多项研究,利用生物技术、热催化、电催化和光催化技术,将二氧化碳和生物质原料进行共价化,以生产有机酸和精细化学品,但在扩大清洁生产规模方面仍存在各种障碍,其中包括:(i) 解决环境问题;(ii) 生物质的复杂结构和化学成分、(iii) 转化机制和过程,(iv) 设计具有更高的耐用性和可回收性的催化剂材料,(v) 用于催化和萃取的更环保溶剂系统,(vi) 采用现代技术进行表征,(vii) 工业操作培训和指导,以及 (viii) 政府融资和政策。通过光/生物精炼厂的技术突破,利用生物物质生产的原料可持续地制造生物基产品成为可能,这对清洁和环保地合成有机酸至关重要。预计从生物质中清洁生产有机酸将从社会经济和环境因素中获益,占据主导市场份额。随着未来技术的发展,将生物质原料与二氧化碳一起用于生产燃料和精细化学品,在生态和经济上将更加可行。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Scaling up clean production of biomass-derived organic acids as a step towards the realization of dual carbon goals: a review

The contemporary world faces issues related to energy, the environment, and food security. The use of carbon capture, storage, and utilization technologies can help reduce CO2 emissions from fossil fuels, which will result in major advancements toward dual carbon targets. In addition to promoting environmentally friendly manufacturing, chemical industries may replace fossil fuel-based raw materials with renewable biomass for the synthesis of organic acids and syngas. Although several studies are being conducted on co-valorization of CO2 and biomass feedstocks to produce organic acids and fine chemicals using biotechnology, thermocatalysis, electrocatalysis, and photocatalysis, there are still various obstacles in scaling up clean production, including (i) addressing environmental concerns, (ii) the intricate structure and chemical composition of biomass, (iii) conversion mechanisms and processes, (iv) designing catalyst materials with higher durability and recyclability, (v) greener solvent systems for catalysis and extraction, (vi) the deployment of modern technologies for characterization, (vii) training and guidelines for industrial operations, and (viii) governmental financing and policy. The sustainable manufacturing of biobased products from raw feedstocks produced from biomass has been made possible via technological breakthroughs in photo-/biorefineries, which are essential for the clean and environmentally friendly synthesis of organic acids. It is anticipated that clean production of organic acids from biomass will have a dominant market share, benefiting from both socioeconomic and environmental factors. With future technical developments, the valorization of feedstocks obtained from biomass together with CO2 for manufacturing fuels and fine chemicals will be more ecologically and economically feasible.

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来源期刊
ACS Catalysis
ACS Catalysis CHEMISTRY, PHYSICAL-
CiteScore
20.80
自引率
6.20%
发文量
1253
审稿时长
1.5 months
期刊介绍: ACS Catalysis is an esteemed journal that publishes original research in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. It offers broad coverage across diverse areas such as life sciences, organometallics and synthesis, photochemistry and electrochemistry, drug discovery and synthesis, materials science, environmental protection, polymer discovery and synthesis, and energy and fuels. The scope of the journal is to showcase innovative work in various aspects of catalysis. This includes new reactions and novel synthetic approaches utilizing known catalysts, the discovery or modification of new catalysts, elucidation of catalytic mechanisms through cutting-edge investigations, practical enhancements of existing processes, as well as conceptual advances in the field. Contributions to ACS Catalysis can encompass both experimental and theoretical research focused on catalytic molecules, macromolecules, and materials that exhibit catalytic turnover.
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